Studies on structural, optical nonlinearity and antibacterial activity of Piperazine (bis) p-toluenesulfonate single crystal for optical limiting and biological applications
Piperazine (bis) p-toluenesulfonate (PPTSA), an organic single crystal was synthesized and grown at environmental temperature by slow evaporation process using methanol as the solvent. The grown PPTSA crystal is from the triclinic system and belongs to the space group P1-. Powder X-ray diffraction w...
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| Format: | Article |
| Language: | English |
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Vasyl Stefanyk Precarpathian National University
2023-02-01
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| Series: | Фізика і хімія твердого тіла |
| Subjects: | |
| Online Access: | https://journals.pnu.edu.ua/index.php/pcss/article/view/5971 |
| _version_ | 1797859079233732608 |
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| author | K. Balakrishnan S. Sakthy Priya A. Lakshmanan P. Surendran Karthik Kannan P. Geetha G. Vinitha P. Praveen Kumar P. Rameshkumar |
| author_facet | K. Balakrishnan S. Sakthy Priya A. Lakshmanan P. Surendran Karthik Kannan P. Geetha G. Vinitha P. Praveen Kumar P. Rameshkumar |
| author_sort | K. Balakrishnan |
| collection | DOAJ |
| description | Piperazine (bis) p-toluenesulfonate (PPTSA), an organic single crystal was synthesized and grown at environmental temperature by slow evaporation process using methanol as the solvent. The grown PPTSA crystal is from the triclinic system and belongs to the space group P1-. Powder X-ray diffraction was performed to ensure lattice parameters. Analysis and confirmation of functional groups and bonds were carried out through FT-IR spectral study. The optical characteristics were investigated using the UV-Vis spectrum such as the optical absorption, cut-off wavelength were calculated. The photoluminescence investigation was conducted to assess the luminous characteristics of grown crystal. The calculated NLO parameters like β, n2, and χ(3) were found to be 0.0495×10-4 (cm/W), 8.705×10-10 (cm2/W), 5.316×10-7 (esu) and Optical Limiting threshold value was found to be 3.074×10-3 (Wcm-2). Antibacterial studies were carried out to investigate the biological significance against selected foodborne germs. |
| first_indexed | 2024-04-09T21:24:46Z |
| format | Article |
| id | doaj.art-4ff2cd6236e946f6beedf60833b5053e |
| institution | Directory Open Access Journal |
| issn | 1729-4428 2309-8589 |
| language | English |
| last_indexed | 2024-04-09T21:24:46Z |
| publishDate | 2023-02-01 |
| publisher | Vasyl Stefanyk Precarpathian National University |
| record_format | Article |
| series | Фізика і хімія твердого тіла |
| spelling | doaj.art-4ff2cd6236e946f6beedf60833b5053e2023-03-27T21:41:37ZengVasyl Stefanyk Precarpathian National UniversityФізика і хімія твердого тіла1729-44282309-85892023-02-01241465510.15330/pcss.24.1.46-555971Studies on structural, optical nonlinearity and antibacterial activity of Piperazine (bis) p-toluenesulfonate single crystal for optical limiting and biological applicationsK. Balakrishnan0S. Sakthy Priya1A. Lakshmanan2P. Surendran3Karthik Kannan4P. Geetha5G. Vinitha6P. Praveen Kumar7P. Rameshkumar8PG and Research Department of Physics, Nehru Memorial College (Autonomous), Affiliated to Bharathidasan University, Puthanampatti, IndiaPG and Research Department of Physics, Nehru Memorial College (Autonomous), Affiliated to Bharathidasan University, Puthanampatti, India; Department of Physics, Arignar Anna Government Arts College, Namakkal, Tamilnadu, India PG and Research Department of Physics, Nehru Memorial College (Autonomous), Affiliated to Bharathidasan University, Puthanampatti, India; Department of Physics, MAM College of Engineering, Siruganur, Tiruchirappalli, Tamilnadu, IndiaPG and Research Department of Physics, Nehru Memorial College (Autonomous), Affiliated to Bharathidasan University, Puthanampatti, India; Department of Physics, Government Arts and Science College, Komarapalayam, Tamilnadu, IndiaChemical Sciences Department and the Radical Research Center, Ariel University, Ariel, IsraelDepartment of Physics, Quaid-E-Millath Government College for Women (Autonomous), Chennai, Tamilnadu, IndiaDivision of Physics, School of Advanced Sciences, VIT Chennai, Tamil Nadu, IndiaDepartment of Physics, Presidency College (Autonomous), Chepauk, Triplicane, Chennai, Tamilnadu, IndiaDepartment of Physics, Presidency College (Autonomous), Chepauk, Triplicane, Chennai, Tamilnadu, IndiaPiperazine (bis) p-toluenesulfonate (PPTSA), an organic single crystal was synthesized and grown at environmental temperature by slow evaporation process using methanol as the solvent. The grown PPTSA crystal is from the triclinic system and belongs to the space group P1-. Powder X-ray diffraction was performed to ensure lattice parameters. Analysis and confirmation of functional groups and bonds were carried out through FT-IR spectral study. The optical characteristics were investigated using the UV-Vis spectrum such as the optical absorption, cut-off wavelength were calculated. The photoluminescence investigation was conducted to assess the luminous characteristics of grown crystal. The calculated NLO parameters like β, n2, and χ(3) were found to be 0.0495×10-4 (cm/W), 8.705×10-10 (cm2/W), 5.316×10-7 (esu) and Optical Limiting threshold value was found to be 3.074×10-3 (Wcm-2). Antibacterial studies were carried out to investigate the biological significance against selected foodborne germs.https://journals.pnu.edu.ua/index.php/pcss/article/view/5971crystal growthoptical materialz-scanoptical limitingantibacterial activity |
| spellingShingle | K. Balakrishnan S. Sakthy Priya A. Lakshmanan P. Surendran Karthik Kannan P. Geetha G. Vinitha P. Praveen Kumar P. Rameshkumar Studies on structural, optical nonlinearity and antibacterial activity of Piperazine (bis) p-toluenesulfonate single crystal for optical limiting and biological applications Фізика і хімія твердого тіла crystal growth optical material z-scan optical limiting antibacterial activity |
| title | Studies on structural, optical nonlinearity and antibacterial activity of Piperazine (bis) p-toluenesulfonate single crystal for optical limiting and biological applications |
| title_full | Studies on structural, optical nonlinearity and antibacterial activity of Piperazine (bis) p-toluenesulfonate single crystal for optical limiting and biological applications |
| title_fullStr | Studies on structural, optical nonlinearity and antibacterial activity of Piperazine (bis) p-toluenesulfonate single crystal for optical limiting and biological applications |
| title_full_unstemmed | Studies on structural, optical nonlinearity and antibacterial activity of Piperazine (bis) p-toluenesulfonate single crystal for optical limiting and biological applications |
| title_short | Studies on structural, optical nonlinearity and antibacterial activity of Piperazine (bis) p-toluenesulfonate single crystal for optical limiting and biological applications |
| title_sort | studies on structural optical nonlinearity and antibacterial activity of piperazine bis p toluenesulfonate single crystal for optical limiting and biological applications |
| topic | crystal growth optical material z-scan optical limiting antibacterial activity |
| url | https://journals.pnu.edu.ua/index.php/pcss/article/view/5971 |
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