Elaboration of High Permeable Macrovoid Free Polysulfone Hollow Fiber Membranes for Air Separation
In this work, polysulfone hollow fibers with oxygen permeance 70 L (STP)/(m<sup>2</sup>·h·bar) and selectivity α(O<sub>2</sub>/N<sub>2</sub>) = 6 were obtained. A decrease in the dope solution temperature allowed to diminish macrovoids d...
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MDPI AG
2019-05-01
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Series: | Fibers |
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Online Access: | https://www.mdpi.com/2079-6439/7/5/43 |
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author | George Dibrov Mikhail Ivanov Mikhail Semyashkin Vladislav Sudin Nikita Fateev George Kagramanov |
author_facet | George Dibrov Mikhail Ivanov Mikhail Semyashkin Vladislav Sudin Nikita Fateev George Kagramanov |
author_sort | George Dibrov |
collection | DOAJ |
description | In this work, polysulfone hollow fibers with oxygen permeance 70 L (STP)/(m<sup>2</sup>·h·bar) and selectivity α(O<sub>2</sub>/N<sub>2</sub>) = 6 were obtained. A decrease in the dope solution temperature allowed to diminish macrovoids due to the increase of the dope viscosity from 15.5 Pa·s at 62 °C to 35 Pa·s at 25 °C. To reduce the fiber diameter, thereby increasing the packing density, they were spun at high linear velocities. A hollow fiber membrane element was produced with effective membrane area 2.75 m<sup>2</sup> and packing density 53%. Its air separation performance was evaluated to bridge laboratory studies and practical application. |
first_indexed | 2024-04-13T00:49:48Z |
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id | doaj.art-4efb6e33e0ac418f91d5bb70e6fbe1b6 |
institution | Directory Open Access Journal |
issn | 2079-6439 |
language | English |
last_indexed | 2024-04-13T00:49:48Z |
publishDate | 2019-05-01 |
publisher | MDPI AG |
record_format | Article |
series | Fibers |
spelling | doaj.art-4efb6e33e0ac418f91d5bb70e6fbe1b62022-12-22T03:09:54ZengMDPI AGFibers2079-64392019-05-01754310.3390/fib7050043fib7050043Elaboration of High Permeable Macrovoid Free Polysulfone Hollow Fiber Membranes for Air SeparationGeorge Dibrov0Mikhail Ivanov1Mikhail Semyashkin2Vladislav Sudin3Nikita Fateev4George Kagramanov5D.Mendeleev University of Chemical Technology of Russia, 125047 Moscow, RussiaD.Mendeleev University of Chemical Technology of Russia, 125047 Moscow, RussiaD.Mendeleev University of Chemical Technology of Russia, 125047 Moscow, RussiaBaikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences, 119991 Moscow, RussiaD.Mendeleev University of Chemical Technology of Russia, 125047 Moscow, RussiaD.Mendeleev University of Chemical Technology of Russia, 125047 Moscow, RussiaIn this work, polysulfone hollow fibers with oxygen permeance 70 L (STP)/(m<sup>2</sup>·h·bar) and selectivity α(O<sub>2</sub>/N<sub>2</sub>) = 6 were obtained. A decrease in the dope solution temperature allowed to diminish macrovoids due to the increase of the dope viscosity from 15.5 Pa·s at 62 °C to 35 Pa·s at 25 °C. To reduce the fiber diameter, thereby increasing the packing density, they were spun at high linear velocities. A hollow fiber membrane element was produced with effective membrane area 2.75 m<sup>2</sup> and packing density 53%. Its air separation performance was evaluated to bridge laboratory studies and practical application.https://www.mdpi.com/2079-6439/7/5/43hollow fiber membranespolysulfoneairgas separationnitrogen |
spellingShingle | George Dibrov Mikhail Ivanov Mikhail Semyashkin Vladislav Sudin Nikita Fateev George Kagramanov Elaboration of High Permeable Macrovoid Free Polysulfone Hollow Fiber Membranes for Air Separation Fibers hollow fiber membranes polysulfone air gas separation nitrogen |
title | Elaboration of High Permeable Macrovoid Free Polysulfone Hollow Fiber Membranes for Air Separation |
title_full | Elaboration of High Permeable Macrovoid Free Polysulfone Hollow Fiber Membranes for Air Separation |
title_fullStr | Elaboration of High Permeable Macrovoid Free Polysulfone Hollow Fiber Membranes for Air Separation |
title_full_unstemmed | Elaboration of High Permeable Macrovoid Free Polysulfone Hollow Fiber Membranes for Air Separation |
title_short | Elaboration of High Permeable Macrovoid Free Polysulfone Hollow Fiber Membranes for Air Separation |
title_sort | elaboration of high permeable macrovoid free polysulfone hollow fiber membranes for air separation |
topic | hollow fiber membranes polysulfone air gas separation nitrogen |
url | https://www.mdpi.com/2079-6439/7/5/43 |
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