Enhanced thermoelectric performance of UV-curable silver (I) selenide-based composite for energy harvesting

Abstract Thermoelectric (TE) composites, with photocured resin as the matrix and Ag2Se (AS) as the filler, are synthesized by a digital-light-processing (DLP) based 3D printer. The mixture of diurethane dimethacrylate (DUDMA) and isobornyl acrylate (IBOA) is used as a UV-curable resin because of the...

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Main Authors: Dabin Park, Seonmin Lee, Jooheon Kim
Format: Article
Language:English
Published: Nature Portfolio 2021-08-01
Series:Scientific Reports
Online Access:https://doi.org/10.1038/s41598-021-96267-x
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author Dabin Park
Seonmin Lee
Jooheon Kim
author_facet Dabin Park
Seonmin Lee
Jooheon Kim
author_sort Dabin Park
collection DOAJ
description Abstract Thermoelectric (TE) composites, with photocured resin as the matrix and Ag2Se (AS) as the filler, are synthesized by a digital-light-processing (DLP) based 3D printer. The mixture of diurethane dimethacrylate (DUDMA) and isobornyl acrylate (IBOA) is used as a UV-curable resin because of their low viscosity and high miscibility. Scanning electron microscopy (FE-SEM) images confirm that the filler retains its shape and remains after the UV-curing process. After completing curing, the mechanical and thermoelectric properties of the composite with different AS contents were measured. The addition of the AS filler increases the thermoelectric properties of the cured resin. When the AS contents increase by 30 wt.%, the maximum power factor was obtained (~ 51.5 μW/m·K2 at room temperature). Additionally, due to the phonon scattering effect between the interfaces, the thermal conductivity of composite is lower than that of pristine photoresin. The maximum thermoelectric figure of merit (ZT) is ~ 0.12, which is achieved with 30 wt.% of AS at 300 K with the enhanced power factor and reduced thermal conductivity. This study presents a novel manufacturing method for a thermoelectric composite using 3D printing.
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spelling doaj.art-515f9c91e971496da89babf01e0fb2282022-12-21T21:35:19ZengNature PortfolioScientific Reports2045-23222021-08-011111810.1038/s41598-021-96267-xEnhanced thermoelectric performance of UV-curable silver (I) selenide-based composite for energy harvestingDabin Park0Seonmin Lee1Jooheon Kim2School of Chemical Engineering & Materials Science, Chung-Ang UniversitySchool of Chemical Engineering & Materials Science, Chung-Ang UniversitySchool of Chemical Engineering & Materials Science, Chung-Ang UniversityAbstract Thermoelectric (TE) composites, with photocured resin as the matrix and Ag2Se (AS) as the filler, are synthesized by a digital-light-processing (DLP) based 3D printer. The mixture of diurethane dimethacrylate (DUDMA) and isobornyl acrylate (IBOA) is used as a UV-curable resin because of their low viscosity and high miscibility. Scanning electron microscopy (FE-SEM) images confirm that the filler retains its shape and remains after the UV-curing process. After completing curing, the mechanical and thermoelectric properties of the composite with different AS contents were measured. The addition of the AS filler increases the thermoelectric properties of the cured resin. When the AS contents increase by 30 wt.%, the maximum power factor was obtained (~ 51.5 μW/m·K2 at room temperature). Additionally, due to the phonon scattering effect between the interfaces, the thermal conductivity of composite is lower than that of pristine photoresin. The maximum thermoelectric figure of merit (ZT) is ~ 0.12, which is achieved with 30 wt.% of AS at 300 K with the enhanced power factor and reduced thermal conductivity. This study presents a novel manufacturing method for a thermoelectric composite using 3D printing.https://doi.org/10.1038/s41598-021-96267-x
spellingShingle Dabin Park
Seonmin Lee
Jooheon Kim
Enhanced thermoelectric performance of UV-curable silver (I) selenide-based composite for energy harvesting
Scientific Reports
title Enhanced thermoelectric performance of UV-curable silver (I) selenide-based composite for energy harvesting
title_full Enhanced thermoelectric performance of UV-curable silver (I) selenide-based composite for energy harvesting
title_fullStr Enhanced thermoelectric performance of UV-curable silver (I) selenide-based composite for energy harvesting
title_full_unstemmed Enhanced thermoelectric performance of UV-curable silver (I) selenide-based composite for energy harvesting
title_short Enhanced thermoelectric performance of UV-curable silver (I) selenide-based composite for energy harvesting
title_sort enhanced thermoelectric performance of uv curable silver i selenide based composite for energy harvesting
url https://doi.org/10.1038/s41598-021-96267-x
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AT seonminlee enhancedthermoelectricperformanceofuvcurablesilveriselenidebasedcompositeforenergyharvesting
AT jooheonkim enhancedthermoelectricperformanceofuvcurablesilveriselenidebasedcompositeforenergyharvesting