| Summary: | The main goal of the present work was to synthesize a composite consisting of h-BN particles coated with a γ-Al<sub>2</sub>O<sub>3</sub> nanolayer. A method was proposed for applying nanocrystalline γ-Al<sub>2</sub>O<sub>3</sub> to h-BN particles using a sol–gel technique, which ensures the chemical homogeneity of the composite at the nano level. It has been determined that during crystallization on the h-BN surface, the proportion of spinel in alumina decreases from 40 wt.% in pure γ-Al<sub>2</sub>O<sub>3</sub> to 30 wt.% as a result of the involvement of the B<sup>3+</sup> ions from the surface nitride monolayers into the transition complex. For comparison, nano-alumina was synthesized from the same sol under the same conditions as the composite. The characterization of the obtained nanostructured powders was carried out using TEM and XRD. A mechanism is proposed for the formation of a nanostructured γ-Al<sub>2</sub>O<sub>3</sub>@h-BN composite during the interaction of Al-containing sol and h-BN suspension in aqueous organic media. The resulting composite is a promising model of powdered raw materials for the development of fine-grained ceramic materials for a wide range of applications.
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