Elaboration of High Permeable Macrovoid Free Polysulfone Hollow Fiber Membranes for Air Separation

In this work, polysulfone hollow fibers with oxygen permeance 70 L (STP)/(m<sup>2</sup>&#183;h&#183;bar) and selectivity &#945;(O<sub>2</sub>/N<sub>2</sub>) = 6 were obtained. A decrease in the dope solution temperature allowed to diminish macrovoids d...

Full description

Bibliographic Details
Main Authors: George Dibrov, Mikhail Ivanov, Mikhail Semyashkin, Vladislav Sudin, Nikita Fateev, George Kagramanov
Format: Article
Language:English
Published: MDPI AG 2019-05-01
Series:Fibers
Subjects:
Online Access:https://www.mdpi.com/2079-6439/7/5/43
_version_ 1811279167474368512
author George Dibrov
Mikhail Ivanov
Mikhail Semyashkin
Vladislav Sudin
Nikita Fateev
George Kagramanov
author_facet George Dibrov
Mikhail Ivanov
Mikhail Semyashkin
Vladislav Sudin
Nikita Fateev
George Kagramanov
author_sort George Dibrov
collection DOAJ
description In this work, polysulfone hollow fibers with oxygen permeance 70 L (STP)/(m<sup>2</sup>&#183;h&#183;bar) and selectivity &#945;(O<sub>2</sub>/N<sub>2</sub>) = 6 were obtained. A decrease in the dope solution temperature allowed to diminish macrovoids due to the increase of the dope viscosity from 15.5 Pa&#183;s at 62 &#176;C to 35 Pa&#183;s at 25 &#176;C. To reduce the fiber diameter, thereby increasing the packing density, they were spun at high linear velocities. A hollow fiber membrane element was produced with effective membrane area 2.75 m<sup>2</sup> and packing density 53%. Its air separation performance was evaluated to bridge laboratory studies and practical application.
first_indexed 2024-04-13T00:49:48Z
format Article
id doaj.art-4efb6e33e0ac418f91d5bb70e6fbe1b6
institution Directory Open Access Journal
issn 2079-6439
language English
last_indexed 2024-04-13T00:49:48Z
publishDate 2019-05-01
publisher MDPI AG
record_format Article
series Fibers
spelling doaj.art-4efb6e33e0ac418f91d5bb70e6fbe1b62022-12-22T03:09:54ZengMDPI AGFibers2079-64392019-05-01754310.3390/fib7050043fib7050043Elaboration of High Permeable Macrovoid Free Polysulfone Hollow Fiber Membranes for Air SeparationGeorge Dibrov0Mikhail Ivanov1Mikhail Semyashkin2Vladislav Sudin3Nikita Fateev4George Kagramanov5D.Mendeleev University of Chemical Technology of Russia, 125047 Moscow, RussiaD.Mendeleev University of Chemical Technology of Russia, 125047 Moscow, RussiaD.Mendeleev University of Chemical Technology of Russia, 125047 Moscow, RussiaBaikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences, 119991 Moscow, RussiaD.Mendeleev University of Chemical Technology of Russia, 125047 Moscow, RussiaD.Mendeleev University of Chemical Technology of Russia, 125047 Moscow, RussiaIn this work, polysulfone hollow fibers with oxygen permeance 70 L (STP)/(m<sup>2</sup>&#183;h&#183;bar) and selectivity &#945;(O<sub>2</sub>/N<sub>2</sub>) = 6 were obtained. A decrease in the dope solution temperature allowed to diminish macrovoids due to the increase of the dope viscosity from 15.5 Pa&#183;s at 62 &#176;C to 35 Pa&#183;s at 25 &#176;C. To reduce the fiber diameter, thereby increasing the packing density, they were spun at high linear velocities. A hollow fiber membrane element was produced with effective membrane area 2.75 m<sup>2</sup> and packing density 53%. Its air separation performance was evaluated to bridge laboratory studies and practical application.https://www.mdpi.com/2079-6439/7/5/43hollow fiber membranespolysulfoneairgas separationnitrogen
spellingShingle George Dibrov
Mikhail Ivanov
Mikhail Semyashkin
Vladislav Sudin
Nikita Fateev
George Kagramanov
Elaboration of High Permeable Macrovoid Free Polysulfone Hollow Fiber Membranes for Air Separation
Fibers
hollow fiber membranes
polysulfone
air
gas separation
nitrogen
title Elaboration of High Permeable Macrovoid Free Polysulfone Hollow Fiber Membranes for Air Separation
title_full Elaboration of High Permeable Macrovoid Free Polysulfone Hollow Fiber Membranes for Air Separation
title_fullStr Elaboration of High Permeable Macrovoid Free Polysulfone Hollow Fiber Membranes for Air Separation
title_full_unstemmed Elaboration of High Permeable Macrovoid Free Polysulfone Hollow Fiber Membranes for Air Separation
title_short Elaboration of High Permeable Macrovoid Free Polysulfone Hollow Fiber Membranes for Air Separation
title_sort elaboration of high permeable macrovoid free polysulfone hollow fiber membranes for air separation
topic hollow fiber membranes
polysulfone
air
gas separation
nitrogen
url https://www.mdpi.com/2079-6439/7/5/43
work_keys_str_mv AT georgedibrov elaborationofhighpermeablemacrovoidfreepolysulfonehollowfibermembranesforairseparation
AT mikhailivanov elaborationofhighpermeablemacrovoidfreepolysulfonehollowfibermembranesforairseparation
AT mikhailsemyashkin elaborationofhighpermeablemacrovoidfreepolysulfonehollowfibermembranesforairseparation
AT vladislavsudin elaborationofhighpermeablemacrovoidfreepolysulfonehollowfibermembranesforairseparation
AT nikitafateev elaborationofhighpermeablemacrovoidfreepolysulfonehollowfibermembranesforairseparation
AT georgekagramanov elaborationofhighpermeablemacrovoidfreepolysulfonehollowfibermembranesforairseparation