BaMnII2MnIII(PO4)3
The title compound, barium trimanganese tris(orthophosphate), was synthesized hydrothermally. Its structure is isotypic with the lead and strontium analogues AMnII2MnIII(PO4)3 (A = Pb, Sr). Except for two O atoms on general positions, all atoms are located on special positions. The Ba and one P atom...
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2013-09-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813023106 |
| _version_ | 1819002688077037568 |
|---|---|
| author | Abderrazzak Assani Mohamed Saadi Ghaleb Alhakmi Elham Houmadi Lahcen El Ammari |
| author_facet | Abderrazzak Assani Mohamed Saadi Ghaleb Alhakmi Elham Houmadi Lahcen El Ammari |
| author_sort | Abderrazzak Assani |
| collection | DOAJ |
| description | The title compound, barium trimanganese tris(orthophosphate), was synthesized hydrothermally. Its structure is isotypic with the lead and strontium analogues AMnII2MnIII(PO4)3 (A = Pb, Sr). Except for two O atoms on general positions, all atoms are located on special positions. The Ba and one P atom exhibit mm2 symmetry, the MnII atom 2/m symmetry, the MnIII atom and the other P atom .2. symmetry and two O atoms are located on mirror planes. The crystal structure contains two types of chains running parallel to [010]. One chain is linear and is composed of alternating MnIIIO6 octahedra and PO4 tetrahedra sharing vertices; the other chain has a zigzag arrangement and is built up from two edge-sharing MnIIO6 octahedra connected to PO4 tetrahedra by edges and vertices. The two types of chains are linked through PO4 tetrahedra into an open three-dimensional framework which contains channels parallel to [100] and [010] in which the BaII ions are located. The alkaline earth cation is surrounded by eight O atoms in the form of a slightly distorted bicapped trigonal prism. |
| first_indexed | 2024-12-20T23:09:05Z |
| format | Article |
| id | doaj.art-4ebfb218ff7e42a1844307eee156afdf |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T23:09:05Z |
| publishDate | 2013-09-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-4ebfb218ff7e42a1844307eee156afdf2022-12-21T19:23:47ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-09-01699i60i6010.1107/S1600536813023106BaMnII2MnIII(PO4)3Abderrazzak AssaniMohamed SaadiGhaleb AlhakmiElham HoumadiLahcen El AmmariThe title compound, barium trimanganese tris(orthophosphate), was synthesized hydrothermally. Its structure is isotypic with the lead and strontium analogues AMnII2MnIII(PO4)3 (A = Pb, Sr). Except for two O atoms on general positions, all atoms are located on special positions. The Ba and one P atom exhibit mm2 symmetry, the MnII atom 2/m symmetry, the MnIII atom and the other P atom .2. symmetry and two O atoms are located on mirror planes. The crystal structure contains two types of chains running parallel to [010]. One chain is linear and is composed of alternating MnIIIO6 octahedra and PO4 tetrahedra sharing vertices; the other chain has a zigzag arrangement and is built up from two edge-sharing MnIIO6 octahedra connected to PO4 tetrahedra by edges and vertices. The two types of chains are linked through PO4 tetrahedra into an open three-dimensional framework which contains channels parallel to [100] and [010] in which the BaII ions are located. The alkaline earth cation is surrounded by eight O atoms in the form of a slightly distorted bicapped trigonal prism.http://scripts.iucr.org/cgi-bin/paper?S1600536813023106 |
| spellingShingle | Abderrazzak Assani Mohamed Saadi Ghaleb Alhakmi Elham Houmadi Lahcen El Ammari BaMnII2MnIII(PO4)3 Acta Crystallographica Section E |
| title | BaMnII2MnIII(PO4)3 |
| title_full | BaMnII2MnIII(PO4)3 |
| title_fullStr | BaMnII2MnIII(PO4)3 |
| title_full_unstemmed | BaMnII2MnIII(PO4)3 |
| title_short | BaMnII2MnIII(PO4)3 |
| title_sort | bamnii2mniii po4 3 |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536813023106 |
| work_keys_str_mv | AT abderrazzakassani bamnii2mniiipo43 AT mohamedsaadi bamnii2mniiipo43 AT ghalebalhakmi bamnii2mniiipo43 AT elhamhoumadi bamnii2mniiipo43 AT lahcenelammari bamnii2mniiipo43 |