Reducción de órganohalogenados mediada por vitamina B12 y citrato de titanio (III) en microemulsiones bicontinuas
We studied the electrochemical behavior of both the titanium citrate and the vitamin B12 in bicontinuous microemulsions for the reduction of halogenated organic compounds. The reduced form of titanium citrate complex, Ti(III)-cit, prepared by electrolysis, transforms, in a homogeneous way, the vitam...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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Universidad de Los Andes
2012-05-01
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| Series: | Avances en Química |
| Subjects: | |
| Online Access: | http://www.saber.ula.ve/bitstream/123456789/35284/1/articulo5.pdf |
| _version_ | 1818308511741771776 |
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| author | Lorean Madriz Hermes Carrero Aivlé Cabrera |
| author_facet | Lorean Madriz Hermes Carrero Aivlé Cabrera |
| author_sort | Lorean Madriz |
| collection | DOAJ |
| description | We studied the electrochemical behavior of both the titanium citrate and the vitamin B12 in bicontinuous microemulsions for the reduction of halogenated organic compounds. The reduced form of titanium citrate complex, Ti(III)-cit, prepared by electrolysis, transforms, in a homogeneous way, the vitamin B12 to their reduced (B12r) and super reduced (B12s) forms; the latter form (B12s) easily promotes dehalogenation of organic compounds in microemulsion. Benzyl chloride, for example, was dehalogenated in a short period of time transforming the original amount between 46 and 85%; on the other hand, lindane disappeared completely when it was in the presence of vitamin B12 while no effect was observed for 1,2–dichloroethane |
| first_indexed | 2024-12-13T07:15:26Z |
| format | Article |
| id | doaj.art-4f594b207d3a46eeb3faf27af9f025de |
| institution | Directory Open Access Journal |
| issn | 1856-5301 |
| language | English |
| last_indexed | 2024-12-13T07:15:26Z |
| publishDate | 2012-05-01 |
| publisher | Universidad de Los Andes |
| record_format | Article |
| series | Avances en Química |
| spelling | doaj.art-4f594b207d3a46eeb3faf27af9f025de2022-12-21T23:55:33ZengUniversidad de Los AndesAvances en Química1856-53012012-05-01714355Reducción de órganohalogenados mediada por vitamina B12 y citrato de titanio (III) en microemulsiones bicontinuasLorean MadrizHermes CarreroAivlé CabreraWe studied the electrochemical behavior of both the titanium citrate and the vitamin B12 in bicontinuous microemulsions for the reduction of halogenated organic compounds. The reduced form of titanium citrate complex, Ti(III)-cit, prepared by electrolysis, transforms, in a homogeneous way, the vitamin B12 to their reduced (B12r) and super reduced (B12s) forms; the latter form (B12s) easily promotes dehalogenation of organic compounds in microemulsion. Benzyl chloride, for example, was dehalogenated in a short period of time transforming the original amount between 46 and 85%; on the other hand, lindane disappeared completely when it was in the presence of vitamin B12 while no effect was observed for 1,2–dichloroethanehttp://www.saber.ula.ve/bitstream/123456789/35284/1/articulo5.pdfBicontinuous microemulsionOrgan-halide compoundsTitanium (III) citrateVitamin B12. |
| spellingShingle | Lorean Madriz Hermes Carrero Aivlé Cabrera Reducción de órganohalogenados mediada por vitamina B12 y citrato de titanio (III) en microemulsiones bicontinuas Avances en Química Bicontinuous microemulsion Organ-halide compounds Titanium (III) citrate Vitamin B12. |
| title | Reducción de órganohalogenados mediada por vitamina B12 y citrato de titanio (III) en microemulsiones bicontinuas |
| title_full | Reducción de órganohalogenados mediada por vitamina B12 y citrato de titanio (III) en microemulsiones bicontinuas |
| title_fullStr | Reducción de órganohalogenados mediada por vitamina B12 y citrato de titanio (III) en microemulsiones bicontinuas |
| title_full_unstemmed | Reducción de órganohalogenados mediada por vitamina B12 y citrato de titanio (III) en microemulsiones bicontinuas |
| title_short | Reducción de órganohalogenados mediada por vitamina B12 y citrato de titanio (III) en microemulsiones bicontinuas |
| title_sort | reduccion de organohalogenados mediada por vitamina b12 y citrato de titanio iii en microemulsiones bicontinuas |
| topic | Bicontinuous microemulsion Organ-halide compounds Titanium (III) citrate Vitamin B12. |
| url | http://www.saber.ula.ve/bitstream/123456789/35284/1/articulo5.pdf |
| work_keys_str_mv | AT loreanmadriz reducciondeorganohalogenadosmediadaporvitaminab12ycitratodetitanioiiienmicroemulsionesbicontinuas AT hermescarrero reducciondeorganohalogenadosmediadaporvitaminab12ycitratodetitanioiiienmicroemulsionesbicontinuas AT aivlecabrera reducciondeorganohalogenadosmediadaporvitaminab12ycitratodetitanioiiienmicroemulsionesbicontinuas |