X-ray photoelectron spectroscopy (XPS) and gamma-ray shielding investigation of boro-silicate glasses contained alkali/alkaline modifier
In the present work, seven glass samples have been prepared utilizing melt-quenching method with composition of 40B2O3-10SiO2-10Al2O3-30ZnO-10 (Li2O/Na2O/K2O/MgO/CaO/SrO/BaO) all in mol%. Scanning electron microscope (SEM) and Energy-dispersive X-ray spectroscopy (EDX) have characterized for H3 (K2O...
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Elsevier
2019-09-01
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Series: | Results in Physics |
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author | Kawa M. Kaky Erdem Şakar Uğur Akbaba A. Emre Kasapoğlu M.I. Sayyed Emre Gür S.O. Baki M.A. Mahdi |
author_facet | Kawa M. Kaky Erdem Şakar Uğur Akbaba A. Emre Kasapoğlu M.I. Sayyed Emre Gür S.O. Baki M.A. Mahdi |
author_sort | Kawa M. Kaky |
collection | DOAJ |
description | In the present work, seven glass samples have been prepared utilizing melt-quenching method with composition of 40B2O3-10SiO2-10Al2O3-30ZnO-10 (Li2O/Na2O/K2O/MgO/CaO/SrO/BaO) all in mol%. Scanning electron microscope (SEM) and Energy-dispersive X-ray spectroscopy (EDX) have characterized for H3 (K2O) and H7 (BaO), to examine the structural properties. X-ray Photoelectron Spectroscopy (XPS) has shown that the boron (B) element composition is highest after oxygen elements in all the glasses. It has been also observed that incorporation of potassium (K) and strontium (Sr) elements are maximum compared to the other doped elements into the glass. Further, the photon shielding for H1-H7 samples were also studied. We calculated the mass attenuation coefficients (μ/ρ) for the present samples at some energies between 0.015 and 10 MeV. The results revealed that H7 (BaO) sample owns the highest μ/ρ values followed by H6 (SrO) while H1 (Li2O) has the lowest μ/ρ. Moreover, H7 and H6 samples have higher effective atomic number than the rest of glasses. H7 sample has excellent shielding properties when compared with the other glasses. We found that the composition of the sample affects the attenuation of the glasses and high attenuation can be achieved when we used heavy metal oxides (such as BaO). Keywords: X-ray photoelectron spectroscopy, Borosilicate glasses, Radiation, Attenuation |
first_indexed | 2024-04-14T05:44:46Z |
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issn | 2211-3797 |
language | English |
last_indexed | 2024-04-14T05:44:46Z |
publishDate | 2019-09-01 |
publisher | Elsevier |
record_format | Article |
series | Results in Physics |
spelling | doaj.art-4e530f11af28497faab52af1f7e047432022-12-22T02:09:20ZengElsevierResults in Physics2211-37972019-09-0114X-ray photoelectron spectroscopy (XPS) and gamma-ray shielding investigation of boro-silicate glasses contained alkali/alkaline modifierKawa M. Kaky0Erdem Şakar1Uğur Akbaba2A. Emre Kasapoğlu3M.I. Sayyed4Emre Gür5S.O. Baki6M.A. Mahdi7Directorate of Communication and Information Technology, Council of Representatives of Iraq, Conferences Palace, Baghdad, IraqDepartment of Physics, Faculty of Science, Ataturk University, Erzurum, TurkeyDepartment of Physics Education, Faculty of Education, Kafkas University, Kars, TurkeyEast Anatolia High Technology Application and Research Center, Atatürk University, 25240, TurkeyUniversity of Tabuk, Department of Physics, Tabuk, Saudi ArabiaDepartment of Physics, Faculty of Science, Ataturk University, Erzurum, TurkeyDepartment of Physics, Faculty of Science, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia; Corresponding author.Wireless and Photonic Networks Research Centre, Faculty of Engineering, Universiti Putra Malaysia, 43400 Serdang, Selangor, MalaysiaIn the present work, seven glass samples have been prepared utilizing melt-quenching method with composition of 40B2O3-10SiO2-10Al2O3-30ZnO-10 (Li2O/Na2O/K2O/MgO/CaO/SrO/BaO) all in mol%. Scanning electron microscope (SEM) and Energy-dispersive X-ray spectroscopy (EDX) have characterized for H3 (K2O) and H7 (BaO), to examine the structural properties. X-ray Photoelectron Spectroscopy (XPS) has shown that the boron (B) element composition is highest after oxygen elements in all the glasses. It has been also observed that incorporation of potassium (K) and strontium (Sr) elements are maximum compared to the other doped elements into the glass. Further, the photon shielding for H1-H7 samples were also studied. We calculated the mass attenuation coefficients (μ/ρ) for the present samples at some energies between 0.015 and 10 MeV. The results revealed that H7 (BaO) sample owns the highest μ/ρ values followed by H6 (SrO) while H1 (Li2O) has the lowest μ/ρ. Moreover, H7 and H6 samples have higher effective atomic number than the rest of glasses. H7 sample has excellent shielding properties when compared with the other glasses. We found that the composition of the sample affects the attenuation of the glasses and high attenuation can be achieved when we used heavy metal oxides (such as BaO). Keywords: X-ray photoelectron spectroscopy, Borosilicate glasses, Radiation, Attenuationhttp://www.sciencedirect.com/science/article/pii/S221137971931561X |
spellingShingle | Kawa M. Kaky Erdem Şakar Uğur Akbaba A. Emre Kasapoğlu M.I. Sayyed Emre Gür S.O. Baki M.A. Mahdi X-ray photoelectron spectroscopy (XPS) and gamma-ray shielding investigation of boro-silicate glasses contained alkali/alkaline modifier Results in Physics |
title | X-ray photoelectron spectroscopy (XPS) and gamma-ray shielding investigation of boro-silicate glasses contained alkali/alkaline modifier |
title_full | X-ray photoelectron spectroscopy (XPS) and gamma-ray shielding investigation of boro-silicate glasses contained alkali/alkaline modifier |
title_fullStr | X-ray photoelectron spectroscopy (XPS) and gamma-ray shielding investigation of boro-silicate glasses contained alkali/alkaline modifier |
title_full_unstemmed | X-ray photoelectron spectroscopy (XPS) and gamma-ray shielding investigation of boro-silicate glasses contained alkali/alkaline modifier |
title_short | X-ray photoelectron spectroscopy (XPS) and gamma-ray shielding investigation of boro-silicate glasses contained alkali/alkaline modifier |
title_sort | x ray photoelectron spectroscopy xps and gamma ray shielding investigation of boro silicate glasses contained alkali alkaline modifier |
url | http://www.sciencedirect.com/science/article/pii/S221137971931561X |
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