Research progress in photocatalysis and electrocatalysis of two-dimensional covalent organic framework materials
Two-dimensional covalent organic frameworks (2D COFs) are ideal heterogeneous catalysts, and have been widely used in photocatalysis and electrocatalysis, owing to their high specific surface area, tunable porosity, facile functionalization, highly accessible and dispersed catalytic active sites. St...
| Main Authors: | , , , , , , |
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| Format: | Article |
| Language: | zho |
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Journal of Materials Engineering
2023-05-01
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| Series: | Cailiao gongcheng |
| Subjects: | |
| Online Access: | http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2022.000562 |
| _version_ | 1797822393538838528 |
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| author | ZHAO Dongdong WANG Bing CHONG Yuliang ZHAO Yunqiang ZHANG Junjie QUAN Wenxuan ZHUANG Jinliang |
| author_facet | ZHAO Dongdong WANG Bing CHONG Yuliang ZHAO Yunqiang ZHANG Junjie QUAN Wenxuan ZHUANG Jinliang |
| author_sort | ZHAO Dongdong |
| collection | DOAJ |
| description | Two-dimensional covalent organic frameworks (2D COFs) are ideal heterogeneous catalysts, and have been widely used in photocatalysis and electrocatalysis, owing to their high specific surface area, tunable porosity, facile functionalization, highly accessible and dispersed catalytic active sites. Starting from the rational design strategy of the structure and functionalization of COFs, synthetic methods for 2D COFs were reviewed, including solvothermal synthesis, mechanochemical synthesis, microwave synthesis, ionothermal synthesis, sonochemical synthesis, interfacial synthesis, and room temperature synthesis. Furthermore, recent progress of 2D COFs applications in photocatalysis and electrocatalysis was summarized, including hydrogen evolution reaction, oxygen evolution reaction, oxygen reduction reaction, carbon dioxide reduction reaction, and photo/electrocatalytic organic conversion. Finally, the challenges of 2D COFs in photocatalysis and electrocatalysis were summarized, including high cost of organic ligands, difficulty of industrialization, the use of sacrificial agents, and a cooperative coupling reaction strategy was proposed based on photo/electroorganic synthesis and hydrogen evolution or oxygen evolution reactions. |
| first_indexed | 2024-03-13T10:07:21Z |
| format | Article |
| id | doaj.art-50ebab6854584e8d97a6506add52efba |
| institution | Directory Open Access Journal |
| issn | 1001-4381 |
| language | zho |
| last_indexed | 2024-03-13T10:07:21Z |
| publishDate | 2023-05-01 |
| publisher | Journal of Materials Engineering |
| record_format | Article |
| series | Cailiao gongcheng |
| spelling | doaj.art-50ebab6854584e8d97a6506add52efba2023-05-22T09:10:02ZzhoJournal of Materials EngineeringCailiao gongcheng1001-43812023-05-01515587510.11868/j.issn.1001-4381.2022.00056220230506Research progress in photocatalysis and electrocatalysis of two-dimensional covalent organic framework materialsZHAO Dongdong0WANG Bing1CHONG Yuliang2ZHAO Yunqiang3ZHANG Junjie4QUAN Wenxuan5ZHUANG Jinliang6Key Laboratory of Functional Materials and Chemistry of Guizhou Province, School of Chemistry and Materials Science, Guizhou Normal University, Guiyang 550001, ChinaKey Laboratory of Functional Materials and Chemistry of Guizhou Province, School of Chemistry and Materials Science, Guizhou Normal University, Guiyang 550001, ChinaKey Laboratory of Functional Materials and Chemistry of Guizhou Province, School of Chemistry and Materials Science, Guizhou Normal University, Guiyang 550001, ChinaKey Laboratory of Functional Materials and Chemistry of Guizhou Province, School of Chemistry and Materials Science, Guizhou Normal University, Guiyang 550001, ChinaKey Laboratory of Functional Materials and Chemistry of Guizhou Province, School of Chemistry and Materials Science, Guizhou Normal University, Guiyang 550001, ChinaKey Laboratory of Mountainous Environmental Protection of Guizhou Province, Guizhou Normal University, Guiyang 550001, ChinaKey Laboratory of Functional Materials and Chemistry of Guizhou Province, School of Chemistry and Materials Science, Guizhou Normal University, Guiyang 550001, ChinaTwo-dimensional covalent organic frameworks (2D COFs) are ideal heterogeneous catalysts, and have been widely used in photocatalysis and electrocatalysis, owing to their high specific surface area, tunable porosity, facile functionalization, highly accessible and dispersed catalytic active sites. Starting from the rational design strategy of the structure and functionalization of COFs, synthetic methods for 2D COFs were reviewed, including solvothermal synthesis, mechanochemical synthesis, microwave synthesis, ionothermal synthesis, sonochemical synthesis, interfacial synthesis, and room temperature synthesis. Furthermore, recent progress of 2D COFs applications in photocatalysis and electrocatalysis was summarized, including hydrogen evolution reaction, oxygen evolution reaction, oxygen reduction reaction, carbon dioxide reduction reaction, and photo/electrocatalytic organic conversion. Finally, the challenges of 2D COFs in photocatalysis and electrocatalysis were summarized, including high cost of organic ligands, difficulty of industrialization, the use of sacrificial agents, and a cooperative coupling reaction strategy was proposed based on photo/electroorganic synthesis and hydrogen evolution or oxygen evolution reactions.http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2022.000562two-dimensional covalent organic frameworkphotocatalysiselectrocatalysispost-synthetic modificationcondensation reaction |
| spellingShingle | ZHAO Dongdong WANG Bing CHONG Yuliang ZHAO Yunqiang ZHANG Junjie QUAN Wenxuan ZHUANG Jinliang Research progress in photocatalysis and electrocatalysis of two-dimensional covalent organic framework materials Cailiao gongcheng two-dimensional covalent organic framework photocatalysis electrocatalysis post-synthetic modification condensation reaction |
| title | Research progress in photocatalysis and electrocatalysis of two-dimensional covalent organic framework materials |
| title_full | Research progress in photocatalysis and electrocatalysis of two-dimensional covalent organic framework materials |
| title_fullStr | Research progress in photocatalysis and electrocatalysis of two-dimensional covalent organic framework materials |
| title_full_unstemmed | Research progress in photocatalysis and electrocatalysis of two-dimensional covalent organic framework materials |
| title_short | Research progress in photocatalysis and electrocatalysis of two-dimensional covalent organic framework materials |
| title_sort | research progress in photocatalysis and electrocatalysis of two dimensional covalent organic framework materials |
| topic | two-dimensional covalent organic framework photocatalysis electrocatalysis post-synthetic modification condensation reaction |
| url | http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2022.000562 |
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