Permeability and Adsorption–Desorption Behavior of Rare Earth in Laboratory Leaching Tests

In order to investigate the influence of the ion exchange process on the permeability of rare earth ore bodies in the leaching process, a laboratory-scale comparative experiment with ammonium sulfate solution and deionized (DI) water as leaching solutions is conducted. Compared with the DI water lea...

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Main Authors: Xiaojun Wang, Hao Wang, Can Sui, Lingbo Zhou, Xiao Feng, Chengguang Huang, Kui Zhao, Wen Zhong, Kaijian Hu
Format: Article
Language:English
Published: MDPI AG 2020-10-01
Series:Minerals
Subjects:
Online Access:https://www.mdpi.com/2075-163X/10/10/889
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author Xiaojun Wang
Hao Wang
Can Sui
Lingbo Zhou
Xiao Feng
Chengguang Huang
Kui Zhao
Wen Zhong
Kaijian Hu
author_facet Xiaojun Wang
Hao Wang
Can Sui
Lingbo Zhou
Xiao Feng
Chengguang Huang
Kui Zhao
Wen Zhong
Kaijian Hu
author_sort Xiaojun Wang
collection DOAJ
description In order to investigate the influence of the ion exchange process on the permeability of rare earth ore bodies in the leaching process, a laboratory-scale comparative experiment with ammonium sulfate solution and deionized (DI) water as leaching solutions is conducted. Compared with the DI water leaching test, the permeability coefficient of the rare earth ore sample leached by the ammonium sulfate solution gradually decreases at the beginning and then increases with the completion of leaching. The physical and morphological evolutions of rare earth ore samples in this comparative experiment are also monitored by nuclear magnetic resonance and scanning electron microscopy. It is concluded that the change in the permeability coefficient arises from the adsorption–desorption of a large number of clay microparticles, resulting in a dynamic evolution of pore structures. Further mechanism analysis suggests that the change in internal ionic strength caused by ion exchange and leaching solution seepage promotes the adsorption–desorption behavior of clay microparticles.
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spelling doaj.art-4ef4d0a7ee854434b5aef0a8c0bd39702023-11-20T16:19:08ZengMDPI AGMinerals2075-163X2020-10-01101088910.3390/min10100889Permeability and Adsorption–Desorption Behavior of Rare Earth in Laboratory Leaching TestsXiaojun Wang0Hao Wang1Can Sui2Lingbo Zhou3Xiao Feng4Chengguang Huang5Kui Zhao6Wen Zhong7Kaijian Hu8Jiangxi Key Laboratory of Mining Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, ChinaJiangxi Key Laboratory of Mining Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, ChinaJiangxi Key Laboratory of Mining Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, ChinaJiangxi Key Laboratory of Mining Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, ChinaJiangxi Key Laboratory of Mining Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, ChinaJiangxi Key Laboratory of Mining Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, ChinaJiangxi Key Laboratory of Mining Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, ChinaJiangxi Key Laboratory of Mining Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, ChinaJiangxi Key Laboratory of Mining Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, ChinaIn order to investigate the influence of the ion exchange process on the permeability of rare earth ore bodies in the leaching process, a laboratory-scale comparative experiment with ammonium sulfate solution and deionized (DI) water as leaching solutions is conducted. Compared with the DI water leaching test, the permeability coefficient of the rare earth ore sample leached by the ammonium sulfate solution gradually decreases at the beginning and then increases with the completion of leaching. The physical and morphological evolutions of rare earth ore samples in this comparative experiment are also monitored by nuclear magnetic resonance and scanning electron microscopy. It is concluded that the change in the permeability coefficient arises from the adsorption–desorption of a large number of clay microparticles, resulting in a dynamic evolution of pore structures. Further mechanism analysis suggests that the change in internal ionic strength caused by ion exchange and leaching solution seepage promotes the adsorption–desorption behavior of clay microparticles.https://www.mdpi.com/2075-163X/10/10/889permeabilityadsorption–desorptionrare earthion exchangeleaching
spellingShingle Xiaojun Wang
Hao Wang
Can Sui
Lingbo Zhou
Xiao Feng
Chengguang Huang
Kui Zhao
Wen Zhong
Kaijian Hu
Permeability and Adsorption–Desorption Behavior of Rare Earth in Laboratory Leaching Tests
Minerals
permeability
adsorption–desorption
rare earth
ion exchange
leaching
title Permeability and Adsorption–Desorption Behavior of Rare Earth in Laboratory Leaching Tests
title_full Permeability and Adsorption–Desorption Behavior of Rare Earth in Laboratory Leaching Tests
title_fullStr Permeability and Adsorption–Desorption Behavior of Rare Earth in Laboratory Leaching Tests
title_full_unstemmed Permeability and Adsorption–Desorption Behavior of Rare Earth in Laboratory Leaching Tests
title_short Permeability and Adsorption–Desorption Behavior of Rare Earth in Laboratory Leaching Tests
title_sort permeability and adsorption desorption behavior of rare earth in laboratory leaching tests
topic permeability
adsorption–desorption
rare earth
ion exchange
leaching
url https://www.mdpi.com/2075-163X/10/10/889
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