Synthesis of Polyurethane Based on (Resol Novolac Resin- Polyethylene Glycol) Copolymer and Their Analytical Study
Resol novolac resin was prepared by condensation of novolac resin with formalin solution in the presence of sodium hydroxide as catalyst, then new copolymer were prepared by reaction of this resin with polyethylene glycol. This new copolymer was supported on polyurethane foam as solid phase and app...
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| Format: | Article |
| Language: | English |
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University of Kufa
2019-07-01
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| Series: | Journal of Kufa-Physics |
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| Online Access: | https://journal.uokufa.edu.iq/index.php/jkp/article/view/7218 |
| _version_ | 1797260470967599104 |
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| author | Maiada Abdulaa Adnan |
| author_facet | Maiada Abdulaa Adnan |
| author_sort | Maiada Abdulaa Adnan |
| collection | DOAJ |
| description |
Resol novolac resin was prepared by condensation of novolac resin with formalin solution in the presence of sodium hydroxide as catalyst, then new copolymer were prepared by reaction of this resin with polyethylene glycol. This new copolymer was supported on polyurethane foam as solid phase and applied to separation a mixture of Cr(III) and Cd(II) ions from aqueous solutions prior to the determination by flame atomic absorbtion spectrometry. The optimum conditions of some parameters effect on recovery of the ions such as acidity, eluent condition, shaking time, and eluent flow rate were investigated. At pH 4,5, the maximum recovery (90%) of Cd(II) by stripping with 40 ml of (1N) nitric acid ,while for Cu (11) was 80 % with 50 mL of (2N) nitric acid .On the other hand thermal stability for the prepared polyurethane was evaluated by TGA.
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| first_indexed | 2024-04-24T23:25:51Z |
| format | Article |
| id | doaj.art-4f3ea50771764ecf80683bc0cd00ddfe |
| institution | Directory Open Access Journal |
| issn | 2077-5830 2312-6671 |
| language | English |
| last_indexed | 2024-04-24T23:25:51Z |
| publishDate | 2019-07-01 |
| publisher | University of Kufa |
| record_format | Article |
| series | Journal of Kufa-Physics |
| spelling | doaj.art-4f3ea50771764ecf80683bc0cd00ddfe2024-03-16T01:16:08ZengUniversity of KufaJournal of Kufa-Physics2077-58302312-66712019-07-0111110.31257/2018/JKP/2019/110118Synthesis of Polyurethane Based on (Resol Novolac Resin- Polyethylene Glycol) Copolymer and Their Analytical StudyMaiada Abdulaa Adnan Resol novolac resin was prepared by condensation of novolac resin with formalin solution in the presence of sodium hydroxide as catalyst, then new copolymer were prepared by reaction of this resin with polyethylene glycol. This new copolymer was supported on polyurethane foam as solid phase and applied to separation a mixture of Cr(III) and Cd(II) ions from aqueous solutions prior to the determination by flame atomic absorbtion spectrometry. The optimum conditions of some parameters effect on recovery of the ions such as acidity, eluent condition, shaking time, and eluent flow rate were investigated. At pH 4,5, the maximum recovery (90%) of Cd(II) by stripping with 40 ml of (1N) nitric acid ,while for Cu (11) was 80 % with 50 mL of (2N) nitric acid .On the other hand thermal stability for the prepared polyurethane was evaluated by TGA. https://journal.uokufa.edu.iq/index.php/jkp/article/view/7218Resol novolac resin Copolymer Poluurethane Column Chromatography method and TGA |
| spellingShingle | Maiada Abdulaa Adnan Synthesis of Polyurethane Based on (Resol Novolac Resin- Polyethylene Glycol) Copolymer and Their Analytical Study Journal of Kufa-Physics Resol novolac resin Copolymer Poluurethane Column Chromatography method and TGA |
| title | Synthesis of Polyurethane Based on (Resol Novolac Resin- Polyethylene Glycol) Copolymer and Their Analytical Study |
| title_full | Synthesis of Polyurethane Based on (Resol Novolac Resin- Polyethylene Glycol) Copolymer and Their Analytical Study |
| title_fullStr | Synthesis of Polyurethane Based on (Resol Novolac Resin- Polyethylene Glycol) Copolymer and Their Analytical Study |
| title_full_unstemmed | Synthesis of Polyurethane Based on (Resol Novolac Resin- Polyethylene Glycol) Copolymer and Their Analytical Study |
| title_short | Synthesis of Polyurethane Based on (Resol Novolac Resin- Polyethylene Glycol) Copolymer and Their Analytical Study |
| title_sort | synthesis of polyurethane based on resol novolac resin polyethylene glycol copolymer and their analytical study |
| topic | Resol novolac resin Copolymer Poluurethane Column Chromatography method and TGA |
| url | https://journal.uokufa.edu.iq/index.php/jkp/article/view/7218 |
| work_keys_str_mv | AT maiadaabdulaaadnan synthesisofpolyurethanebasedonresolnovolacresinpolyethyleneglycolcopolymerandtheiranalyticalstudy |