Nitric acid in the stratosphere based on Odin observations from 2001 to 2009 – Part 2: High-altitude polar enhancements

The wintertime abundance of nitric acid (HNO<sub>3</sub>) in the polar upper stratosphere displays a strong inter-annual variability, and is known to be strongly influenced by energetic particle precipitation (EPP), primarily by protons during solar proton events (SPEs),...

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Main Authors: Y. J. Orsolini, J. Urban, D. P. Murtagh
Format: Article
Language:English
Published: Copernicus Publications 2009-09-01
Series:Atmospheric Chemistry and Physics
Online Access:http://www.atmos-chem-phys.net/9/7045/2009/acp-9-7045-2009.pdf
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author Y. J. Orsolini
J. Urban
D. P. Murtagh
author_facet Y. J. Orsolini
J. Urban
D. P. Murtagh
author_sort Y. J. Orsolini
collection DOAJ
description The wintertime abundance of nitric acid (HNO<sub>3</sub>) in the polar upper stratosphere displays a strong inter-annual variability, and is known to be strongly influenced by energetic particle precipitation (EPP), primarily by protons during solar proton events (SPEs), but also by precipitating auroral or relativistic electrons. We analyse a multi-year record (August 2001 to April 2009) of middle atmospheric HNO<sub>3</sub> measurements by the Sub-Millimeter Radiometer instrument aboard the Odin satellite, with a focus on the polar upper stratosphere. SMR observations show clear evidence of two different types of polar high-altitude HNO<sub>3</sub> enhancements linked to EPP. In the first type, referred to as direct enhancements by analogy with the EPP/NO<sub>x</sub> direct effect, enhanced HNO<sub>3</sub> mixing ratios are observed for a short period (1 week) after a SPE, upwards of a level typically in the mid-stratosphere. In a second type, referred to as indirect enhancements by analogy with the EPP/NO<sub>x</sub> indirect effect, the descent of mesospheric air triggers a stronger and longer-lasting enhancement. Each of the three major SPEs that occurred during the Northern Hemisphere autumn or winter, in November 2001, October–November 2003 and January 2005, are observed to lead to both direct and indirect HNO<sub>3</sub> enhancements. On the other hand, indirect enhancements occur recurrently in winter, are stronger in the Southern Hemisphere, and are influenced by EPP at higher altitudes.
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spelling doaj.art-4ef48f240add48c387fd82361b0fc8b32022-12-21T20:44:32ZengCopernicus PublicationsAtmospheric Chemistry and Physics1680-73161680-73242009-09-0191870457052Nitric acid in the stratosphere based on Odin observations from 2001 to 2009 – Part 2: High-altitude polar enhancementsY. J. OrsoliniJ. UrbanD. P. MurtaghThe wintertime abundance of nitric acid (HNO<sub>3</sub>) in the polar upper stratosphere displays a strong inter-annual variability, and is known to be strongly influenced by energetic particle precipitation (EPP), primarily by protons during solar proton events (SPEs), but also by precipitating auroral or relativistic electrons. We analyse a multi-year record (August 2001 to April 2009) of middle atmospheric HNO<sub>3</sub> measurements by the Sub-Millimeter Radiometer instrument aboard the Odin satellite, with a focus on the polar upper stratosphere. SMR observations show clear evidence of two different types of polar high-altitude HNO<sub>3</sub> enhancements linked to EPP. In the first type, referred to as direct enhancements by analogy with the EPP/NO<sub>x</sub> direct effect, enhanced HNO<sub>3</sub> mixing ratios are observed for a short period (1 week) after a SPE, upwards of a level typically in the mid-stratosphere. In a second type, referred to as indirect enhancements by analogy with the EPP/NO<sub>x</sub> indirect effect, the descent of mesospheric air triggers a stronger and longer-lasting enhancement. Each of the three major SPEs that occurred during the Northern Hemisphere autumn or winter, in November 2001, October–November 2003 and January 2005, are observed to lead to both direct and indirect HNO<sub>3</sub> enhancements. On the other hand, indirect enhancements occur recurrently in winter, are stronger in the Southern Hemisphere, and are influenced by EPP at higher altitudes.http://www.atmos-chem-phys.net/9/7045/2009/acp-9-7045-2009.pdf
spellingShingle Y. J. Orsolini
J. Urban
D. P. Murtagh
Nitric acid in the stratosphere based on Odin observations from 2001 to 2009 – Part 2: High-altitude polar enhancements
Atmospheric Chemistry and Physics
title Nitric acid in the stratosphere based on Odin observations from 2001 to 2009 – Part 2: High-altitude polar enhancements
title_full Nitric acid in the stratosphere based on Odin observations from 2001 to 2009 – Part 2: High-altitude polar enhancements
title_fullStr Nitric acid in the stratosphere based on Odin observations from 2001 to 2009 – Part 2: High-altitude polar enhancements
title_full_unstemmed Nitric acid in the stratosphere based on Odin observations from 2001 to 2009 – Part 2: High-altitude polar enhancements
title_short Nitric acid in the stratosphere based on Odin observations from 2001 to 2009 – Part 2: High-altitude polar enhancements
title_sort nitric acid in the stratosphere based on odin observations from 2001 to 2009 part 2 high altitude polar enhancements
url http://www.atmos-chem-phys.net/9/7045/2009/acp-9-7045-2009.pdf
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