catena-Poly[[[aquabis(1H-imidazole-κN3)copper(II)]-μ-furan-2,5-dicarboxylato-κ2O2:O5] trihydrate]
In the title cooridnation polymer, {[Cu(C6H2O5)(C3H4N2)2(H2O)]·3H2O}n, an infinite chain is formed along [001] by linking of the Cu(C3N2H4)2(H2O) entities with two bridging monodentate carboxylate groups of two different furan-2,5-dicarboxylate dianions. The geometry of the Cu2+ ion is...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2012-05-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812016856 |
| _version_ | 1798025828985995264 |
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| author | Yue Gao Wen-Yuan Gao Yue Xu Ya-Feng Li Xiao-Lin Qin |
| author_facet | Yue Gao Wen-Yuan Gao Yue Xu Ya-Feng Li Xiao-Lin Qin |
| author_sort | Yue Gao |
| collection | DOAJ |
| description | In the title cooridnation polymer, {[Cu(C6H2O5)(C3H4N2)2(H2O)]·3H2O}n, an infinite chain is formed along [001] by linking of the Cu(C3N2H4)2(H2O) entities with two bridging monodentate carboxylate groups of two different furan-2,5-dicarboxylate dianions. The geometry of the Cu2+ ion is a square-based pyramid with the water atom in the apical position and the ligand O and N atoms in a trans orientation. The dihedral angle between the imidazole planes is 83.96 (14)°. Ow–H...O and Ni–H...O (w = water and i = imidazole) hydrogen bonds help to establish the packing. |
| first_indexed | 2024-04-11T18:25:12Z |
| format | Article |
| id | doaj.art-4f6f5b08206e401885aecfc35d047d2d |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T18:25:12Z |
| publishDate | 2012-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-4f6f5b08206e401885aecfc35d047d2d2022-12-22T04:09:39ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-05-01685m659m65910.1107/S1600536812016856catena-Poly[[[aquabis(1H-imidazole-κN3)copper(II)]-μ-furan-2,5-dicarboxylato-κ2O2:O5] trihydrate]Yue GaoWen-Yuan GaoYue XuYa-Feng LiXiao-Lin QinIn the title cooridnation polymer, {[Cu(C6H2O5)(C3H4N2)2(H2O)]·3H2O}n, an infinite chain is formed along [001] by linking of the Cu(C3N2H4)2(H2O) entities with two bridging monodentate carboxylate groups of two different furan-2,5-dicarboxylate dianions. The geometry of the Cu2+ ion is a square-based pyramid with the water atom in the apical position and the ligand O and N atoms in a trans orientation. The dihedral angle between the imidazole planes is 83.96 (14)°. Ow–H...O and Ni–H...O (w = water and i = imidazole) hydrogen bonds help to establish the packing.http://scripts.iucr.org/cgi-bin/paper?S1600536812016856 |
| spellingShingle | Yue Gao Wen-Yuan Gao Yue Xu Ya-Feng Li Xiao-Lin Qin catena-Poly[[[aquabis(1H-imidazole-κN3)copper(II)]-μ-furan-2,5-dicarboxylato-κ2O2:O5] trihydrate] Acta Crystallographica Section E |
| title | catena-Poly[[[aquabis(1H-imidazole-κN3)copper(II)]-μ-furan-2,5-dicarboxylato-κ2O2:O5] trihydrate] |
| title_full | catena-Poly[[[aquabis(1H-imidazole-κN3)copper(II)]-μ-furan-2,5-dicarboxylato-κ2O2:O5] trihydrate] |
| title_fullStr | catena-Poly[[[aquabis(1H-imidazole-κN3)copper(II)]-μ-furan-2,5-dicarboxylato-κ2O2:O5] trihydrate] |
| title_full_unstemmed | catena-Poly[[[aquabis(1H-imidazole-κN3)copper(II)]-μ-furan-2,5-dicarboxylato-κ2O2:O5] trihydrate] |
| title_short | catena-Poly[[[aquabis(1H-imidazole-κN3)copper(II)]-μ-furan-2,5-dicarboxylato-κ2O2:O5] trihydrate] |
| title_sort | catena poly aquabis 1h imidazole amp 954 n3 copper ii amp 956 furan 2 5 dicarboxylato amp 954 2o2 o5 trihydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812016856 |
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