Bis[1-(3,5-di-tert-butyl-2-hydroxybenzyl)-3-isopropylimidazolium] pentachlorido(tetrahydrofuran)samarate(III)–tetrahydrofuran–toluene (1/1/1)
The title compound, (C21H33N2O)2[SmCl5(C4H8O)]·C7H8·C4H8O, has a layered structure in which each distorted octahedral [SmCl5(THF)]2− unit (THF is tetrahydrofuran) is capped by two cations. The central metal SmIII atom of the [SmCl5(THF)]2− anioni...
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-06-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810017678 |
| _version_ | 1818999622087999488 |
|---|---|
| author | Zhiguo Wang Siman Liu Qinquan Bian |
| author_facet | Zhiguo Wang Siman Liu Qinquan Bian |
| author_sort | Zhiguo Wang |
| collection | DOAJ |
| description | The title compound, (C21H33N2O)2[SmCl5(C4H8O)]·C7H8·C4H8O, has a layered structure in which each distorted octahedral [SmCl5(THF)]2− unit (THF is tetrahydrofuran) is capped by two cations. The central metal SmIII atom of the [SmCl5(THF)]2− anionic unit is coordinated by five Cl atoms and one THF O atom, forming a distorted octahedral geometry. The crystal structure displays C—H...Cl and O—H...Cl hydrogen bonding. The structure exhibits disorder of the solvent. |
| first_indexed | 2024-12-20T22:20:21Z |
| format | Article |
| id | doaj.art-5175439c88ab441ea7e2bf30f2675d7f |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T22:20:21Z |
| publishDate | 2010-06-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-5175439c88ab441ea7e2bf30f2675d7f2022-12-21T19:24:57ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-06-01666m683m68310.1107/S1600536810017678Bis[1-(3,5-di-tert-butyl-2-hydroxybenzyl)-3-isopropylimidazolium] pentachlorido(tetrahydrofuran)samarate(III)–tetrahydrofuran–toluene (1/1/1)Zhiguo WangSiman LiuQinquan BianThe title compound, (C21H33N2O)2[SmCl5(C4H8O)]·C7H8·C4H8O, has a layered structure in which each distorted octahedral [SmCl5(THF)]2− unit (THF is tetrahydrofuran) is capped by two cations. The central metal SmIII atom of the [SmCl5(THF)]2− anionic unit is coordinated by five Cl atoms and one THF O atom, forming a distorted octahedral geometry. The crystal structure displays C—H...Cl and O—H...Cl hydrogen bonding. The structure exhibits disorder of the solvent.http://scripts.iucr.org/cgi-bin/paper?S1600536810017678 |
| spellingShingle | Zhiguo Wang Siman Liu Qinquan Bian Bis[1-(3,5-di-tert-butyl-2-hydroxybenzyl)-3-isopropylimidazolium] pentachlorido(tetrahydrofuran)samarate(III)–tetrahydrofuran–toluene (1/1/1) Acta Crystallographica Section E |
| title | Bis[1-(3,5-di-tert-butyl-2-hydroxybenzyl)-3-isopropylimidazolium] pentachlorido(tetrahydrofuran)samarate(III)–tetrahydrofuran–toluene (1/1/1) |
| title_full | Bis[1-(3,5-di-tert-butyl-2-hydroxybenzyl)-3-isopropylimidazolium] pentachlorido(tetrahydrofuran)samarate(III)–tetrahydrofuran–toluene (1/1/1) |
| title_fullStr | Bis[1-(3,5-di-tert-butyl-2-hydroxybenzyl)-3-isopropylimidazolium] pentachlorido(tetrahydrofuran)samarate(III)–tetrahydrofuran–toluene (1/1/1) |
| title_full_unstemmed | Bis[1-(3,5-di-tert-butyl-2-hydroxybenzyl)-3-isopropylimidazolium] pentachlorido(tetrahydrofuran)samarate(III)–tetrahydrofuran–toluene (1/1/1) |
| title_short | Bis[1-(3,5-di-tert-butyl-2-hydroxybenzyl)-3-isopropylimidazolium] pentachlorido(tetrahydrofuran)samarate(III)–tetrahydrofuran–toluene (1/1/1) |
| title_sort | bis 1 3 5 di tert butyl 2 hydroxybenzyl 3 isopropylimidazolium pentachlorido tetrahydrofuran samarate iii amp 8211 tetrahydrofuran amp 8211 toluene 1 1 1 |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810017678 |
| work_keys_str_mv | AT zhiguowang bis135ditertbutyl2hydroxybenzyl3isopropylimidazoliumpentachloridotetrahydrofuransamarateiiiamp8211tetrahydrofuranamp8211toluene111 AT simanliu bis135ditertbutyl2hydroxybenzyl3isopropylimidazoliumpentachloridotetrahydrofuransamarateiiiamp8211tetrahydrofuranamp8211toluene111 AT qinquanbian bis135ditertbutyl2hydroxybenzyl3isopropylimidazoliumpentachloridotetrahydrofuransamarateiiiamp8211tetrahydrofuranamp8211toluene111 |