Activity of Mono-, Bi-, and Trimetallic Catalysts Pt-Ni-Cr/C in the Bicyclohexyl Dehydrogenation Reaction
The influence of metals with different redox properties and a carbon carrier on the activity of mono-, bi- and trimetallic Pt-Ni-Cr/C catalysts has been studied in the bicyclohexyl dehydrogenation reaction as the hydrogen release stage in hydrogen storage. An increase in the conversion (X > 62%)...
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| Format: | Article |
| Language: | English |
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MDPI AG
2022-12-01
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| Series: | Molecules |
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| Online Access: | https://www.mdpi.com/1420-3049/27/23/8416 |
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| author | Alexander N. Kalenchuk Leonid M. Kustov |
| author_facet | Alexander N. Kalenchuk Leonid M. Kustov |
| author_sort | Alexander N. Kalenchuk |
| collection | DOAJ |
| description | The influence of metals with different redox properties and a carbon carrier on the activity of mono-, bi- and trimetallic Pt-Ni-Cr/C catalysts has been studied in the bicyclohexyl dehydrogenation reaction as the hydrogen release stage in hydrogen storage. An increase in the conversion (X > 62%) of bicyclohexyl and selectivity for biphenyl (S > 84%) was observed on trimetallic catalysts Pt-Ni-Cr/C compared with the monometallic catalyst Rt/C (X > 55%; S > 68%). It has been established that the increase in the conversion of bicyclohexyl and selectivity for biphenyl in the dehydrogenation reaction on trimetallic catalysts is due to an increase in the activity of Pt nanoparticles in the vicinity of local Cr-Ni clusters of solid substitution solutions. |
| first_indexed | 2024-03-09T17:39:33Z |
| format | Article |
| id | doaj.art-510333eccd064815946fc74297c79229 |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-03-09T17:39:33Z |
| publishDate | 2022-12-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-510333eccd064815946fc74297c792292023-11-24T11:41:52ZengMDPI AGMolecules1420-30492022-12-012723841610.3390/molecules27238416Activity of Mono-, Bi-, and Trimetallic Catalysts Pt-Ni-Cr/C in the Bicyclohexyl Dehydrogenation ReactionAlexander N. Kalenchuk0Leonid M. Kustov1Chemistry Department, Moscow State University, 1 Leninskie Gory, Bldg. 3, 119991 Moscow, RussiaChemistry Department, Moscow State University, 1 Leninskie Gory, Bldg. 3, 119991 Moscow, RussiaThe influence of metals with different redox properties and a carbon carrier on the activity of mono-, bi- and trimetallic Pt-Ni-Cr/C catalysts has been studied in the bicyclohexyl dehydrogenation reaction as the hydrogen release stage in hydrogen storage. An increase in the conversion (X > 62%) of bicyclohexyl and selectivity for biphenyl (S > 84%) was observed on trimetallic catalysts Pt-Ni-Cr/C compared with the monometallic catalyst Rt/C (X > 55%; S > 68%). It has been established that the increase in the conversion of bicyclohexyl and selectivity for biphenyl in the dehydrogenation reaction on trimetallic catalysts is due to an increase in the activity of Pt nanoparticles in the vicinity of local Cr-Ni clusters of solid substitution solutions.https://www.mdpi.com/1420-3049/27/23/8416hydrogen storagebicyclohexyldehydrogenationPtNiCr/C catalysts |
| spellingShingle | Alexander N. Kalenchuk Leonid M. Kustov Activity of Mono-, Bi-, and Trimetallic Catalysts Pt-Ni-Cr/C in the Bicyclohexyl Dehydrogenation Reaction Molecules hydrogen storage bicyclohexyl dehydrogenation PtNiCr/C catalysts |
| title | Activity of Mono-, Bi-, and Trimetallic Catalysts Pt-Ni-Cr/C in the Bicyclohexyl Dehydrogenation Reaction |
| title_full | Activity of Mono-, Bi-, and Trimetallic Catalysts Pt-Ni-Cr/C in the Bicyclohexyl Dehydrogenation Reaction |
| title_fullStr | Activity of Mono-, Bi-, and Trimetallic Catalysts Pt-Ni-Cr/C in the Bicyclohexyl Dehydrogenation Reaction |
| title_full_unstemmed | Activity of Mono-, Bi-, and Trimetallic Catalysts Pt-Ni-Cr/C in the Bicyclohexyl Dehydrogenation Reaction |
| title_short | Activity of Mono-, Bi-, and Trimetallic Catalysts Pt-Ni-Cr/C in the Bicyclohexyl Dehydrogenation Reaction |
| title_sort | activity of mono bi and trimetallic catalysts pt ni cr c in the bicyclohexyl dehydrogenation reaction |
| topic | hydrogen storage bicyclohexyl dehydrogenation PtNiCr/C catalysts |
| url | https://www.mdpi.com/1420-3049/27/23/8416 |
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