Study of the zinc action on the 2-chloroethyl 2-bromo-2-perfluoroalkylethanoates
2-Bromo-2-perfluoroalkyl acids are converted into the corresponding esters by a reaction of alcoholysis in the 2-chloroethanol. The action of zinc on perfluoroalkylated bromo-esters resulted in the bromine reduction products formation via zinc organic intermediates. When heated at 100°C, for 48 h, i...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Taylor & Francis Group
2018-05-01
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| Series: | Journal of Taibah University for Science |
| Subjects: | |
| Online Access: | http://dx.doi.org/10.1080/16583655.2018.1465265 |
| Summary: | 2-Bromo-2-perfluoroalkyl acids are converted into the corresponding esters by a reaction of alcoholysis in the 2-chloroethanol. The action of zinc on perfluoroalkylated bromo-esters resulted in the bromine reduction products formation via zinc organic intermediates. When heated at 100°C, for 48 h, in the presence of an excess of zinc, the bromo-esters produce the symmetrical bis(vinyl perfluoroalkyl ester) ethoxide compounds, resulting from the BrZnF elimination reaction, followed by a dimerization reaction. |
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| ISSN: | 1658-3655 |