Hydrogen Transfer Reactions of Carbonyls, Alkynes, and Alkenes with Noble Metals in the Presence of Alcohols/Ethers and Amines as Hydrogen Donors
Hydrogen transfer reactions have exceptional importance, due to their applicability in numerous synthetic pathways, with academic as well as industrial relevance. The most important transformations are, e.g., reduction, ring-closing, stereoselective reactions, and the synthesis of heterocycles. The...
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| Format: | Article |
| Language: | English |
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MDPI AG
2018-12-01
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| Series: | Catalysts |
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| Online Access: | https://www.mdpi.com/2073-4344/8/12/671 |
| _version_ | 1811256696347033600 |
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| author | Eszter Baráth |
| author_facet | Eszter Baráth |
| author_sort | Eszter Baráth |
| collection | DOAJ |
| description | Hydrogen transfer reactions have exceptional importance, due to their applicability in numerous synthetic pathways, with academic as well as industrial relevance. The most important transformations are, e.g., reduction, ring-closing, stereoselective reactions, and the synthesis of heterocycles. The present review provides insights into the hydrogen transfer reactions in the condensed phase in the presence of noble metals (Rh, Ru, Pd) as catalysts. Since the H-donor molecules (such as alcohols/ethers and amines (1°, 2°, 3°)) and the acceptor molecules (alkenes (C=C), alkynes (C≡C), and carbonyl (C=O) compounds) play a crucial role from mechanistic viewpoints, the present summary points out the key mechanistic differences with the interpretation of current contributions and the corresponding historical achievements as well. |
| first_indexed | 2024-04-12T17:44:03Z |
| format | Article |
| id | doaj.art-518e9410a4f447faa8452d2dd9c3e3ba |
| institution | Directory Open Access Journal |
| issn | 2073-4344 |
| language | English |
| last_indexed | 2024-04-12T17:44:03Z |
| publishDate | 2018-12-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Catalysts |
| spelling | doaj.art-518e9410a4f447faa8452d2dd9c3e3ba2022-12-22T03:22:42ZengMDPI AGCatalysts2073-43442018-12-0181267110.3390/catal8120671catal8120671Hydrogen Transfer Reactions of Carbonyls, Alkynes, and Alkenes with Noble Metals in the Presence of Alcohols/Ethers and Amines as Hydrogen DonorsEszter Baráth0Department of Chemistry and Catalysis Research Center, Technische Universität München, Lichtenbergstr. 4, D-85748 Garching, GermanyHydrogen transfer reactions have exceptional importance, due to their applicability in numerous synthetic pathways, with academic as well as industrial relevance. The most important transformations are, e.g., reduction, ring-closing, stereoselective reactions, and the synthesis of heterocycles. The present review provides insights into the hydrogen transfer reactions in the condensed phase in the presence of noble metals (Rh, Ru, Pd) as catalysts. Since the H-donor molecules (such as alcohols/ethers and amines (1°, 2°, 3°)) and the acceptor molecules (alkenes (C=C), alkynes (C≡C), and carbonyl (C=O) compounds) play a crucial role from mechanistic viewpoints, the present summary points out the key mechanistic differences with the interpretation of current contributions and the corresponding historical achievements as well.https://www.mdpi.com/2073-4344/8/12/671hydrogen transferasymmetric hydrogen transferhydridenoble metalsalcoholsamines |
| spellingShingle | Eszter Baráth Hydrogen Transfer Reactions of Carbonyls, Alkynes, and Alkenes with Noble Metals in the Presence of Alcohols/Ethers and Amines as Hydrogen Donors Catalysts hydrogen transfer asymmetric hydrogen transfer hydride noble metals alcohols amines |
| title | Hydrogen Transfer Reactions of Carbonyls, Alkynes, and Alkenes with Noble Metals in the Presence of Alcohols/Ethers and Amines as Hydrogen Donors |
| title_full | Hydrogen Transfer Reactions of Carbonyls, Alkynes, and Alkenes with Noble Metals in the Presence of Alcohols/Ethers and Amines as Hydrogen Donors |
| title_fullStr | Hydrogen Transfer Reactions of Carbonyls, Alkynes, and Alkenes with Noble Metals in the Presence of Alcohols/Ethers and Amines as Hydrogen Donors |
| title_full_unstemmed | Hydrogen Transfer Reactions of Carbonyls, Alkynes, and Alkenes with Noble Metals in the Presence of Alcohols/Ethers and Amines as Hydrogen Donors |
| title_short | Hydrogen Transfer Reactions of Carbonyls, Alkynes, and Alkenes with Noble Metals in the Presence of Alcohols/Ethers and Amines as Hydrogen Donors |
| title_sort | hydrogen transfer reactions of carbonyls alkynes and alkenes with noble metals in the presence of alcohols ethers and amines as hydrogen donors |
| topic | hydrogen transfer asymmetric hydrogen transfer hydride noble metals alcohols amines |
| url | https://www.mdpi.com/2073-4344/8/12/671 |
| work_keys_str_mv | AT eszterbarath hydrogentransferreactionsofcarbonylsalkynesandalkeneswithnoblemetalsinthepresenceofalcoholsethersandaminesashydrogendonors |