Dust evolution, a global view I. Nanoparticles, nascence, nitrogen and natural selection … joining the dots

The role and importance of nanoparticles for interstellar chemistry and beyond is explored within the framework of The Heterogeneous dust Evolution Model for Interstellar Solids (THEMIS), focusing on their active surface chemistry, the effects of nitrogen doping and the natural selection of interest...

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Main Author: A. P. Jones
Format: Article
Language:English
Published: The Royal Society 2016-01-01
Series:Royal Society Open Science
Subjects:
Online Access:https://royalsocietypublishing.org/doi/pdf/10.1098/rsos.160221
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author A. P. Jones
author_facet A. P. Jones
author_sort A. P. Jones
collection DOAJ
description The role and importance of nanoparticles for interstellar chemistry and beyond is explored within the framework of The Heterogeneous dust Evolution Model for Interstellar Solids (THEMIS), focusing on their active surface chemistry, the effects of nitrogen doping and the natural selection of interesting nanoparticle sub-structures. Nanoparticle-driven chemistry, and in particular the role of intrinsic epoxide-type structures, could provide a viable route to the observed gas phase OH in tenuous interstellar clouds en route to becoming molecular clouds. The aromatic-rich moieties present in asphaltenes probably provide a viable model for the structures present within aromatic-rich interstellar carbonaceous grains. The observed doping of such nanoparticle structures with nitrogen, if also prevalent in interstellar dust, could perhaps have important and observable consequences for surface chemistry and the formation of precursor pre-biotic species.
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spelling doaj.art-5091b1ffef584da18a7e068e13ecb2922022-12-22T02:51:14ZengThe Royal SocietyRoyal Society Open Science2054-57032016-01-0131210.1098/rsos.160221160221Dust evolution, a global view I. Nanoparticles, nascence, nitrogen and natural selection … joining the dotsA. P. JonesThe role and importance of nanoparticles for interstellar chemistry and beyond is explored within the framework of The Heterogeneous dust Evolution Model for Interstellar Solids (THEMIS), focusing on their active surface chemistry, the effects of nitrogen doping and the natural selection of interesting nanoparticle sub-structures. Nanoparticle-driven chemistry, and in particular the role of intrinsic epoxide-type structures, could provide a viable route to the observed gas phase OH in tenuous interstellar clouds en route to becoming molecular clouds. The aromatic-rich moieties present in asphaltenes probably provide a viable model for the structures present within aromatic-rich interstellar carbonaceous grains. The observed doping of such nanoparticle structures with nitrogen, if also prevalent in interstellar dust, could perhaps have important and observable consequences for surface chemistry and the formation of precursor pre-biotic species.https://royalsocietypublishing.org/doi/pdf/10.1098/rsos.160221interstellar mediuminterstellar dustinterstellar molecules
spellingShingle A. P. Jones
Dust evolution, a global view I. Nanoparticles, nascence, nitrogen and natural selection … joining the dots
Royal Society Open Science
interstellar medium
interstellar dust
interstellar molecules
title Dust evolution, a global view I. Nanoparticles, nascence, nitrogen and natural selection … joining the dots
title_full Dust evolution, a global view I. Nanoparticles, nascence, nitrogen and natural selection … joining the dots
title_fullStr Dust evolution, a global view I. Nanoparticles, nascence, nitrogen and natural selection … joining the dots
title_full_unstemmed Dust evolution, a global view I. Nanoparticles, nascence, nitrogen and natural selection … joining the dots
title_short Dust evolution, a global view I. Nanoparticles, nascence, nitrogen and natural selection … joining the dots
title_sort dust evolution a global view i nanoparticles nascence nitrogen and natural selection joining the dots
topic interstellar medium
interstellar dust
interstellar molecules
url https://royalsocietypublishing.org/doi/pdf/10.1098/rsos.160221
work_keys_str_mv AT apjones dustevolutionaglobalviewinanoparticlesnascencenitrogenandnaturalselectionjoiningthedots