SYNTHESIS AND PHOTO- IRRADIATION OF SOME PYRIMIDINE AND PURINE DERIVATIVES
The current study included the synthesis of a series of azo compounds. These compounds were prepared by coupling nitrogen bases with phenyl diazonium salts. While the azo Schiff compounds were prepared by direct condensation of the prepared azoaldehydes with the nitrogen bases (2-amino pyrimidine &a...
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| Format: | Article |
| Language: | English |
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University of Anbar
2012-10-01
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| Series: | مجلة جامعة الانبار للعلوم الصرفة |
| Online Access: | https://juaps.uoanbar.edu.iq/article_62394_9cf2638fa1f6fad3ac762a88eb133eaa.pdf |
| _version_ | 1827396234765139968 |
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| author | HAMEED H. ALI SALMAN A. AHMED ISMAIL ALKHATEEB |
| author_facet | HAMEED H. ALI SALMAN A. AHMED ISMAIL ALKHATEEB |
| author_sort | HAMEED H. ALI |
| collection | DOAJ |
| description | The current study included the synthesis of a series of azo compounds. These compounds were prepared by coupling nitrogen bases with phenyl diazonium salts. While the azo Schiff compounds were prepared by direct condensation of the prepared azoaldehydes with the nitrogen bases (2-amino pyrimidine & guanine ). The Schiff base derivatives were prepared by direct condensation of nitrogen bases (2-amino pyrimidine & adenine) with substituted benzaldehyde and chloral.The structures of the prepared compounds were confirmed by spectral analysis including ultra-violet visible and infra red spectra. Also photo irradiation of these compounds at (=356nm) has been done to study the stability of these compounds. The results revealed complete disappearance of the (OH) and (NH) bands in a number of compounds and partial disappearance in others which reflects the photo-oxidation or hydrogen bonding for the groups of (OH) or (NH).The disappearance of the (NH2) and (C=O) bands conforms the successful of prepared compounds. |
| first_indexed | 2024-03-08T18:47:58Z |
| format | Article |
| id | doaj.art-514eafe5460e4c08b2718d0c59645768 |
| institution | Directory Open Access Journal |
| issn | 1991-8941 2706-6703 |
| language | English |
| last_indexed | 2024-03-08T18:47:58Z |
| publishDate | 2012-10-01 |
| publisher | University of Anbar |
| record_format | Article |
| series | مجلة جامعة الانبار للعلوم الصرفة |
| spelling | doaj.art-514eafe5460e4c08b2718d0c596457682023-12-28T21:55:58ZengUniversity of Anbarمجلة جامعة الانبار للعلوم الصرفة1991-89412706-67032012-10-0161869910.37652/juaps.2012.6239462394SYNTHESIS AND PHOTO- IRRADIATION OF SOME PYRIMIDINE AND PURINE DERIVATIVESHAMEED H. ALI0SALMAN A. AHMED1ISMAIL ALKHATEEB2University of Anbar - College of ScienceAl-Nahrain University - College of ScienceUniversity of Anbar - College of ScienceThe current study included the synthesis of a series of azo compounds. These compounds were prepared by coupling nitrogen bases with phenyl diazonium salts. While the azo Schiff compounds were prepared by direct condensation of the prepared azoaldehydes with the nitrogen bases (2-amino pyrimidine & guanine ). The Schiff base derivatives were prepared by direct condensation of nitrogen bases (2-amino pyrimidine & adenine) with substituted benzaldehyde and chloral.The structures of the prepared compounds were confirmed by spectral analysis including ultra-violet visible and infra red spectra. Also photo irradiation of these compounds at (=356nm) has been done to study the stability of these compounds. The results revealed complete disappearance of the (OH) and (NH) bands in a number of compounds and partial disappearance in others which reflects the photo-oxidation or hydrogen bonding for the groups of (OH) or (NH).The disappearance of the (NH2) and (C=O) bands conforms the successful of prepared compounds.https://juaps.uoanbar.edu.iq/article_62394_9cf2638fa1f6fad3ac762a88eb133eaa.pdf |
| spellingShingle | HAMEED H. ALI SALMAN A. AHMED ISMAIL ALKHATEEB SYNTHESIS AND PHOTO- IRRADIATION OF SOME PYRIMIDINE AND PURINE DERIVATIVES مجلة جامعة الانبار للعلوم الصرفة |
| title | SYNTHESIS AND PHOTO- IRRADIATION OF SOME PYRIMIDINE AND PURINE DERIVATIVES |
| title_full | SYNTHESIS AND PHOTO- IRRADIATION OF SOME PYRIMIDINE AND PURINE DERIVATIVES |
| title_fullStr | SYNTHESIS AND PHOTO- IRRADIATION OF SOME PYRIMIDINE AND PURINE DERIVATIVES |
| title_full_unstemmed | SYNTHESIS AND PHOTO- IRRADIATION OF SOME PYRIMIDINE AND PURINE DERIVATIVES |
| title_short | SYNTHESIS AND PHOTO- IRRADIATION OF SOME PYRIMIDINE AND PURINE DERIVATIVES |
| title_sort | synthesis and photo irradiation of some pyrimidine and purine derivatives |
| url | https://juaps.uoanbar.edu.iq/article_62394_9cf2638fa1f6fad3ac762a88eb133eaa.pdf |
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