β-Scission by Direct Electrochemical Oxidation: Proton-coupled Electron Transfer Mechanism Dictated by Synthetic Study and Computations

β-Scission by Direct Electrochemical Oxidation: Proton-coupled Electron Transfer Mechanism Dictated by Synthetic Study and Computations

β-Scission from alkoxy radical enables selective Csp3-Csp3 bond cleavage under ambient conditions, offering a useful method for organic synthesis. Various photocatalytic systems for β-scission have been reported, where proton-coupled electron transfer (PCET) mechanism plays a key role in the generat...

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Bibliographic Details
Main Authors: Rumi IZUMIYA, Mahito ATOBE, Naoki SHIDA
Format: Article
Language:English
Published: The Electrochemical Society of Japan 2023-11-01
Series:Electrochemistry
Subjects:
β-scission
csp3-csp3 bond cleavage
electrochemical proton-coupled electron transfer
cyclic voltammetry simulation
Online Access:https://www.jstage.jst.go.jp/article/electrochemistry/91/11/91_23-67010/_html/-char/en

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