Design, Synthesis, and Temperature-Driven Molecular Conformation-Dependent Delayed Fluorescence Characteristics of Dianthrylboron-Based Donor–Acceptor Systems

Design, Synthesis, and Temperature-Driven Molecular Conformation-Dependent Delayed Fluorescence Characteristics of Dianthrylboron-Based Donor–Acceptor Systems

We report a simple and novel molecular design strategy to enhance rISC in boron-based donor–acceptor systems to achieve improved delayed fluorescence characteristics. Dianthrylboryl ((An)2B)-based aryl aminoboranes 1 (donor: phenothiazine) and 2 (donor: N,N-diphenylamine) were synthesized by a simpl...

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Bibliographic Details
Main Authors: Umesh Pratap Pandey, Rajendra Prasad Nandi, Pakkirisamy Thilagar
Format: Article
Language:English
Published: Frontiers Media S.A. 2020-10-01
Series:Frontiers in Chemistry
Subjects:
boron
aminoboron
TADF
anthracene
phenothiazine
Online Access:https://www.frontiersin.org/article/10.3389/fchem.2020.541331/full

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