Accelerated Corrosion Behavior of B10 Cu-Ni Alloy in Seawater

B10 Cu-Ni alloy has good corrosion resistance against seawater. Natural seawater from Xiamen, was used to study the seawater corrosion behaviour of B10 Cu-Ni alloy, H<sub>2</sub>O<sub>2</sub> was added as corrosion accelerator. The whole seawater immersion corrosion simulatio...

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Main Authors: LIU Tian-jiao, CHEN Hui-peng, ZHANG Wei-fang, LOU Wei-tao
Format: Article
Language:zho
Published: Journal of Materials Engineering 2017-05-01
Series:Cailiao gongcheng
Subjects:
Online Access:http://jme.biam.ac.cn/CN/Y2017/V45/I5/31
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author LIU Tian-jiao
CHEN Hui-peng
ZHANG Wei-fang
LOU Wei-tao
author_facet LIU Tian-jiao
CHEN Hui-peng
ZHANG Wei-fang
LOU Wei-tao
author_sort LIU Tian-jiao
collection DOAJ
description B10 Cu-Ni alloy has good corrosion resistance against seawater. Natural seawater from Xiamen, was used to study the seawater corrosion behaviour of B10 Cu-Ni alloy, H<sub>2</sub>O<sub>2</sub> was added as corrosion accelerator. The whole seawater immersion corrosion simulation experiments were conducted in laboratory. Geometric measurement and electrochemical impedance spectroscopy (EIS) technique were used to obtain the tendency of corrosion rate versus corrosion time. The growth and damage of the oxidation film on the surface of the alloy of 1cm<sup>2</sup> working area were characterized by the impedance spectra features with different corrosion time.Scanning electron microscope(SEM),energy spectrum analysis(EDX), X-ray photoelectron spectroscopy(XPS) and raman spectrum were used to analyse the constitution of corrosion product and the corrosion types. The results show that the instantaneous corrosion rate exhibits decreasing first then increasing due to the state of oxidation film. The corrosion products consist of Cu<sub>2</sub>(OH)<sub>3</sub>Cl and Cu<sub>2</sub>O. And the corrosion of B10 Cu-Ni alloy starts with pitting corrosion, then gradually goes through the evolution process of intergranular corrosion to exfoliation.
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spelling doaj.art-4f5d7c3d8f7e49ae95c127f578be3cb72023-01-03T01:57:56ZzhoJournal of Materials EngineeringCailiao gongcheng1001-43811001-43812017-05-01455313710.11868/j.issn.1001-4381.2015.000411201705000411Accelerated Corrosion Behavior of B10 Cu-Ni Alloy in SeawaterLIU Tian-jiao0CHEN Hui-peng1ZHANG Wei-fang2LOU Wei-tao3National Defense Science & Technology Laboratory on Reliability & Environmental Engineering, Beihang University, Beijing 100191, ChinaNational Defense Science & Technology Laboratory on Reliability & Environmental Engineering, Beihang University, Beijing 100191, ChinaNational Defense Science & Technology Laboratory on Reliability & Environmental Engineering, Beihang University, Beijing 100191, ChinaNational Defense Science & Technology Laboratory on Reliability & Environmental Engineering, Beihang University, Beijing 100191, ChinaB10 Cu-Ni alloy has good corrosion resistance against seawater. Natural seawater from Xiamen, was used to study the seawater corrosion behaviour of B10 Cu-Ni alloy, H<sub>2</sub>O<sub>2</sub> was added as corrosion accelerator. The whole seawater immersion corrosion simulation experiments were conducted in laboratory. Geometric measurement and electrochemical impedance spectroscopy (EIS) technique were used to obtain the tendency of corrosion rate versus corrosion time. The growth and damage of the oxidation film on the surface of the alloy of 1cm<sup>2</sup> working area were characterized by the impedance spectra features with different corrosion time.Scanning electron microscope(SEM),energy spectrum analysis(EDX), X-ray photoelectron spectroscopy(XPS) and raman spectrum were used to analyse the constitution of corrosion product and the corrosion types. The results show that the instantaneous corrosion rate exhibits decreasing first then increasing due to the state of oxidation film. The corrosion products consist of Cu<sub>2</sub>(OH)<sub>3</sub>Cl and Cu<sub>2</sub>O. And the corrosion of B10 Cu-Ni alloy starts with pitting corrosion, then gradually goes through the evolution process of intergranular corrosion to exfoliation.http://jme.biam.ac.cn/CN/Y2017/V45/I5/31B10 Cu-Ni alloyseawater corrosionEISSEMcorrosion product
spellingShingle LIU Tian-jiao
CHEN Hui-peng
ZHANG Wei-fang
LOU Wei-tao
Accelerated Corrosion Behavior of B10 Cu-Ni Alloy in Seawater
Cailiao gongcheng
B10 Cu-Ni alloy
seawater corrosion
EIS
SEM
corrosion product
title Accelerated Corrosion Behavior of B10 Cu-Ni Alloy in Seawater
title_full Accelerated Corrosion Behavior of B10 Cu-Ni Alloy in Seawater
title_fullStr Accelerated Corrosion Behavior of B10 Cu-Ni Alloy in Seawater
title_full_unstemmed Accelerated Corrosion Behavior of B10 Cu-Ni Alloy in Seawater
title_short Accelerated Corrosion Behavior of B10 Cu-Ni Alloy in Seawater
title_sort accelerated corrosion behavior of b10 cu ni alloy in seawater
topic B10 Cu-Ni alloy
seawater corrosion
EIS
SEM
corrosion product
url http://jme.biam.ac.cn/CN/Y2017/V45/I5/31
work_keys_str_mv AT liutianjiao acceleratedcorrosionbehaviorofb10cunialloyinseawater
AT chenhuipeng acceleratedcorrosionbehaviorofb10cunialloyinseawater
AT zhangweifang acceleratedcorrosionbehaviorofb10cunialloyinseawater
AT louweitao acceleratedcorrosionbehaviorofb10cunialloyinseawater