Air-Flow Impacting: A New Mechanochemical Method for Continuous, Highly Efficient, Large-Scale Synthesis of Metal–Organic Frameworks and Mechanistic Research
The novel air-flow impacting (AFI) synthesis technology for mechanochemical synthesis of MOFs (ZIF-67) was first reported. AFI was an improvement of the traditional mechanochemical synthesis method. The results indicated that ZIF-67 was successfully synthesized after 30 min at a rate of 60 kg h−1. T...
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| Format: | Article |
| Language: | English |
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Frontiers Media S.A.
2021-12-01
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| Series: | Frontiers in Materials |
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| Online Access: | https://www.frontiersin.org/articles/10.3389/fmats.2021.800820/full |
| _version_ | 1831755238130843648 |
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| author | Jun Zhao Jun Zhao |
| author_facet | Jun Zhao Jun Zhao |
| author_sort | Jun Zhao |
| collection | DOAJ |
| description | The novel air-flow impacting (AFI) synthesis technology for mechanochemical synthesis of MOFs (ZIF-67) was first reported. AFI was an improvement of the traditional mechanochemical synthesis method. The results indicated that ZIF-67 was successfully synthesized after 30 min at a rate of 60 kg h−1. The as-prepared ZIF-67 was characterized by Fourier transform infrared spectroscopy (FT-IR), powder x-ray diffraction (P-XRD), thermogravimetric analysis (DTA/TG), scanning electron microscope (SEM), transmission electron microscope (TEM), and single-crystal x-ray diffraction. The kinetic analysis of the reaction mechanism was carried out by detecting the P-XRD patterns of the products with different reaction times. The synthesis belonged to the one-dimensional diffusion-controlled model. |
| first_indexed | 2024-12-21T23:52:11Z |
| format | Article |
| id | doaj.art-4ef0fcd26e724af1b5dd895e6fb2325d |
| institution | Directory Open Access Journal |
| issn | 2296-8016 |
| language | English |
| last_indexed | 2024-12-21T23:52:11Z |
| publishDate | 2021-12-01 |
| publisher | Frontiers Media S.A. |
| record_format | Article |
| series | Frontiers in Materials |
| spelling | doaj.art-4ef0fcd26e724af1b5dd895e6fb2325d2022-12-21T18:45:54ZengFrontiers Media S.A.Frontiers in Materials2296-80162021-12-01810.3389/fmats.2021.800820800820Air-Flow Impacting: A New Mechanochemical Method for Continuous, Highly Efficient, Large-Scale Synthesis of Metal–Organic Frameworks and Mechanistic ResearchJun Zhao0Jun Zhao1State Key Laboratory of Environment-friendly Energy Materials, Southwest University of Science and Technology, Mianyang, ChinaSichuan College of Architecture and Technology, Deyang, ChinaThe novel air-flow impacting (AFI) synthesis technology for mechanochemical synthesis of MOFs (ZIF-67) was first reported. AFI was an improvement of the traditional mechanochemical synthesis method. The results indicated that ZIF-67 was successfully synthesized after 30 min at a rate of 60 kg h−1. The as-prepared ZIF-67 was characterized by Fourier transform infrared spectroscopy (FT-IR), powder x-ray diffraction (P-XRD), thermogravimetric analysis (DTA/TG), scanning electron microscope (SEM), transmission electron microscope (TEM), and single-crystal x-ray diffraction. The kinetic analysis of the reaction mechanism was carried out by detecting the P-XRD patterns of the products with different reaction times. The synthesis belonged to the one-dimensional diffusion-controlled model.https://www.frontiersin.org/articles/10.3389/fmats.2021.800820/fullair-flow impactingmetal–organic frameworkssolid-phase synthesisZIF-67 crystalpreparation mechanism |
| spellingShingle | Jun Zhao Jun Zhao Air-Flow Impacting: A New Mechanochemical Method for Continuous, Highly Efficient, Large-Scale Synthesis of Metal–Organic Frameworks and Mechanistic Research Frontiers in Materials air-flow impacting metal–organic frameworks solid-phase synthesis ZIF-67 crystal preparation mechanism |
| title | Air-Flow Impacting: A New Mechanochemical Method for Continuous, Highly Efficient, Large-Scale Synthesis of Metal–Organic Frameworks and Mechanistic Research |
| title_full | Air-Flow Impacting: A New Mechanochemical Method for Continuous, Highly Efficient, Large-Scale Synthesis of Metal–Organic Frameworks and Mechanistic Research |
| title_fullStr | Air-Flow Impacting: A New Mechanochemical Method for Continuous, Highly Efficient, Large-Scale Synthesis of Metal–Organic Frameworks and Mechanistic Research |
| title_full_unstemmed | Air-Flow Impacting: A New Mechanochemical Method for Continuous, Highly Efficient, Large-Scale Synthesis of Metal–Organic Frameworks and Mechanistic Research |
| title_short | Air-Flow Impacting: A New Mechanochemical Method for Continuous, Highly Efficient, Large-Scale Synthesis of Metal–Organic Frameworks and Mechanistic Research |
| title_sort | air flow impacting a new mechanochemical method for continuous highly efficient large scale synthesis of metal organic frameworks and mechanistic research |
| topic | air-flow impacting metal–organic frameworks solid-phase synthesis ZIF-67 crystal preparation mechanism |
| url | https://www.frontiersin.org/articles/10.3389/fmats.2021.800820/full |
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