Oxide Materials for Thermoelectric Conversion

Thermoelectric technology has emerged as a prominent area of research in the past few decades for harnessing waste heat and improving the efficiency of next-generation renewable energy technologies. There has been rapid progress in the development of high-performance thermoelectric materials, as mea...

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Bibliographic Details
Main Authors: Yucen Liu, Jun Zhi, Wannuo Li, Qian Yang, Long Zhang, Yuqiao Zhang
Format: Article
Language:English
Published: MDPI AG 2023-08-01
Series:Molecules
Subjects:
Online Access:https://www.mdpi.com/1420-3049/28/15/5894
Description
Summary:Thermoelectric technology has emerged as a prominent area of research in the past few decades for harnessing waste heat and improving the efficiency of next-generation renewable energy technologies. There has been rapid progress in the development of high-performance thermoelectric materials, as measured by the dimensionless figure of merit (<i>ZT</i> = <i>S</i><sup>2</sup> · <i>σ</i> · <i>κ</i><sup>−1</sup>). Several heavy-metal-based thermoelectric materials with commercial-level performance (<i>ZT</i> = 1) have so far been proposed. However, the extensive application of these materials still faces challenges due to their low thermal/chemical stability, high toxicity, and limited abundance in the Earth’s crust. In contrast, oxide-based thermoelectric materials, such as ZnO, SrTiO<sub>3</sub>, layered cobalt oxides, etc., have attracted growing interest as they can overcome the limitations of their heavy-metal-based counterparts. In this review, we summarize the recent research progress and introduce improvement strategies in oxide-based thermoelectric materials. This will provide an overview of their development history and design schemes, ultimately aiding in enhancing the overall performance of oxide-based thermoelectric materials.
ISSN:1420-3049