Vanadate‐Based Fibrous Electrode Materials for High Performance Aqueous Zinc Ion Batteries
Abstract Aqueous zinc‐ion batteries (AZIBs) are considered as attractive energy storage systems with great promise owing to their low cost, environmental friendliness and high safety. Nevertheless, cathode materials with stable structure and rapid diffusion of zinc ions are in great demand for AZIBs...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
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Wiley
2024-03-01
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| Series: | Advanced Science |
| Subjects: | |
| Online Access: | https://doi.org/10.1002/advs.202307872 |
| _version_ | 1827313273924485120 |
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| author | Qimeng Wang Jianping Wu Mingming Wang Haizhou Yu Xiaoyan Qiu Wei Chen |
| author_facet | Qimeng Wang Jianping Wu Mingming Wang Haizhou Yu Xiaoyan Qiu Wei Chen |
| author_sort | Qimeng Wang |
| collection | DOAJ |
| description | Abstract Aqueous zinc‐ion batteries (AZIBs) are considered as attractive energy storage systems with great promise owing to their low cost, environmental friendliness and high safety. Nevertheless, cathode materials with stable structure and rapid diffusion of zinc ions are in great demand for AZIBs. In this work, a new kind of potassium vanadate compound (KV3O8) is synthesized with fibrous morphology as an excellent cathode material for AZIBs, which shows outstanding electrochemical performance. KV3O8 exhibits a high discharge capacity of 556.4 mAh g−1 at 0.8 A g−1, and the capacity retention is 81.3% at 6 A g−1 even after a long cycle life of 5000 cycles. The excellent performance of the KV3O8 cathode is benefited from the structural stability, sufficient active sites, and high conductivity, which is revealed by in situ X‐ray diffraction and various other characterizations. This work offers a new design strategy into fabricating high efficiency cathode materials for AZIBs and beyond. |
| first_indexed | 2024-04-24T21:58:53Z |
| format | Article |
| id | doaj.art-4e8bb683b53e47e3bfa941265d25e710 |
| institution | Directory Open Access Journal |
| issn | 2198-3844 |
| language | English |
| last_indexed | 2024-04-24T21:58:53Z |
| publishDate | 2024-03-01 |
| publisher | Wiley |
| record_format | Article |
| series | Advanced Science |
| spelling | doaj.art-4e8bb683b53e47e3bfa941265d25e7102024-03-20T12:56:12ZengWileyAdvanced Science2198-38442024-03-011111n/an/a10.1002/advs.202307872Vanadate‐Based Fibrous Electrode Materials for High Performance Aqueous Zinc Ion BatteriesQimeng Wang0Jianping Wu1Mingming Wang2Haizhou Yu3Xiaoyan Qiu4Wei Chen5Key Laboratory of Flexible Electronics (KLOFE) and Institute of Advanced Materials (IAM), School of Flexible Electronics (Future Technologies) Nanjing Tech University Nanjing 211816 P. R. ChinaKey Laboratory of Flexible Electronics (KLOFE) and Institute of Advanced Materials (IAM), School of Flexible Electronics (Future Technologies) Nanjing Tech University Nanjing 211816 P. R. ChinaDepartment of Applied Chemistry School of Chemistry and Materials Science Hefei National Research Center for Physical Sciences at the Microscale University of Science and Technology of China Hefei Anhui 230026 P. R. ChinaInstitute of Advanced Synthesis (IAS) School of Chemistry and Molecular Engineering Nanjing Tech University Nanjing 211816 P. R. ChinaKey Laboratory of Flexible Electronics (KLOFE) and Institute of Advanced Materials (IAM), School of Flexible Electronics (Future Technologies) Nanjing Tech University Nanjing 211816 P. R. ChinaDepartment of Applied Chemistry School of Chemistry and Materials Science Hefei National Research Center for Physical Sciences at the Microscale University of Science and Technology of China Hefei Anhui 230026 P. R. ChinaAbstract Aqueous zinc‐ion batteries (AZIBs) are considered as attractive energy storage systems with great promise owing to their low cost, environmental friendliness and high safety. Nevertheless, cathode materials with stable structure and rapid diffusion of zinc ions are in great demand for AZIBs. In this work, a new kind of potassium vanadate compound (KV3O8) is synthesized with fibrous morphology as an excellent cathode material for AZIBs, which shows outstanding electrochemical performance. KV3O8 exhibits a high discharge capacity of 556.4 mAh g−1 at 0.8 A g−1, and the capacity retention is 81.3% at 6 A g−1 even after a long cycle life of 5000 cycles. The excellent performance of the KV3O8 cathode is benefited from the structural stability, sufficient active sites, and high conductivity, which is revealed by in situ X‐ray diffraction and various other characterizations. This work offers a new design strategy into fabricating high efficiency cathode materials for AZIBs and beyond.https://doi.org/10.1002/advs.202307872cathodeion dopinglarge‐scale energy storagevanadate based materialzinc ion battery |
| spellingShingle | Qimeng Wang Jianping Wu Mingming Wang Haizhou Yu Xiaoyan Qiu Wei Chen Vanadate‐Based Fibrous Electrode Materials for High Performance Aqueous Zinc Ion Batteries Advanced Science cathode ion doping large‐scale energy storage vanadate based material zinc ion battery |
| title | Vanadate‐Based Fibrous Electrode Materials for High Performance Aqueous Zinc Ion Batteries |
| title_full | Vanadate‐Based Fibrous Electrode Materials for High Performance Aqueous Zinc Ion Batteries |
| title_fullStr | Vanadate‐Based Fibrous Electrode Materials for High Performance Aqueous Zinc Ion Batteries |
| title_full_unstemmed | Vanadate‐Based Fibrous Electrode Materials for High Performance Aqueous Zinc Ion Batteries |
| title_short | Vanadate‐Based Fibrous Electrode Materials for High Performance Aqueous Zinc Ion Batteries |
| title_sort | vanadate based fibrous electrode materials for high performance aqueous zinc ion batteries |
| topic | cathode ion doping large‐scale energy storage vanadate based material zinc ion battery |
| url | https://doi.org/10.1002/advs.202307872 |
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