Reduction effect of coercivity of electroplated Fe-Pt film magnets by chloride ion in plating baths

We recently reported the electroplating of Fe-Pt thick films using plating baths with varying concentrations of NaCl, suggesting the potential for coercivity enhancement by Na ions. In the present study, our focus shifted to not Na ions but Cl ones, and we investigated the effect of the Cl ions on t...

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Bibliographic Details
Main Authors: Takeshi Yanai, Daiki Fukushima, Ryuta Narabayashi, Naoki Ogushi, Yuito Yamaguchi, Akihiro Yamashita, Masaki Nakano, Hirotoshi Fukunaga
Format: Article
Language:English
Published: AIP Publishing LLC 2024-02-01
Series:AIP Advances
Online Access:http://dx.doi.org/10.1063/9.0000776
Description
Summary:We recently reported the electroplating of Fe-Pt thick films using plating baths with varying concentrations of NaCl, suggesting the potential for coercivity enhancement by Na ions. In the present study, our focus shifted to not Na ions but Cl ones, and we investigated the effect of the Cl ions on the crystal structures and magnetic properties of electroplated Fe-Pt films. With the increasing concentration of Cl ions, the coercivity of the films decreased. Furthermore, XRD analysis suggested that the Cl ions in the plating baths prevent the L10 ordering of the Fe-Pt crystalline phase, leading us to conclude that a Cl-free bath is favorable for preparing Fe-Pt thick-film magnets with high coercivity.
ISSN:2158-3226