Tetrakis(μ2-diphenylphosphinato-κ2O,O′)tetra-μ3-oxido-tetraoxidohexamolybdenum(V)
The molecule of the title compound, [Mo4(μ2-C12H10OP2)4(μ3-O)4O4], exhibits point group symmetry 2 with the twofold rotation axis passing through two opposite P atoms. Each MoV atom is bridged by three O atoms resulting in an Mo4O4 heterocubane core. In the crystal, weak C—H...O interactions may hel...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2016-01-01
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| Series: | IUCrData |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314616000365 |
| _version_ | 1819263181358366720 |
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| author | Sara Raquel Mota Merelo de Aguiar Berthold Stöger Matthias Weil Karl Kirchner |
| author_facet | Sara Raquel Mota Merelo de Aguiar Berthold Stöger Matthias Weil Karl Kirchner |
| author_sort | Sara Raquel Mota Merelo de Aguiar |
| collection | DOAJ |
| description | The molecule of the title compound, [Mo4(μ2-C12H10OP2)4(μ3-O)4O4], exhibits point group symmetry 2 with the twofold rotation axis passing through two opposite P atoms. Each MoV atom is bridged by three O atoms resulting in an Mo4O4 heterocubane core. In the crystal, weak C—H...O interactions may help to consolidate packing of the molecules. |
| first_indexed | 2024-12-23T20:09:30Z |
| format | Article |
| id | doaj.art-4f88d387526e448aad17b96c4214c6ea |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-12-23T20:09:30Z |
| publishDate | 2016-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-4f88d387526e448aad17b96c4214c6ea2022-12-21T17:32:50ZengInternational Union of CrystallographyIUCrData2414-31462016-01-0111x16003610.1107/S2414314616000365sj4007Tetrakis(μ2-diphenylphosphinato-κ2O,O′)tetra-μ3-oxido-tetraoxidohexamolybdenum(V)Sara Raquel Mota Merelo de Aguiar0Berthold Stöger1Matthias Weil2Karl Kirchner3Institute of Applied Synthetic Chemistry, TU Wien, Getreidemarkt 9/163, A-1060 Vienna, AustriaInstitute for Chemical Technologies and Analytics, Division of Structural Chemistry, TU Wien, Getreidemarkt 9/164-SC, A-1060 Vienna, AustriaInstitute for Chemical Technologies and Analytics, Division of Structural Chemistry, TU Wien, Getreidemarkt 9/164-SC, A-1060 Vienna, AustriaInstitute of Applied Synthetic Chemistry, TU Wien, Getreidemarkt 9/163, A-1060 Vienna, AustriaThe molecule of the title compound, [Mo4(μ2-C12H10OP2)4(μ3-O)4O4], exhibits point group symmetry 2 with the twofold rotation axis passing through two opposite P atoms. Each MoV atom is bridged by three O atoms resulting in an Mo4O4 heterocubane core. In the crystal, weak C—H...O interactions may help to consolidate packing of the molecules.http://scripts.iucr.org/cgi-bin/paper?S2414314616000365crystal structureheterocubanemolybdenumMo4O4 core |
| spellingShingle | Sara Raquel Mota Merelo de Aguiar Berthold Stöger Matthias Weil Karl Kirchner Tetrakis(μ2-diphenylphosphinato-κ2O,O′)tetra-μ3-oxido-tetraoxidohexamolybdenum(V) IUCrData crystal structure heterocubane molybdenum Mo4O4 core |
| title | Tetrakis(μ2-diphenylphosphinato-κ2O,O′)tetra-μ3-oxido-tetraoxidohexamolybdenum(V) |
| title_full | Tetrakis(μ2-diphenylphosphinato-κ2O,O′)tetra-μ3-oxido-tetraoxidohexamolybdenum(V) |
| title_fullStr | Tetrakis(μ2-diphenylphosphinato-κ2O,O′)tetra-μ3-oxido-tetraoxidohexamolybdenum(V) |
| title_full_unstemmed | Tetrakis(μ2-diphenylphosphinato-κ2O,O′)tetra-μ3-oxido-tetraoxidohexamolybdenum(V) |
| title_short | Tetrakis(μ2-diphenylphosphinato-κ2O,O′)tetra-μ3-oxido-tetraoxidohexamolybdenum(V) |
| title_sort | tetrakis μ2 diphenylphosphinato κ2o o tetra μ3 oxido tetraoxidohexamolybdenum v |
| topic | crystal structure heterocubane molybdenum Mo4O4 core |
| url | http://scripts.iucr.org/cgi-bin/paper?S2414314616000365 |
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