Nanostructured materials for sensing Pb(II) and Cd(II) ions: Manganese oxohydroxide versus carbonized polyanilines?

Nanostructured materials including three different carbonized polyanilines and manganese oxyhydroxide were prepared and evaluated as electrode materials for sensing of lead and cadmium ions in aqueous media. Anodic stripping voltammetry results indicated that all prepared materials could be...

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Main Authors: Šljukić Biljana, Micić Darko, Cvjetićanin Nikola, Ćirić-Marjanović Gordana
Format: Article
Language:English
Published: Serbian Chemical Society 2013-01-01
Series:Journal of the Serbian Chemical Society
Subjects:
Online Access:http://www.doiserbia.nb.rs/img/doi/0352-5139/2013/0352-51391300101S.pdf
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author Šljukić Biljana
Micić Darko
Cvjetićanin Nikola
Ćirić-Marjanović Gordana
author_facet Šljukić Biljana
Micić Darko
Cvjetićanin Nikola
Ćirić-Marjanović Gordana
author_sort Šljukić Biljana
collection DOAJ
description Nanostructured materials including three different carbonized polyanilines and manganese oxyhydroxide were prepared and evaluated as electrode materials for sensing of lead and cadmium ions in aqueous media. Anodic stripping voltammetry results indicated that all prepared materials could be successfully used for determination of these two heavy metal ions. Carbonized polyaniline-based electrodes have higher signal and lower limits of detection (10-7 М) compared to manganese oxyhydroxide-based electrode. Among the three studied carbonized polyanilines, the one that was derived from polyaniline precursor produced in the presence of 3,5-dinitrosalicyclic acid showed the highest electrocatalytic activity towards the lead and cadmium oxidation. [Projekat Ministarstva nauke Republike Srbije, br. OI172043 i br. III45014]
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spelling doaj.art-4e73669c941b404992b7d5f3b84217222022-12-22T01:50:12ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51391820-74212013-01-0178111717172710.2298/JSC130731101S0352-51391300101SNanostructured materials for sensing Pb(II) and Cd(II) ions: Manganese oxohydroxide versus carbonized polyanilines?Šljukić Biljana0Micić Darko1Cvjetićanin Nikola2Ćirić-Marjanović Gordana3Faculty of Physical Chemistry, BelgradeFaculty of Physical Chemistry, BelgradeFaculty of Physical Chemistry, BelgradeFaculty of Physical Chemistry, BelgradeNanostructured materials including three different carbonized polyanilines and manganese oxyhydroxide were prepared and evaluated as electrode materials for sensing of lead and cadmium ions in aqueous media. Anodic stripping voltammetry results indicated that all prepared materials could be successfully used for determination of these two heavy metal ions. Carbonized polyaniline-based electrodes have higher signal and lower limits of detection (10-7 М) compared to manganese oxyhydroxide-based electrode. Among the three studied carbonized polyanilines, the one that was derived from polyaniline precursor produced in the presence of 3,5-dinitrosalicyclic acid showed the highest electrocatalytic activity towards the lead and cadmium oxidation. [Projekat Ministarstva nauke Republike Srbije, br. OI172043 i br. III45014]http://www.doiserbia.nb.rs/img/doi/0352-5139/2013/0352-51391300101S.pdflead ionscadmium ionscarbonized nanostructured polyanilinemanganese oxyhydroxideelectrochemical sensors
spellingShingle Šljukić Biljana
Micić Darko
Cvjetićanin Nikola
Ćirić-Marjanović Gordana
Nanostructured materials for sensing Pb(II) and Cd(II) ions: Manganese oxohydroxide versus carbonized polyanilines?
Journal of the Serbian Chemical Society
lead ions
cadmium ions
carbonized nanostructured polyaniline
manganese oxyhydroxide
electrochemical sensors
title Nanostructured materials for sensing Pb(II) and Cd(II) ions: Manganese oxohydroxide versus carbonized polyanilines?
title_full Nanostructured materials for sensing Pb(II) and Cd(II) ions: Manganese oxohydroxide versus carbonized polyanilines?
title_fullStr Nanostructured materials for sensing Pb(II) and Cd(II) ions: Manganese oxohydroxide versus carbonized polyanilines?
title_full_unstemmed Nanostructured materials for sensing Pb(II) and Cd(II) ions: Manganese oxohydroxide versus carbonized polyanilines?
title_short Nanostructured materials for sensing Pb(II) and Cd(II) ions: Manganese oxohydroxide versus carbonized polyanilines?
title_sort nanostructured materials for sensing pb ii and cd ii ions manganese oxohydroxide versus carbonized polyanilines
topic lead ions
cadmium ions
carbonized nanostructured polyaniline
manganese oxyhydroxide
electrochemical sensors
url http://www.doiserbia.nb.rs/img/doi/0352-5139/2013/0352-51391300101S.pdf
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AT micicdarko nanostructuredmaterialsforsensingpbiiandcdiiionsmanganeseoxohydroxideversuscarbonizedpolyanilines
AT cvjeticaninnikola nanostructuredmaterialsforsensingpbiiandcdiiionsmanganeseoxohydroxideversuscarbonizedpolyanilines
AT ciricmarjanovicgordana nanostructuredmaterialsforsensingpbiiandcdiiionsmanganeseoxohydroxideversuscarbonizedpolyanilines