Dual photoredox and cobalt catalysis enpowers site-selective allylic amination
The development of a highly efficient, selective and atom-economical method for the construction of allylic amines are a challenge in green synthetic chemistry. In a recent work published in Nature Catalysis, Lei, Qi, and co-workers reported that the combination of a photoredox catalyst and cobaloxi...
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| Format: | Article |
| Language: | English |
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KeAi Communications Co. Ltd.
2022-11-01
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| Series: | Green Synthesis and Catalysis |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S266655492200103X |
| _version_ | 1811179779367370752 |
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| author | Guoqing Li Jiarong Chen |
| author_facet | Guoqing Li Jiarong Chen |
| author_sort | Guoqing Li |
| collection | DOAJ |
| description | The development of a highly efficient, selective and atom-economical method for the construction of allylic amines are a challenge in green synthetic chemistry. In a recent work published in Nature Catalysis, Lei, Qi, and co-workers reported that the combination of a photoredox catalyst and cobaloxime catalyst enables site-selective allylic amination of various olefins with secondary alkyl amines, affording the valuable tertiary aliphatic allylamines, without the need for external oxidants. |
| first_indexed | 2024-04-11T06:39:13Z |
| format | Article |
| id | doaj.art-50ca968d7a9f4ecaa7cb29070d714ea2 |
| institution | Directory Open Access Journal |
| issn | 2666-5549 |
| language | English |
| last_indexed | 2024-04-11T06:39:13Z |
| publishDate | 2022-11-01 |
| publisher | KeAi Communications Co. Ltd. |
| record_format | Article |
| series | Green Synthesis and Catalysis |
| spelling | doaj.art-50ca968d7a9f4ecaa7cb29070d714ea22022-12-22T04:39:35ZengKeAi Communications Co. Ltd.Green Synthesis and Catalysis2666-55492022-11-0134306308Dual photoredox and cobalt catalysis enpowers site-selective allylic aminationGuoqing Li0Jiarong Chen1CCNU-uOttawa Joint Research Centre, Key Laboratory of Pesticides & Chemical Biology Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, ChinaCorresponding author.; CCNU-uOttawa Joint Research Centre, Key Laboratory of Pesticides & Chemical Biology Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, ChinaThe development of a highly efficient, selective and atom-economical method for the construction of allylic amines are a challenge in green synthetic chemistry. In a recent work published in Nature Catalysis, Lei, Qi, and co-workers reported that the combination of a photoredox catalyst and cobaloxime catalyst enables site-selective allylic amination of various olefins with secondary alkyl amines, affording the valuable tertiary aliphatic allylamines, without the need for external oxidants.http://www.sciencedirect.com/science/article/pii/S266655492200103XAliphatic allylaminesHydrogen evolutionPhotocatalysisCobaloximeHydrogen atom transfer |
| spellingShingle | Guoqing Li Jiarong Chen Dual photoredox and cobalt catalysis enpowers site-selective allylic amination Green Synthesis and Catalysis Aliphatic allylamines Hydrogen evolution Photocatalysis Cobaloxime Hydrogen atom transfer |
| title | Dual photoredox and cobalt catalysis enpowers site-selective allylic amination |
| title_full | Dual photoredox and cobalt catalysis enpowers site-selective allylic amination |
| title_fullStr | Dual photoredox and cobalt catalysis enpowers site-selective allylic amination |
| title_full_unstemmed | Dual photoredox and cobalt catalysis enpowers site-selective allylic amination |
| title_short | Dual photoredox and cobalt catalysis enpowers site-selective allylic amination |
| title_sort | dual photoredox and cobalt catalysis enpowers site selective allylic amination |
| topic | Aliphatic allylamines Hydrogen evolution Photocatalysis Cobaloxime Hydrogen atom transfer |
| url | http://www.sciencedirect.com/science/article/pii/S266655492200103X |
| work_keys_str_mv | AT guoqingli dualphotoredoxandcobaltcatalysisenpowerssiteselectiveallylicamination AT jiarongchen dualphotoredoxandcobaltcatalysisenpowerssiteselectiveallylicamination |