Corrosion Resistance of Titanium Alloys Anodized in Alkaline Solutions

Titanium alloys present superior electrochemical properties due to the generation of the TiO<sub>2</sub> passive layer. The ability to generate an oxide passive layer depends on the anodized alloy. This work mainly studies the corrosion resistance of the alloys Ti-6Al-2Sn-4Zr-2Mo and Ti-...

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Bibliographic Details
Main Authors: Facundo Almeraya-Calderón, Jesús M. Jáquez-Muñoz, Erick Maldonado-Bandala, Jose Cabral-Miramontes, Demetrio Nieves-Mendoza, Javier Olgui-Coca, Luis Daimir Lopez-Leon, Francisco Estupiñán-López, Alejandro Lira-Martínez, Citlalli Gaona Tiburcio
Format: Article
Language:English
Published: MDPI AG 2023-08-01
Series:Metals
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Online Access:https://www.mdpi.com/2075-4701/13/9/1510
Description
Summary:Titanium alloys present superior electrochemical properties due to the generation of the TiO<sub>2</sub> passive layer. The ability to generate an oxide passive layer depends on the anodized alloy. This work mainly studies the corrosion resistance of the alloys Ti-6Al-2Sn-4Zr-2Mo and Ti-6Al-4V anodized in NaOH and KOH at 1 M and 0.025 A/cm<sup>2</sup> of current density. The electrochemical techniques were performed in a conventional three-electrode cell exposed to electrolytes of NaCl and H<sub>2</sub>SO<sub>4</sub>. Based on ASTM-G61 and G199, cyclic potentiodynamic polarization (CPP) and electrochemical noise (EN) techniques were used. The results indicated that Ti-6Al-2Sn-4Zr-2Mo anodized on NaOH presented a higher passivity range than anodized on KOH, relating to the high reactivity of Na<sup>+</sup> ions. The former anodized alloy also demonstrated a higher passive layer rupture potential. In EN, the results showed that Ti-6Al-4V anodized in KOH presented a trend toward a localized process due to the heterogeneity of anodized porosity and the presence of V in the alloy.
ISSN:2075-4701