Toward Self‐Supported Bifunctional Air Electrodes for Flexible Solid‐State Zn–Air Batteries

The demand for flexibility and rechargeability in tandem with high energy density, reliability, and safety in energy‐storage devices to power wearable electronics has translated to significant advances in flexible solid‐state Zn–air batteries (FSZABs) technology. FSZABs using self‐supported bifuncti...

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Main Authors: Xixi Wang, Lei Xu, Chuan Zhou, Ngie Hing Wong, Jaka Sunarso, Ran Ran, Wei Zhou, Zongping Shao
Format: Article
Language:English
Published: Wiley-VCH 2023-10-01
Series:Small Science
Subjects:
Online Access:https://doi.org/10.1002/smsc.202300066
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author Xixi Wang
Lei Xu
Chuan Zhou
Ngie Hing Wong
Jaka Sunarso
Ran Ran
Wei Zhou
Zongping Shao
author_facet Xixi Wang
Lei Xu
Chuan Zhou
Ngie Hing Wong
Jaka Sunarso
Ran Ran
Wei Zhou
Zongping Shao
author_sort Xixi Wang
collection DOAJ
description The demand for flexibility and rechargeability in tandem with high energy density, reliability, and safety in energy‐storage devices to power wearable electronics has translated to significant advances in flexible solid‐state Zn–air batteries (FSZABs) technology. FSZABs using self‐supported bifunctional air electrodes are currently one of the most attractive alternatives to Li‐ion battery technology for next‐generation wearable electronics. Unlike the conventional powder‐based air electrodes, self‐supported bifunctional air electrodes offer higher electron‐transfer rate, larger specific surface area (and catalyst–reactant–product interfacial contact area), mechanical flexibility, and better operational robustness. To realize their potential nonetheless, self‐supported bifunctional air electrodes should have high and stable bifunctional catalytic activity, low cost, and environmental compatibility. This review first summarizes the three typical configurations and working principles of FSZABs. Then, significant development of self‐supported bifunctional air electrodes for FSZABs and efficient synthesis strategies are emphasized. The review concludes by providing perspectives on how to further improve the electrochemical performance of FSZABs and their suitability for next‐generation wearable electronic devices.
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spelling doaj.art-4f816a9bae9544a2ba696b68ad066b8d2023-10-16T07:06:38ZengWiley-VCHSmall Science2688-40462023-10-01310n/an/a10.1002/smsc.202300066Toward Self‐Supported Bifunctional Air Electrodes for Flexible Solid‐State Zn–Air BatteriesXixi Wang0Lei Xu1Chuan Zhou2Ngie Hing Wong3Jaka Sunarso4Ran Ran5Wei Zhou6Zongping Shao7State Key Laboratory of Materials-Oriented Chemical Engineering College of Chemical Engineering Nanjing Tech University Nanjing 210009 ChinaState Key Laboratory of Materials-Oriented Chemical Engineering College of Chemical Engineering Nanjing Tech University Nanjing 210009 ChinaState Key Laboratory of Materials-Oriented Chemical Engineering College of Chemical Engineering Nanjing Tech University Nanjing 210009 ChinaResearch Centre for Sustainable Technologies Faculty of Engineering, Computing, and Science Swinburne University of Technology Jalan Simpang Tiga Kuching Sarawak 93350 MalaysiaResearch Centre for Sustainable Technologies Faculty of Engineering, Computing, and Science Swinburne University of Technology Jalan Simpang Tiga Kuching Sarawak 93350 MalaysiaState Key Laboratory of Materials-Oriented Chemical Engineering College of Chemical Engineering Nanjing Tech University Nanjing 210009 ChinaState Key Laboratory of Materials-Oriented Chemical Engineering College of Chemical Engineering Nanjing Tech University Nanjing 210009 ChinaState Key Laboratory of Materials-Oriented Chemical Engineering College of Chemical Engineering Nanjing Tech University Nanjing 210009 ChinaThe demand for flexibility and rechargeability in tandem with high energy density, reliability, and safety in energy‐storage devices to power wearable electronics has translated to significant advances in flexible solid‐state Zn–air batteries (FSZABs) technology. FSZABs using self‐supported bifunctional air electrodes are currently one of the most attractive alternatives to Li‐ion battery technology for next‐generation wearable electronics. Unlike the conventional powder‐based air electrodes, self‐supported bifunctional air electrodes offer higher electron‐transfer rate, larger specific surface area (and catalyst–reactant–product interfacial contact area), mechanical flexibility, and better operational robustness. To realize their potential nonetheless, self‐supported bifunctional air electrodes should have high and stable bifunctional catalytic activity, low cost, and environmental compatibility. This review first summarizes the three typical configurations and working principles of FSZABs. Then, significant development of self‐supported bifunctional air electrodes for FSZABs and efficient synthesis strategies are emphasized. The review concludes by providing perspectives on how to further improve the electrochemical performance of FSZABs and their suitability for next‐generation wearable electronic devices.https://doi.org/10.1002/smsc.202300066flexible solid-state Zn–air batteriesoxygen reduction and evolution reactionself-supported bifunctional air electrodessynthesis strategieswearable electronic devices
spellingShingle Xixi Wang
Lei Xu
Chuan Zhou
Ngie Hing Wong
Jaka Sunarso
Ran Ran
Wei Zhou
Zongping Shao
Toward Self‐Supported Bifunctional Air Electrodes for Flexible Solid‐State Zn–Air Batteries
Small Science
flexible solid-state Zn–air batteries
oxygen reduction and evolution reaction
self-supported bifunctional air electrodes
synthesis strategies
wearable electronic devices
title Toward Self‐Supported Bifunctional Air Electrodes for Flexible Solid‐State Zn–Air Batteries
title_full Toward Self‐Supported Bifunctional Air Electrodes for Flexible Solid‐State Zn–Air Batteries
title_fullStr Toward Self‐Supported Bifunctional Air Electrodes for Flexible Solid‐State Zn–Air Batteries
title_full_unstemmed Toward Self‐Supported Bifunctional Air Electrodes for Flexible Solid‐State Zn–Air Batteries
title_short Toward Self‐Supported Bifunctional Air Electrodes for Flexible Solid‐State Zn–Air Batteries
title_sort toward self supported bifunctional air electrodes for flexible solid state zn air batteries
topic flexible solid-state Zn–air batteries
oxygen reduction and evolution reaction
self-supported bifunctional air electrodes
synthesis strategies
wearable electronic devices
url https://doi.org/10.1002/smsc.202300066
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