A crystallographically isolated dimeric hydrolyzed chlorophosphazene dianion
Single crystals of the title compound bis[bis(1-ethyl-3-methyl-imidazol-2-ylidene)silver(I)] 1,5,5,7,11,11-hexachloro-2,8-dioxa-4,6,10,12,13,14-hexaaza-1λ5,3,5λ5,7λ5,9,11λ5-hexaphosphatricyclo[7.3.1.13,7]tetradeca-1(13),4,7(14),10-tetraene-6,12-diide 3,9-dioxide,...
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-01-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808042116 |
| _version_ | 1818322471293550592 |
|---|---|
| author | Matthew J. Panzner Wiley J. Youngs Claire A. Tessier |
| author_facet | Matthew J. Panzner Wiley J. Youngs Claire A. Tessier |
| author_sort | Matthew J. Panzner |
| collection | DOAJ |
| description | Single crystals of the title compound bis[bis(1-ethyl-3-methyl-imidazol-2-ylidene)silver(I)] 1,5,5,7,11,11-hexachloro-2,8-dioxa-4,6,10,12,13,14-hexaaza-1λ5,3,5λ5,7λ5,9,11λ5-hexaphosphatricyclo[7.3.1.13,7]tetradeca-1(13),4,7(14),10-tetraene-6,12-diide 3,9-dioxide, [Ag(C6H10N2)2](Cl6N6O4P6)0.5, were isolated from the reaction of the silver N-heteocyclic carbene complex [Ag(C6H10N2)2]Cl and hexachlorocyclotriphosphazene [NPCl2]3 in the presence of water. The asymmetric unit contains one silver carbene cation with the carbene ligands bound to the Ag(I) in an almost linear arrangement and one half of a hydrolyzed phosphazene dianion. The second cation and additional half of the anion are generated by an inversion center. |
| first_indexed | 2024-12-13T10:57:19Z |
| format | Article |
| id | doaj.art-4f446997a1ec4c71852cf358ed74c513 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T10:57:19Z |
| publishDate | 2009-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-4f446997a1ec4c71852cf358ed74c5132022-12-21T23:49:26ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-01-01651m105m10510.1107/S1600536808042116A crystallographically isolated dimeric hydrolyzed chlorophosphazene dianionMatthew J. PanznerWiley J. YoungsClaire A. TessierSingle crystals of the title compound bis[bis(1-ethyl-3-methyl-imidazol-2-ylidene)silver(I)] 1,5,5,7,11,11-hexachloro-2,8-dioxa-4,6,10,12,13,14-hexaaza-1λ5,3,5λ5,7λ5,9,11λ5-hexaphosphatricyclo[7.3.1.13,7]tetradeca-1(13),4,7(14),10-tetraene-6,12-diide 3,9-dioxide, [Ag(C6H10N2)2](Cl6N6O4P6)0.5, were isolated from the reaction of the silver N-heteocyclic carbene complex [Ag(C6H10N2)2]Cl and hexachlorocyclotriphosphazene [NPCl2]3 in the presence of water. The asymmetric unit contains one silver carbene cation with the carbene ligands bound to the Ag(I) in an almost linear arrangement and one half of a hydrolyzed phosphazene dianion. The second cation and additional half of the anion are generated by an inversion center.http://scripts.iucr.org/cgi-bin/paper?S1600536808042116 |
| spellingShingle | Matthew J. Panzner Wiley J. Youngs Claire A. Tessier A crystallographically isolated dimeric hydrolyzed chlorophosphazene dianion Acta Crystallographica Section E |
| title | A crystallographically isolated dimeric hydrolyzed chlorophosphazene dianion |
| title_full | A crystallographically isolated dimeric hydrolyzed chlorophosphazene dianion |
| title_fullStr | A crystallographically isolated dimeric hydrolyzed chlorophosphazene dianion |
| title_full_unstemmed | A crystallographically isolated dimeric hydrolyzed chlorophosphazene dianion |
| title_short | A crystallographically isolated dimeric hydrolyzed chlorophosphazene dianion |
| title_sort | crystallographically isolated dimeric hydrolyzed chlorophosphazene dianion |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808042116 |
| work_keys_str_mv | AT matthewjpanzner acrystallographicallyisolateddimerichydrolyzedchlorophosphazenedianion AT wileyjyoungs acrystallographicallyisolateddimerichydrolyzedchlorophosphazenedianion AT claireatessier acrystallographicallyisolateddimerichydrolyzedchlorophosphazenedianion AT matthewjpanzner crystallographicallyisolateddimerichydrolyzedchlorophosphazenedianion AT wileyjyoungs crystallographicallyisolateddimerichydrolyzedchlorophosphazenedianion AT claireatessier crystallographicallyisolateddimerichydrolyzedchlorophosphazenedianion |