Synthèse, étude et validation structurale d'un triple bis-molybdate en couches, Ag0.60Na0.40Fe(MoO4)2 lié à yavapaiite
The title compound, Ag0.60Na0.40Fe(MoO4)2 {silver sodium iron(III) bis[molybdate(VI)]}, was synthesized by a solid-state reaction. The structure is built up from FeO6 octahedra and MoO4 tetrahedra sharing corners to form a two-dimensional framework parallel to the (001) plane. The occupationally dis...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2016-05-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989016006654 |
| _version_ | 1818320247650779136 |
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| author | Amira Souilem Mohamed Faouzi Zid |
| author_facet | Amira Souilem Mohamed Faouzi Zid |
| author_sort | Amira Souilem |
| collection | DOAJ |
| description | The title compound, Ag0.60Na0.40Fe(MoO4)2 {silver sodium iron(III) bis[molybdate(VI)]}, was synthesized by a solid-state reaction. The structure is built up from FeO6 octahedra and MoO4 tetrahedra sharing corners to form a two-dimensional framework parallel to the (001) plane. The occupationally disordered (Ag/Na)+ cations are located in the interlayer space. These [Fe(MoO4)2−]n layers are similar to those in the isotypic yavapaiite-related structure of NaFe(MoO4)2. All atoms are on general positions except for Fe (site symmetry -1) and Ag/Na (site symmetry 2). The Ag/Na occupancies of the latter site were refined to 0.597 (4):0.403 (5). The title structure is compared to similar structures. |
| first_indexed | 2024-12-13T10:21:59Z |
| format | Article |
| id | doaj.art-4eb0d4ed9bdd4e4bb822fda6f9d22c77 |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-12-13T10:21:59Z |
| publishDate | 2016-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-4eb0d4ed9bdd4e4bb822fda6f9d22c772022-12-21T23:51:10ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902016-05-0172573774010.1107/S2056989016006654vn2110Synthèse, étude et validation structurale d'un triple bis-molybdate en couches, Ag0.60Na0.40Fe(MoO4)2 lié à yavapaiiteAmira Souilem0Mohamed Faouzi Zid1Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis El Manar, 2092 El Manar Tunis, TunisiaLaboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis El Manar, 2092 El Manar Tunis, TunisiaThe title compound, Ag0.60Na0.40Fe(MoO4)2 {silver sodium iron(III) bis[molybdate(VI)]}, was synthesized by a solid-state reaction. The structure is built up from FeO6 octahedra and MoO4 tetrahedra sharing corners to form a two-dimensional framework parallel to the (001) plane. The occupationally disordered (Ag/Na)+ cations are located in the interlayer space. These [Fe(MoO4)2−]n layers are similar to those in the isotypic yavapaiite-related structure of NaFe(MoO4)2. All atoms are on general positions except for Fe (site symmetry -1) and Ag/Na (site symmetry 2). The Ag/Na occupancies of the latter site were refined to 0.597 (4):0.403 (5). The title structure is compared to similar structures.http://scripts.iucr.org/cgi-bin/paper?S2056989016006654crystal structuresodium-iron molybdateoccupational substitution |
| spellingShingle | Amira Souilem Mohamed Faouzi Zid Synthèse, étude et validation structurale d'un triple bis-molybdate en couches, Ag0.60Na0.40Fe(MoO4)2 lié à yavapaiite Acta Crystallographica Section E: Crystallographic Communications crystal structure sodium-iron molybdate occupational substitution |
| title | Synthèse, étude et validation structurale d'un triple bis-molybdate en couches, Ag0.60Na0.40Fe(MoO4)2 lié à yavapaiite |
| title_full | Synthèse, étude et validation structurale d'un triple bis-molybdate en couches, Ag0.60Na0.40Fe(MoO4)2 lié à yavapaiite |
| title_fullStr | Synthèse, étude et validation structurale d'un triple bis-molybdate en couches, Ag0.60Na0.40Fe(MoO4)2 lié à yavapaiite |
| title_full_unstemmed | Synthèse, étude et validation structurale d'un triple bis-molybdate en couches, Ag0.60Na0.40Fe(MoO4)2 lié à yavapaiite |
| title_short | Synthèse, étude et validation structurale d'un triple bis-molybdate en couches, Ag0.60Na0.40Fe(MoO4)2 lié à yavapaiite |
| title_sort | synthese etude et validation structurale d un triple bis molybdate en couches ag0 60na0 40fe moo4 2 lie a yavapaiite |
| topic | crystal structure sodium-iron molybdate occupational substitution |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989016006654 |
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