Non-Local Vectorial Internal Variables and Generalized Guyer-Krumhansl Evolution Equations for the Heat Flux

In this paper, we ask ourselves how non-local effects affect the description of thermodynamic systems with internal variables. Usually, one assumes that the internal variables are local, but that their evolution equations are non-local, i.e., for instance, that their evolution equations contain non-...

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Main Authors: Liliana Restuccia, David Jou
Format: Article
Language:English
Published: MDPI AG 2023-08-01
Series:Entropy
Subjects:
Online Access:https://www.mdpi.com/1099-4300/25/9/1259
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author Liliana Restuccia
David Jou
author_facet Liliana Restuccia
David Jou
author_sort Liliana Restuccia
collection DOAJ
description In this paper, we ask ourselves how non-local effects affect the description of thermodynamic systems with internal variables. Usually, one assumes that the internal variables are local, but that their evolution equations are non-local, i.e., for instance, that their evolution equations contain non-local differential terms (gradients, Laplacians) or integral terms with memory kernels. In contrast to this typical situation, which has led to substantial progress in several fields, we ask ourselves whether in some cases it would be convenient to start from non-local internal variables with non-local evolution equations. We examine this point by considering three main lengths: the observation scale <i>R</i> defining the elementary volumes used in the description of the system, the mean free path <i>l</i> of the microscopic elements of the fluid (particles, phonons, photons, and molecules), and the overall characteristic size <i>L</i> of the global system. We illustrate these ideas by considering three-dimensional rigid heat conductors within the regime of phonon hydrodynamics in the presence of thermal vortices. In particular, we obtain a generalization of the Guyer–Krumhansl equation, which may be of interest for heat transport in nanosystems or in systems with small-scale inhomogeneities.
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spelling doaj.art-4f60dca64b464337aaff2c330c3630a22023-11-19T10:35:07ZengMDPI AGEntropy1099-43002023-08-01259125910.3390/e25091259Non-Local Vectorial Internal Variables and Generalized Guyer-Krumhansl Evolution Equations for the Heat FluxLiliana Restuccia0David Jou1Department of Mathematical and Computer Sciences, Physical Sciences and Earth Sciences, University of Messina, Viale F. Stagno d’Alcontres, Salita Sperone 31, 98166 Messina, ItalyGrup de Fisíca Estadística, Universitat Autònoma de Barcelona, 08193 Bellaterra, SpainIn this paper, we ask ourselves how non-local effects affect the description of thermodynamic systems with internal variables. Usually, one assumes that the internal variables are local, but that their evolution equations are non-local, i.e., for instance, that their evolution equations contain non-local differential terms (gradients, Laplacians) or integral terms with memory kernels. In contrast to this typical situation, which has led to substantial progress in several fields, we ask ourselves whether in some cases it would be convenient to start from non-local internal variables with non-local evolution equations. We examine this point by considering three main lengths: the observation scale <i>R</i> defining the elementary volumes used in the description of the system, the mean free path <i>l</i> of the microscopic elements of the fluid (particles, phonons, photons, and molecules), and the overall characteristic size <i>L</i> of the global system. We illustrate these ideas by considering three-dimensional rigid heat conductors within the regime of phonon hydrodynamics in the presence of thermal vortices. In particular, we obtain a generalization of the Guyer–Krumhansl equation, which may be of interest for heat transport in nanosystems or in systems with small-scale inhomogeneities.https://www.mdpi.com/1099-4300/25/9/1259continuum thermodynamicsheat transportclassical irreversible thermodynamicsinternal variablesphonon hydrodynamics
spellingShingle Liliana Restuccia
David Jou
Non-Local Vectorial Internal Variables and Generalized Guyer-Krumhansl Evolution Equations for the Heat Flux
Entropy
continuum thermodynamics
heat transport
classical irreversible thermodynamics
internal variables
phonon hydrodynamics
title Non-Local Vectorial Internal Variables and Generalized Guyer-Krumhansl Evolution Equations for the Heat Flux
title_full Non-Local Vectorial Internal Variables and Generalized Guyer-Krumhansl Evolution Equations for the Heat Flux
title_fullStr Non-Local Vectorial Internal Variables and Generalized Guyer-Krumhansl Evolution Equations for the Heat Flux
title_full_unstemmed Non-Local Vectorial Internal Variables and Generalized Guyer-Krumhansl Evolution Equations for the Heat Flux
title_short Non-Local Vectorial Internal Variables and Generalized Guyer-Krumhansl Evolution Equations for the Heat Flux
title_sort non local vectorial internal variables and generalized guyer krumhansl evolution equations for the heat flux
topic continuum thermodynamics
heat transport
classical irreversible thermodynamics
internal variables
phonon hydrodynamics
url https://www.mdpi.com/1099-4300/25/9/1259
work_keys_str_mv AT lilianarestuccia nonlocalvectorialinternalvariablesandgeneralizedguyerkrumhanslevolutionequationsfortheheatflux
AT davidjou nonlocalvectorialinternalvariablesandgeneralizedguyerkrumhanslevolutionequationsfortheheatflux