Carbon and Graphene Coatings for the Thermal Management of Sustainable LMP Batteries for Automotive Applications

The increment of battery temperature during the operation caused by internal heat generation is one of the main issues to face in the management of storage systems for automotive and power generation applications. The temperature strongly affects the battery efficiency, granting the best performance...

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Main Authors: Luigi Sequino, Gaetano Sebastianelli, Bianca Maria Vaglieco
Format: Article
Language:English
Published: MDPI AG 2022-11-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/15/21/7744
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author Luigi Sequino
Gaetano Sebastianelli
Bianca Maria Vaglieco
author_facet Luigi Sequino
Gaetano Sebastianelli
Bianca Maria Vaglieco
author_sort Luigi Sequino
collection DOAJ
description The increment of battery temperature during the operation caused by internal heat generation is one of the main issues to face in the management of storage systems for automotive and power generation applications. The temperature strongly affects the battery efficiency, granting the best performance in a limited range. The investigation and testing of materials for the improvement of heat dissipation are crucial for modern battery systems that must provide high power and energy density. This study presents an analysis of the thermal behavior of a lithium-polymer cell, which can be stacked in a battery pack for electric vehicles. The cell is sheltered with layers of two different materials: carbon and graphene, used in turn, to dissipate the heat generated during the operation in natural convection. Optical diagnostics in the infrared band is used to evaluate the battery surface temperature and the effect of the coatings. Experiments are performed in two operating conditions varying the current demand. Moreover, two theoretical correlations are used to estimate the thermal parameters of the battery with a reverse-logic approach. The convective heat transfer coefficient h and the specific heat capacity c<sub>p</sub> of the battery are evaluated and provided for the Li-ion battery under investigation for different coatings’ conductivity. The results highlight the advantage of using a coating and the effect of the coating properties to reduce the battery temperature under operation. In particular, graphene is preferable because it provides the lowest battery temperature in the most intense operating condition.
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spelling doaj.art-4e5f48be27fd4bf7a0a659e20a28cd852023-11-24T05:40:07ZengMDPI AGMaterials1996-19442022-11-011521774410.3390/ma15217744Carbon and Graphene Coatings for the Thermal Management of Sustainable LMP Batteries for Automotive ApplicationsLuigi Sequino0Gaetano Sebastianelli1Bianca Maria Vaglieco2Istituto di Scienze e Tecnologie per l’Energia e la Mobilità Sostenibili—CNR, 80125 Napoli, ItalyIstituto di Scienze e Tecnologie per l’Energia e la Mobilità Sostenibili—CNR, 80125 Napoli, ItalyIstituto di Scienze e Tecnologie per l’Energia e la Mobilità Sostenibili—CNR, 80125 Napoli, ItalyThe increment of battery temperature during the operation caused by internal heat generation is one of the main issues to face in the management of storage systems for automotive and power generation applications. The temperature strongly affects the battery efficiency, granting the best performance in a limited range. The investigation and testing of materials for the improvement of heat dissipation are crucial for modern battery systems that must provide high power and energy density. This study presents an analysis of the thermal behavior of a lithium-polymer cell, which can be stacked in a battery pack for electric vehicles. The cell is sheltered with layers of two different materials: carbon and graphene, used in turn, to dissipate the heat generated during the operation in natural convection. Optical diagnostics in the infrared band is used to evaluate the battery surface temperature and the effect of the coatings. Experiments are performed in two operating conditions varying the current demand. Moreover, two theoretical correlations are used to estimate the thermal parameters of the battery with a reverse-logic approach. The convective heat transfer coefficient h and the specific heat capacity c<sub>p</sub> of the battery are evaluated and provided for the Li-ion battery under investigation for different coatings’ conductivity. The results highlight the advantage of using a coating and the effect of the coating properties to reduce the battery temperature under operation. In particular, graphene is preferable because it provides the lowest battery temperature in the most intense operating condition.https://www.mdpi.com/1996-1944/15/21/7744carbon coatinggraphene coatingLi-ion batteries
spellingShingle Luigi Sequino
Gaetano Sebastianelli
Bianca Maria Vaglieco
Carbon and Graphene Coatings for the Thermal Management of Sustainable LMP Batteries for Automotive Applications
Materials
carbon coating
graphene coating
Li-ion batteries
title Carbon and Graphene Coatings for the Thermal Management of Sustainable LMP Batteries for Automotive Applications
title_full Carbon and Graphene Coatings for the Thermal Management of Sustainable LMP Batteries for Automotive Applications
title_fullStr Carbon and Graphene Coatings for the Thermal Management of Sustainable LMP Batteries for Automotive Applications
title_full_unstemmed Carbon and Graphene Coatings for the Thermal Management of Sustainable LMP Batteries for Automotive Applications
title_short Carbon and Graphene Coatings for the Thermal Management of Sustainable LMP Batteries for Automotive Applications
title_sort carbon and graphene coatings for the thermal management of sustainable lmp batteries for automotive applications
topic carbon coating
graphene coating
Li-ion batteries
url https://www.mdpi.com/1996-1944/15/21/7744
work_keys_str_mv AT luigisequino carbonandgraphenecoatingsforthethermalmanagementofsustainablelmpbatteriesforautomotiveapplications
AT gaetanosebastianelli carbonandgraphenecoatingsforthethermalmanagementofsustainablelmpbatteriesforautomotiveapplications
AT biancamariavaglieco carbonandgraphenecoatingsforthethermalmanagementofsustainablelmpbatteriesforautomotiveapplications