Nano-palladium/amphiphilic layered double hydroxides as catalyst for the Suzuki coupling reaction in aqueous media(钯纳米粒子/双亲性水滑石催化的水相中Suzuki偶联反应)
设计合成了一种层间含有表面活性剂分子及纳米钯粒子的水滑石(LDHs)层状材料.设计方法是通过层间含表面活性剂负离子的LDHs与钯络负离子[]进行部分离子交换，得到贵金属络负离子与表面活性剂负离子共同插层的LDHs，再对金属络离子还原处理，最终得到被LDHs主体层板限域的客体纳米金属团簇.所得水滑石层状材料同时具有碱性、双亲性及金属纳米粒子催化位点三重功能，且层间距属于介孔范围，利于中长度有机反应分子的畅通.研究表明该材料对多种卤代芳烃与苯硼酸之间的水相中Suzuki偶联反应表现出优异的催化性能，催化剂具有高转化效率及良好的循环使用性....
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | zho |
| Published: |
Zhejiang University Press
2012-11-01
|
| Series: | Zhejiang Daxue xuebao. Lixue ban |
| Subjects: | |
| Online Access: | https://doi.org/10.3785/j.issn.1008-9497.2012.06.011 |
| _version_ | 1827303159806033920 |
|---|---|
| author | JINZheng-neng(金正能) ZHUOGuang-lan(卓广澜) LIUShi-yong(刘诗咏) |
| author_facet | JINZheng-neng(金正能) ZHUOGuang-lan(卓广澜) LIUShi-yong(刘诗咏) |
| author_sort | JINZheng-neng(金正能) |
| collection | DOAJ |
| description | 设计合成了一种层间含有表面活性剂分子及纳米钯粒子的水滑石(LDHs)层状材料.设计方法是通过层间含表面活性剂负离子的LDHs与钯络负离子[]进行部分离子交换，得到贵金属络负离子与表面活性剂负离子共同插层的LDHs，再对金属络离子还原处理，最终得到被LDHs主体层板限域的客体纳米金属团簇.所得水滑石层状材料同时具有碱性、双亲性及金属纳米粒子催化位点三重功能，且层间距属于介孔范围，利于中长度有机反应分子的畅通.研究表明该材料对多种卤代芳烃与苯硼酸之间的水相中Suzuki偶联反应表现出优异的催化性能，催化剂具有高转化效率及良好的循环使用性. |
| first_indexed | 2024-04-24T16:57:13Z |
| format | Article |
| id | doaj.art-4ddfcfad00ed4078bfa3f718cc05651d |
| institution | Directory Open Access Journal |
| issn | 1008-9497 |
| language | zho |
| last_indexed | 2024-04-24T16:57:13Z |
| publishDate | 2012-11-01 |
| publisher | Zhejiang University Press |
| record_format | Article |
| series | Zhejiang Daxue xuebao. Lixue ban |
| spelling | doaj.art-4ddfcfad00ed4078bfa3f718cc05651d2024-03-29T01:58:31ZzhoZhejiang University PressZhejiang Daxue xuebao. Lixue ban1008-94972012-11-0139665465810.3785/j.issn.1008-9497.2012.06.011Nano-palladium/amphiphilic layered double hydroxides as catalyst for the Suzuki coupling reaction in aqueous media(钯纳米粒子/双亲性水滑石催化的水相中Suzuki偶联反应)JINZheng-neng(金正能)0ZHUOGuang-lan(卓广澜)1LIUShi-yong(刘诗咏)2 1.College of Chemistry & Pharmacy, Taizhou University, Linhai 317000, Zhejiang Province, China( 1.台州学院化学系，浙江 临海 317000) 2.Department of Chemistry, Zhejiang Science & Technology University, Hangzhou 310018, China( 2.浙江理工大学化学系，浙江 杭州 310018) 1.College of Chemistry & Pharmacy, Taizhou University, Linhai 317000, Zhejiang Province, China( 1.台州学院化学系，浙江 临海 317000)设计合成了一种层间含有表面活性剂分子及纳米钯粒子的水滑石(LDHs)层状材料.设计方法是通过层间含表面活性剂负离子的LDHs与钯络负离子[]进行部分离子交换，得到贵金属络负离子与表面活性剂负离子共同插层的LDHs，再对金属络离子还原处理，最终得到被LDHs主体层板限域的客体纳米金属团簇.所得水滑石层状材料同时具有碱性、双亲性及金属纳米粒子催化位点三重功能，且层间距属于介孔范围，利于中长度有机反应分子的畅通.研究表明该材料对多种卤代芳烃与苯硼酸之间的水相中Suzuki偶联反应表现出优异的催化性能，催化剂具有高转化效率及良好的循环使用性.https://doi.org/10.3785/j.issn.1008-9497.2012.06.011水滑石双亲性纳米钯suzuki偶联水相反应 |
| spellingShingle | JINZheng-neng(金正能) ZHUOGuang-lan(卓广澜) LIUShi-yong(刘诗咏) Nano-palladium/amphiphilic layered double hydroxides as catalyst for the Suzuki coupling reaction in aqueous media(钯纳米粒子/双亲性水滑石催化的水相中Suzuki偶联反应) Zhejiang Daxue xuebao. Lixue ban 水滑石 双亲性 纳米钯 suzuki偶联 水相反应 |
| title | Nano-palladium/amphiphilic layered double hydroxides as catalyst for the Suzuki coupling reaction in aqueous media(钯纳米粒子/双亲性水滑石催化的水相中Suzuki偶联反应) |
| title_full | Nano-palladium/amphiphilic layered double hydroxides as catalyst for the Suzuki coupling reaction in aqueous media(钯纳米粒子/双亲性水滑石催化的水相中Suzuki偶联反应) |
| title_fullStr | Nano-palladium/amphiphilic layered double hydroxides as catalyst for the Suzuki coupling reaction in aqueous media(钯纳米粒子/双亲性水滑石催化的水相中Suzuki偶联反应) |
| title_full_unstemmed | Nano-palladium/amphiphilic layered double hydroxides as catalyst for the Suzuki coupling reaction in aqueous media(钯纳米粒子/双亲性水滑石催化的水相中Suzuki偶联反应) |
| title_short | Nano-palladium/amphiphilic layered double hydroxides as catalyst for the Suzuki coupling reaction in aqueous media(钯纳米粒子/双亲性水滑石催化的水相中Suzuki偶联反应) |
| title_sort | nano palladium amphiphilic layered double hydroxides as catalyst for the suzuki coupling reaction in aqueous media 钯纳米粒子 双亲性水滑石催化的水相中suzuki偶联反应 |
| topic | 水滑石 双亲性 纳米钯 suzuki偶联 水相反应 |
| url | https://doi.org/10.3785/j.issn.1008-9497.2012.06.011 |
| work_keys_str_mv | AT jinzhengnengjīnzhèngnéng nanopalladiumamphiphiliclayereddoublehydroxidesascatalystforthesuzukicouplingreactioninaqueousmediabǎnàmǐlìzishuāngqīnxìngshuǐhuáshícuīhuàdeshuǐxiāngzhōngsuzukiǒuliánfǎnyīng AT zhuoguanglanzhuōguǎnglán nanopalladiumamphiphiliclayereddoublehydroxidesascatalystforthesuzukicouplingreactioninaqueousmediabǎnàmǐlìzishuāngqīnxìngshuǐhuáshícuīhuàdeshuǐxiāngzhōngsuzukiǒuliánfǎnyīng AT liushiyongliúshīyǒng nanopalladiumamphiphiliclayereddoublehydroxidesascatalystforthesuzukicouplingreactioninaqueousmediabǎnàmǐlìzishuāngqīnxìngshuǐhuáshícuīhuàdeshuǐxiāngzhōngsuzukiǒuliánfǎnyīng |