Metal and Covalent Organic Frameworks for Membrane Applications

Better and more efficient membranes are needed to face imminent and future scientific, technological and societal challenges. New materials endowed with enhanced properties are required for the preparation of such membranes. Metal and Covalent Organic Frameworks (MOFs and COFs) are a new class of cr...

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Main Authors: Mingyuan Fang, Carmen Montoro, Mona Semsarilar
Format: Article
Language:English
Published: MDPI AG 2020-05-01
Series:Membranes
Subjects:
Online Access:https://www.mdpi.com/2077-0375/10/5/107
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author Mingyuan Fang
Carmen Montoro
Mona Semsarilar
author_facet Mingyuan Fang
Carmen Montoro
Mona Semsarilar
author_sort Mingyuan Fang
collection DOAJ
description Better and more efficient membranes are needed to face imminent and future scientific, technological and societal challenges. New materials endowed with enhanced properties are required for the preparation of such membranes. Metal and Covalent Organic Frameworks (MOFs and COFs) are a new class of crystalline porous materials with large surface area, tuneable pore size, structure, and functionality, making them a perfect candidate for membrane applications. In recent years an enormous number of articles have been published on the use of MOFs and COFs in preparation of membranes for various applications. This review gathers the work reported on the synthesis and preparation of membranes containing MOFs and COFs in the last 10 years. Here we give an overview on membranes and their use in separation technology, discussing the essential factors in their synthesis as well as their limitations. A full detailed summary of the preparation and characterization methods used for MOF and COF membranes is given. Finally, applications of these membranes in gas and liquid separation as well as fuel cells are discussed. This review is aimed at both experts in the field and newcomers, including students at both undergraduate and postgraduate levels, who would like to learn about preparation of membranes from crystalline porous materials.
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spelling doaj.art-4f71a5d4224e47d0a49cccfe9d56c6cd2023-11-20T01:24:26ZengMDPI AGMembranes2077-03752020-05-0110510710.3390/membranes10050107Metal and Covalent Organic Frameworks for Membrane ApplicationsMingyuan Fang0Carmen Montoro1Mona Semsarilar2Institut Européen des Membranes—IEM UMR 5635, Univ Montpellier, CNRS, ENSCM, 34095 Montpellier, FranceInstitut Européen des Membranes—IEM UMR 5635, Univ Montpellier, CNRS, ENSCM, 34095 Montpellier, FranceInstitut Européen des Membranes—IEM UMR 5635, Univ Montpellier, CNRS, ENSCM, 34095 Montpellier, FranceBetter and more efficient membranes are needed to face imminent and future scientific, technological and societal challenges. New materials endowed with enhanced properties are required for the preparation of such membranes. Metal and Covalent Organic Frameworks (MOFs and COFs) are a new class of crystalline porous materials with large surface area, tuneable pore size, structure, and functionality, making them a perfect candidate for membrane applications. In recent years an enormous number of articles have been published on the use of MOFs and COFs in preparation of membranes for various applications. This review gathers the work reported on the synthesis and preparation of membranes containing MOFs and COFs in the last 10 years. Here we give an overview on membranes and their use in separation technology, discussing the essential factors in their synthesis as well as their limitations. A full detailed summary of the preparation and characterization methods used for MOF and COF membranes is given. Finally, applications of these membranes in gas and liquid separation as well as fuel cells are discussed. This review is aimed at both experts in the field and newcomers, including students at both undergraduate and postgraduate levels, who would like to learn about preparation of membranes from crystalline porous materials.https://www.mdpi.com/2077-0375/10/5/107MOF membranesCOF membranesmembrane characterisationgas separationliquid separationsfuel cells
spellingShingle Mingyuan Fang
Carmen Montoro
Mona Semsarilar
Metal and Covalent Organic Frameworks for Membrane Applications
Membranes
MOF membranes
COF membranes
membrane characterisation
gas separation
liquid separations
fuel cells
title Metal and Covalent Organic Frameworks for Membrane Applications
title_full Metal and Covalent Organic Frameworks for Membrane Applications
title_fullStr Metal and Covalent Organic Frameworks for Membrane Applications
title_full_unstemmed Metal and Covalent Organic Frameworks for Membrane Applications
title_short Metal and Covalent Organic Frameworks for Membrane Applications
title_sort metal and covalent organic frameworks for membrane applications
topic MOF membranes
COF membranes
membrane characterisation
gas separation
liquid separations
fuel cells
url https://www.mdpi.com/2077-0375/10/5/107
work_keys_str_mv AT mingyuanfang metalandcovalentorganicframeworksformembraneapplications
AT carmenmontoro metalandcovalentorganicframeworksformembraneapplications
AT monasemsarilar metalandcovalentorganicframeworksformembraneapplications