Crystal structure of trans-1-{2-[4-(dimethylamino)phenyl]ethyl}-4-[2-(pyren-1-yl)ethyl]cyclohexane
The title compound, C34H37N, is a pyrene derivative in which the pyrene ring system is linked to an ethylcyclohexane unit which, in turn, carries a [4-(dimethylamino)phenyl]ethyl substituent in the para position. The central cyclohexane ring has a chair conformation, with the exocyclic C—C bonds in...
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2015-08-01
|
| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989015013729 |
| _version_ | 1798027052740247552 |
|---|---|
| author | Sreevidya Thekku Veedu Simone Techert |
| author_facet | Sreevidya Thekku Veedu Simone Techert |
| author_sort | Sreevidya Thekku Veedu |
| collection | DOAJ |
| description | The title compound, C34H37N, is a pyrene derivative in which the pyrene ring system is linked to an ethylcyclohexane unit which, in turn, carries a [4-(dimethylamino)phenyl]ethyl substituent in the para position. The central cyclohexane ring has a chair conformation, with the exocyclic C—C bonds in equatorial orientations. The benzene ring is inclined to the mean plane of the pyrene ring system [maximum deviation = 0.038 (4) Å] by 14.84 (15)°. In the crystal, molecules are linked by C—H...π interactions, forming chains propagating along [010]. The crystal was refined as a non-merohedral twin [domain ratio = 0.9989 (4):0.0011 (4)]. |
| first_indexed | 2024-04-11T18:45:04Z |
| format | Article |
| id | doaj.art-504271faef904eb299dc9378c7e01564 |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-04-11T18:45:04Z |
| publishDate | 2015-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-504271faef904eb299dc9378c7e015642022-12-22T04:08:50ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902015-08-01718o629o63010.1107/S2056989015013729su5171Crystal structure of trans-1-{2-[4-(dimethylamino)phenyl]ethyl}-4-[2-(pyren-1-yl)ethyl]cyclohexaneSreevidya Thekku Veedu0Simone Techert1FS–SCS, Deutsches Elecktronen-Synchrotron (DESY), Notkestrasse 85, 22607 Hamburg, GermanyFS–SCS, Deutsches Elecktronen-Synchrotron (DESY), Notkestrasse 85, 22607 Hamburg, GermanyThe title compound, C34H37N, is a pyrene derivative in which the pyrene ring system is linked to an ethylcyclohexane unit which, in turn, carries a [4-(dimethylamino)phenyl]ethyl substituent in the para position. The central cyclohexane ring has a chair conformation, with the exocyclic C—C bonds in equatorial orientations. The benzene ring is inclined to the mean plane of the pyrene ring system [maximum deviation = 0.038 (4) Å] by 14.84 (15)°. In the crystal, molecules are linked by C—H...π interactions, forming chains propagating along [010]. The crystal was refined as a non-merohedral twin [domain ratio = 0.9989 (4):0.0011 (4)].http://scripts.iucr.org/cgi-bin/paper?S2056989015013729crystal structurepyrenedonor acceptorelectron transferC—H...π interactions |
| spellingShingle | Sreevidya Thekku Veedu Simone Techert Crystal structure of trans-1-{2-[4-(dimethylamino)phenyl]ethyl}-4-[2-(pyren-1-yl)ethyl]cyclohexane Acta Crystallographica Section E: Crystallographic Communications crystal structure pyrene donor acceptor electron transfer C—H...π interactions |
| title | Crystal structure of trans-1-{2-[4-(dimethylamino)phenyl]ethyl}-4-[2-(pyren-1-yl)ethyl]cyclohexane |
| title_full | Crystal structure of trans-1-{2-[4-(dimethylamino)phenyl]ethyl}-4-[2-(pyren-1-yl)ethyl]cyclohexane |
| title_fullStr | Crystal structure of trans-1-{2-[4-(dimethylamino)phenyl]ethyl}-4-[2-(pyren-1-yl)ethyl]cyclohexane |
| title_full_unstemmed | Crystal structure of trans-1-{2-[4-(dimethylamino)phenyl]ethyl}-4-[2-(pyren-1-yl)ethyl]cyclohexane |
| title_short | Crystal structure of trans-1-{2-[4-(dimethylamino)phenyl]ethyl}-4-[2-(pyren-1-yl)ethyl]cyclohexane |
| title_sort | crystal structure of trans 1 2 4 dimethylamino phenyl ethyl 4 2 pyren 1 yl ethyl cyclohexane |
| topic | crystal structure pyrene donor acceptor electron transfer C—H...π interactions |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989015013729 |
| work_keys_str_mv | AT sreevidyathekkuveedu crystalstructureoftrans124dimethylaminophenylethyl42pyren1ylethylcyclohexane AT simonetechert crystalstructureoftrans124dimethylaminophenylethyl42pyren1ylethylcyclohexane |