Potentiodynamic Corrosion Behavior and Microstructural Characteristics of Pulsed CMT-Welded AA2014-T6 Aluminium Alloy Joints: Effect of PWHT

AA2014-T6 is an Al-Cu-Mg-based precipitation-hardened aluminium alloy widely used in aerospace due to its high strength to weight ratio. This alloy is joined by a pulsed cold metal transfer (PCMT) arc welding process to overcome the high heat input related problems in gas metal arc welding (GMAW) su...

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Main Authors: A. Padma Rao, Manzoor Hadi, C. Rajendran, Sonar Tushar, Mikhail Ivanov, P. Senthil Kumar, V. Murali Krishna
Format: Article
Language:English
Published: Hindawi Limited 2022-01-01
Series:Advances in Materials Science and Engineering
Online Access:http://dx.doi.org/10.1155/2022/4874834
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author A. Padma Rao
Manzoor Hadi
C. Rajendran
Sonar Tushar
Mikhail Ivanov
P. Senthil Kumar
V. Murali Krishna
author_facet A. Padma Rao
Manzoor Hadi
C. Rajendran
Sonar Tushar
Mikhail Ivanov
P. Senthil Kumar
V. Murali Krishna
author_sort A. Padma Rao
collection DOAJ
description AA2014-T6 is an Al-Cu-Mg-based precipitation-hardened aluminium alloy widely used in aerospace due to its high strength to weight ratio. This alloy is joined by a pulsed cold metal transfer (PCMT) arc welding process to overcome the high heat input related problems in gas metal arc welding (GMAW) such as a coarser dendritic structure in the fusion zone (FZ), wider heat affected zone (HAZ), solidification and HAZ liquation cracking, softening in HAZ, and poor corrosion resistance of welded joints in salt environment. The joints were subjected to PWHT of artificial aging (AA), solution treatment (ST), and solution treatment + aging (STA) conditions. The corrosion rate was determined using a potentiodynamic corrosion test in a solution of 3.56 wt.% NaCl with pH values of 4, 7, and 11. Results disclosed that the PCMT joints subjected to the potentiodynamic corrosion test in NaCl solution of pH-4, pH-7, and pH-11 disclosed very low, moderate, and extremely high pitting corrosion, respectively. The corrosion resistance of ST joints was improved by 53.34%, 15%, and 15.12% in pH-4, pH-7, and pH-11 NaCl solution compared to as-welded joints. The pitting potential of ST joints is comparable to BM. The BM showed the pitting potential of −175, −450, and −550 mV in pH-4, pH-7, and pH-11 NaCl solution. The ST joints showed 75.29%, 29.16%, and 27.85% lower corrosion potential compared to STA joints in pH-4, pH-7, and pH-11 NaCl solution, respectively. The ST joints disclosed the lower pitting potential of −105, −425, and −505 mV in pH-4, pH-7, and pH-11 NaCl solution, respectively, whereas the STA joints revealed greater pitting potential of −425, −600, and −700 mV in pH-4, pH-7, and pH-11 NaCl solution, respectively. The superior corrosion resistance of ST joints compared to AA and STA joints is attributed to the dissolution of precipitates in Al solid solution resulting in a lower potential difference in FZ. This minimizes the preferential sites for pitting corrosion to occur.
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spelling doaj.art-4eb1d1104e64465787699e66f25345202022-12-22T04:06:33ZengHindawi LimitedAdvances in Materials Science and Engineering1687-84422022-01-01202210.1155/2022/4874834Potentiodynamic Corrosion Behavior and Microstructural Characteristics of Pulsed CMT-Welded AA2014-T6 Aluminium Alloy Joints: Effect of PWHTA. Padma Rao0Manzoor Hadi1C. Rajendran2Sonar Tushar3Mikhail Ivanov4P. Senthil Kumar5V. Murali Krishna6Department of Mechanical EngineeringDepartment of Mechanical EngineeringDepartment of Mechanical EngineeringDepartment of Welding EngineeringDepartment of Welding EngineeringDepartment of Mechanical EngineeringDepartment of Mechanical EngineeringAA2014-T6 is an Al-Cu-Mg-based precipitation-hardened aluminium alloy widely used in aerospace due to its high strength to weight ratio. This alloy is joined by a pulsed cold metal transfer (PCMT) arc welding process to overcome the high heat input related problems in gas metal arc welding (GMAW) such as a coarser dendritic structure in the fusion zone (FZ), wider heat affected zone (HAZ), solidification and HAZ liquation cracking, softening in HAZ, and poor corrosion resistance of welded joints in salt environment. The joints were subjected to PWHT of artificial aging (AA), solution treatment (ST), and solution treatment + aging (STA) conditions. The corrosion rate was determined using a potentiodynamic corrosion test in a solution of 3.56 wt.% NaCl with pH values of 4, 7, and 11. Results disclosed that the PCMT joints subjected to the potentiodynamic corrosion test in NaCl solution of pH-4, pH-7, and pH-11 disclosed very low, moderate, and extremely high pitting corrosion, respectively. The corrosion resistance of ST joints was improved by 53.34%, 15%, and 15.12% in pH-4, pH-7, and pH-11 NaCl solution compared to as-welded joints. The pitting potential of ST joints is comparable to BM. The BM showed the pitting potential of −175, −450, and −550 mV in pH-4, pH-7, and pH-11 NaCl solution. The ST joints showed 75.29%, 29.16%, and 27.85% lower corrosion potential compared to STA joints in pH-4, pH-7, and pH-11 NaCl solution, respectively. The ST joints disclosed the lower pitting potential of −105, −425, and −505 mV in pH-4, pH-7, and pH-11 NaCl solution, respectively, whereas the STA joints revealed greater pitting potential of −425, −600, and −700 mV in pH-4, pH-7, and pH-11 NaCl solution, respectively. The superior corrosion resistance of ST joints compared to AA and STA joints is attributed to the dissolution of precipitates in Al solid solution resulting in a lower potential difference in FZ. This minimizes the preferential sites for pitting corrosion to occur.http://dx.doi.org/10.1155/2022/4874834
spellingShingle A. Padma Rao
Manzoor Hadi
C. Rajendran
Sonar Tushar
Mikhail Ivanov
P. Senthil Kumar
V. Murali Krishna
Potentiodynamic Corrosion Behavior and Microstructural Characteristics of Pulsed CMT-Welded AA2014-T6 Aluminium Alloy Joints: Effect of PWHT
Advances in Materials Science and Engineering
title Potentiodynamic Corrosion Behavior and Microstructural Characteristics of Pulsed CMT-Welded AA2014-T6 Aluminium Alloy Joints: Effect of PWHT
title_full Potentiodynamic Corrosion Behavior and Microstructural Characteristics of Pulsed CMT-Welded AA2014-T6 Aluminium Alloy Joints: Effect of PWHT
title_fullStr Potentiodynamic Corrosion Behavior and Microstructural Characteristics of Pulsed CMT-Welded AA2014-T6 Aluminium Alloy Joints: Effect of PWHT
title_full_unstemmed Potentiodynamic Corrosion Behavior and Microstructural Characteristics of Pulsed CMT-Welded AA2014-T6 Aluminium Alloy Joints: Effect of PWHT
title_short Potentiodynamic Corrosion Behavior and Microstructural Characteristics of Pulsed CMT-Welded AA2014-T6 Aluminium Alloy Joints: Effect of PWHT
title_sort potentiodynamic corrosion behavior and microstructural characteristics of pulsed cmt welded aa2014 t6 aluminium alloy joints effect of pwht
url http://dx.doi.org/10.1155/2022/4874834
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