Bis(μ-2-{[oxido(phenyl)methylidene]hydrazinylidene}propanoato)bis[dibenzyl(ethanol)tin(IV)]
In the title complex, [Sn2(C7H7)4(C10H8N2O3)2(C2H5OH)2], the Sn(IV) atom is seven-coordinated in a distorted pentagonal–bipyramidal geometry by three O atoms and one N atom from the pyruvate benzoyl hydrazone ligand, one ethanol O atom and two axial C atoms from trans-benzyl groups, th...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-05-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811011937 |
| _version_ | 1831654628342628352 |
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| author | Shaojun Sun Jie Yang |
| author_facet | Shaojun Sun Jie Yang |
| author_sort | Shaojun Sun |
| collection | DOAJ |
| description | In the title complex, [Sn2(C7H7)4(C10H8N2O3)2(C2H5OH)2], the Sn(IV) atom is seven-coordinated in a distorted pentagonal–bipyramidal geometry by three O atoms and one N atom from the pyruvate benzoyl hydrazone ligand, one ethanol O atom and two axial C atoms from trans-benzyl groups, thus forming a dimeric molecule (overline{1} symmetry) via weak Sn—O interactions. The C atoms of one phenyl ring and the ethanol molecule are disordered over two sets of sites with site-occupancy factors of 0.57 (5):0.43 (5) and 0.79 (2):0.21 (2), respectively. Intermolecular O—H...O hydrogen bonds stabilize the crystal structure. |
| first_indexed | 2024-12-19T16:31:39Z |
| format | Article |
| id | doaj.art-50a292f24e324070ac610ce018faf1ed |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-19T16:31:39Z |
| publishDate | 2011-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-50a292f24e324070ac610ce018faf1ed2022-12-21T20:14:09ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-05-01675m544m54410.1107/S1600536811011937Bis(μ-2-{[oxido(phenyl)methylidene]hydrazinylidene}propanoato)bis[dibenzyl(ethanol)tin(IV)]Shaojun SunJie YangIn the title complex, [Sn2(C7H7)4(C10H8N2O3)2(C2H5OH)2], the Sn(IV) atom is seven-coordinated in a distorted pentagonal–bipyramidal geometry by three O atoms and one N atom from the pyruvate benzoyl hydrazone ligand, one ethanol O atom and two axial C atoms from trans-benzyl groups, thus forming a dimeric molecule (overline{1} symmetry) via weak Sn—O interactions. The C atoms of one phenyl ring and the ethanol molecule are disordered over two sets of sites with site-occupancy factors of 0.57 (5):0.43 (5) and 0.79 (2):0.21 (2), respectively. Intermolecular O—H...O hydrogen bonds stabilize the crystal structure.http://scripts.iucr.org/cgi-bin/paper?S1600536811011937 |
| spellingShingle | Shaojun Sun Jie Yang Bis(μ-2-{[oxido(phenyl)methylidene]hydrazinylidene}propanoato)bis[dibenzyl(ethanol)tin(IV)] Acta Crystallographica Section E |
| title | Bis(μ-2-{[oxido(phenyl)methylidene]hydrazinylidene}propanoato)bis[dibenzyl(ethanol)tin(IV)] |
| title_full | Bis(μ-2-{[oxido(phenyl)methylidene]hydrazinylidene}propanoato)bis[dibenzyl(ethanol)tin(IV)] |
| title_fullStr | Bis(μ-2-{[oxido(phenyl)methylidene]hydrazinylidene}propanoato)bis[dibenzyl(ethanol)tin(IV)] |
| title_full_unstemmed | Bis(μ-2-{[oxido(phenyl)methylidene]hydrazinylidene}propanoato)bis[dibenzyl(ethanol)tin(IV)] |
| title_short | Bis(μ-2-{[oxido(phenyl)methylidene]hydrazinylidene}propanoato)bis[dibenzyl(ethanol)tin(IV)] |
| title_sort | bis amp 956 2 oxido phenyl methylidene hydrazinylidene propanoato bis dibenzyl ethanol tin iv |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811011937 |
| work_keys_str_mv | AT shaojunsun bisamp9562oxidophenylmethylidenehydrazinylidenepropanoatobisdibenzylethanoltiniv AT jieyang bisamp9562oxidophenylmethylidenehydrazinylidenepropanoatobisdibenzylethanoltiniv |