Combination of fingerprint and chemometric analytical approaches to identify the geographical origin of Qinghai-Tibet plateau rapeseed oil

Verification of the geographical origin of rapeseed oil is essential to protect consumers from fraudulent products. A prospective study was conducted on 45 samples from three rapeseed oil-producing areas in Qinghai Province, which were analyzed by GC-FID and GC-MS. To assess the accuracy of the pred...

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Main Authors: Ziqin Ye, Jinying Wang, Shengrui Gan, Guoxin Dong, Furong Yang
Format: Article
Language:English
Published: Elsevier 2024-03-01
Series:Heliyon
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2405844024031980
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author Ziqin Ye
Jinying Wang
Shengrui Gan
Guoxin Dong
Furong Yang
author_facet Ziqin Ye
Jinying Wang
Shengrui Gan
Guoxin Dong
Furong Yang
author_sort Ziqin Ye
collection DOAJ
description Verification of the geographical origin of rapeseed oil is essential to protect consumers from fraudulent products. A prospective study was conducted on 45 samples from three rapeseed oil-producing areas in Qinghai Province, which were analyzed by GC-FID and GC-MS. To assess the accuracy of the prediction of origin, classification models were developed using PCA, OPLS-DA, and LDA. It was found that multivariate analysis combined with PCA separate 96% of the samples, and the correct sample discrimination rate based on the OPLS-DA model was over 98%. The predictive index of the model was Q2 = 0.841, indicating that the model had good predictive ability. The LDA results showed highly accurate classification (100%) and cross-validation (100%) rates for the rapeseed oil samples, demonstrating that the model had strong predictive capacity. These findings will serve as a foundation for the implementation and advancement of origin traceability using the combination of fatty acid, phytosterol and tocopherol fingerprints.
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spelling doaj.art-4e77d5b49a97482dbdeaec332abd2f442024-03-17T07:57:32ZengElsevierHeliyon2405-84402024-03-01105e27167Combination of fingerprint and chemometric analytical approaches to identify the geographical origin of Qinghai-Tibet plateau rapeseed oilZiqin Ye0Jinying Wang1Shengrui Gan2Guoxin Dong3Furong Yang4College of Agriculture and Animal Husbandry, Qinghai University, Xining, 810016, PR ChinaCollege of Agriculture and Animal Husbandry, Qinghai University, Xining, 810016, PR China; State Key Laboratory of Plateau Ecology and Agriculture, Qinghai University, Xining, 810016, PR China; Corresponding author.College of Agriculture and Animal Husbandry, Qinghai University, Xining, Qinghai, 810016, PR China.College of Agriculture and Animal Husbandry, Qinghai University, Xining, 810016, PR ChinaCollege of Agriculture and Animal Husbandry, Qinghai University, Xining, 810016, PR ChinaCollege of Agriculture and Animal Husbandry, Qinghai University, Xining, 810016, PR ChinaVerification of the geographical origin of rapeseed oil is essential to protect consumers from fraudulent products. A prospective study was conducted on 45 samples from three rapeseed oil-producing areas in Qinghai Province, which were analyzed by GC-FID and GC-MS. To assess the accuracy of the prediction of origin, classification models were developed using PCA, OPLS-DA, and LDA. It was found that multivariate analysis combined with PCA separate 96% of the samples, and the correct sample discrimination rate based on the OPLS-DA model was over 98%. The predictive index of the model was Q2 = 0.841, indicating that the model had good predictive ability. The LDA results showed highly accurate classification (100%) and cross-validation (100%) rates for the rapeseed oil samples, demonstrating that the model had strong predictive capacity. These findings will serve as a foundation for the implementation and advancement of origin traceability using the combination of fatty acid, phytosterol and tocopherol fingerprints.http://www.sciencedirect.com/science/article/pii/S2405844024031980Fatty acidsPhytosterolsTocopherolsRapeseed oilChemometricsGeographical origin
spellingShingle Ziqin Ye
Jinying Wang
Shengrui Gan
Guoxin Dong
Furong Yang
Combination of fingerprint and chemometric analytical approaches to identify the geographical origin of Qinghai-Tibet plateau rapeseed oil
Heliyon
Fatty acids
Phytosterols
Tocopherols
Rapeseed oil
Chemometrics
Geographical origin
title Combination of fingerprint and chemometric analytical approaches to identify the geographical origin of Qinghai-Tibet plateau rapeseed oil
title_full Combination of fingerprint and chemometric analytical approaches to identify the geographical origin of Qinghai-Tibet plateau rapeseed oil
title_fullStr Combination of fingerprint and chemometric analytical approaches to identify the geographical origin of Qinghai-Tibet plateau rapeseed oil
title_full_unstemmed Combination of fingerprint and chemometric analytical approaches to identify the geographical origin of Qinghai-Tibet plateau rapeseed oil
title_short Combination of fingerprint and chemometric analytical approaches to identify the geographical origin of Qinghai-Tibet plateau rapeseed oil
title_sort combination of fingerprint and chemometric analytical approaches to identify the geographical origin of qinghai tibet plateau rapeseed oil
topic Fatty acids
Phytosterols
Tocopherols
Rapeseed oil
Chemometrics
Geographical origin
url http://www.sciencedirect.com/science/article/pii/S2405844024031980
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