Microporous Silica Based Membranes for Desalination

This review provides a global overview of microporous silica based membranes for desalination via pervaporation with a focus on membrane synthesis and processing, transport mechanisms and current state of the art membrane performance. Most importantly, the recent development and novel concepts for i...

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Main Authors: João C. Diniz da Costa, Simon Smart, David K. Wang, Christelle Yacou, Muthia Elma
Format: Article
Language:English
Published: MDPI AG 2012-09-01
Series:Water
Subjects:
Online Access:http://www.mdpi.com/2073-4441/4/3/629
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author João C. Diniz da Costa
Simon Smart
David K. Wang
Christelle Yacou
Muthia Elma
author_facet João C. Diniz da Costa
Simon Smart
David K. Wang
Christelle Yacou
Muthia Elma
author_sort João C. Diniz da Costa
collection DOAJ
description This review provides a global overview of microporous silica based membranes for desalination via pervaporation with a focus on membrane synthesis and processing, transport mechanisms and current state of the art membrane performance. Most importantly, the recent development and novel concepts for improving the hydro-stability and separating performance of silica membranes for desalination are critically examined. Research into silica based membranes for desalination has focussed on three primary methods for improving the hydro-stability. These include incorporating carbon templates into the microporous silica both as surfactants and hybrid organic-inorganic structures and incorporation of metal oxide nanoparticles into the silica matrix. The literature examined identified that only metal oxide silica membranes have demonstrated high salt rejections under a variety of feed concentrations, reasonable fluxes and unaltered performance over long-term operation. As this is an embryonic field of research several target areas for researchers were discussed including further improvement of the membrane materials, but also regarding the necessity of integrating waste or solar heat sources into the final process design to ensure cost competitiveness with conventional reverse osmosis processes.
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spelling doaj.art-4e29de66354a4a99ab8e32331b0459122022-12-22T03:23:07ZengMDPI AGWater2073-44412012-09-014362964910.3390/w4030629Microporous Silica Based Membranes for DesalinationJoão C. Diniz da CostaSimon SmartDavid K. WangChristelle YacouMuthia ElmaThis review provides a global overview of microporous silica based membranes for desalination via pervaporation with a focus on membrane synthesis and processing, transport mechanisms and current state of the art membrane performance. Most importantly, the recent development and novel concepts for improving the hydro-stability and separating performance of silica membranes for desalination are critically examined. Research into silica based membranes for desalination has focussed on three primary methods for improving the hydro-stability. These include incorporating carbon templates into the microporous silica both as surfactants and hybrid organic-inorganic structures and incorporation of metal oxide nanoparticles into the silica matrix. The literature examined identified that only metal oxide silica membranes have demonstrated high salt rejections under a variety of feed concentrations, reasonable fluxes and unaltered performance over long-term operation. As this is an embryonic field of research several target areas for researchers were discussed including further improvement of the membrane materials, but also regarding the necessity of integrating waste or solar heat sources into the final process design to ensure cost competitiveness with conventional reverse osmosis processes.http://www.mdpi.com/2073-4441/4/3/629desalinationpervaporationmicroporous silicametal oxide silicahybrid silicacarbon template silica
spellingShingle João C. Diniz da Costa
Simon Smart
David K. Wang
Christelle Yacou
Muthia Elma
Microporous Silica Based Membranes for Desalination
Water
desalination
pervaporation
microporous silica
metal oxide silica
hybrid silica
carbon template silica
title Microporous Silica Based Membranes for Desalination
title_full Microporous Silica Based Membranes for Desalination
title_fullStr Microporous Silica Based Membranes for Desalination
title_full_unstemmed Microporous Silica Based Membranes for Desalination
title_short Microporous Silica Based Membranes for Desalination
title_sort microporous silica based membranes for desalination
topic desalination
pervaporation
microporous silica
metal oxide silica
hybrid silica
carbon template silica
url http://www.mdpi.com/2073-4441/4/3/629
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AT christelleyacou microporoussilicabasedmembranesfordesalination
AT muthiaelma microporoussilicabasedmembranesfordesalination