Modeling of optical properties of hybrid metal-organic nanostructures

To model spectral characteristics of hybrid metal-organic nanostructures, the extended Mie theory was used, which makes it possible to calculate the extinction efficiency factor (Qext) and the scattering efficiency factor in the near zone (QNF) of two-layer spherical particles placed in an absorbing...

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Main Authors: A. N. Ponyavina, K. A. Barbarchyk, A. D. Zamkovets, S. A. Tikhomirov
Format: Article
Language:Russian
Published: Educational institution «Belarusian State University of Informatics and Radioelectronics» 2022-01-01
Series:Doklady Belorusskogo gosudarstvennogo universiteta informatiki i radioèlektroniki
Subjects:
Online Access:https://doklady.bsuir.by/jour/article/view/3238
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author A. N. Ponyavina
K. A. Barbarchyk
A. D. Zamkovets
S. A. Tikhomirov
author_facet A. N. Ponyavina
K. A. Barbarchyk
A. D. Zamkovets
S. A. Tikhomirov
author_sort A. N. Ponyavina
collection DOAJ
description To model spectral characteristics of hybrid metal-organic nanostructures, the extended Mie theory was used, which makes it possible to calculate the extinction efficiency factor (Qext) and the scattering efficiency factor in the near zone (QNF) of two-layer spherical particles placed in an absorbing matrix. Two-layer plasmon nanospheres consisting of a metallic core (Ag, Cu) coated with dielectric shells and located into the copper phthalocyanine (CuPc) matrix were considered. The influence of dielectric shell thickness and refractive index on the characteristics of the surface plasmon resonance of absorption (SPRA) was studied. The possibility of the SPRA band tuning by changing the optical and geometrical parameters of dielectric shells was shown. It was established that dielectric shells allow to shift the surface plasmon resonance band of plasmonic  nanoparticles absorption both  to  short-  and  long-wavelength  spectral  range  depending on the relation between shell and matrix refractive indexes.
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spelling doaj.art-51a68c504f5f4a549e93a2b3b39153532023-03-13T07:33:22ZrusEducational institution «Belarusian State University of Informatics and Radioelectronics»Doklady Belorusskogo gosudarstvennogo universiteta informatiki i radioèlektroniki1729-76482022-01-01198151910.35596/1729-7648-2021-19-8-15-191756Modeling of optical properties of hybrid metal-organic nanostructuresA. N. Ponyavina0K. A. Barbarchyk1A. D. Zamkovets2S. A. Tikhomirov3B.I. Stepanov Institute of Physics of the National Academy of Sciences of BelarusB.I. Stepanov Institute of Physics of the National Academy of Sciences of BelarusB.I. Stepanov Institute of Physics of the National Academy of Sciences of BelarusB.I. Stepanov Institute of Physics of the National Academy of Sciences of BelarusTo model spectral characteristics of hybrid metal-organic nanostructures, the extended Mie theory was used, which makes it possible to calculate the extinction efficiency factor (Qext) and the scattering efficiency factor in the near zone (QNF) of two-layer spherical particles placed in an absorbing matrix. Two-layer plasmon nanospheres consisting of a metallic core (Ag, Cu) coated with dielectric shells and located into the copper phthalocyanine (CuPc) matrix were considered. The influence of dielectric shell thickness and refractive index on the characteristics of the surface plasmon resonance of absorption (SPRA) was studied. The possibility of the SPRA band tuning by changing the optical and geometrical parameters of dielectric shells was shown. It was established that dielectric shells allow to shift the surface plasmon resonance band of plasmonic  nanoparticles absorption both  to  short-  and  long-wavelength  spectral  range  depending on the relation between shell and matrix refractive indexes.https://doklady.bsuir.by/jour/article/view/3238surface plasmon resonancehybrid nanostructures
spellingShingle A. N. Ponyavina
K. A. Barbarchyk
A. D. Zamkovets
S. A. Tikhomirov
Modeling of optical properties of hybrid metal-organic nanostructures
Doklady Belorusskogo gosudarstvennogo universiteta informatiki i radioèlektroniki
surface plasmon resonance
hybrid nanostructures
title Modeling of optical properties of hybrid metal-organic nanostructures
title_full Modeling of optical properties of hybrid metal-organic nanostructures
title_fullStr Modeling of optical properties of hybrid metal-organic nanostructures
title_full_unstemmed Modeling of optical properties of hybrid metal-organic nanostructures
title_short Modeling of optical properties of hybrid metal-organic nanostructures
title_sort modeling of optical properties of hybrid metal organic nanostructures
topic surface plasmon resonance
hybrid nanostructures
url https://doklady.bsuir.by/jour/article/view/3238
work_keys_str_mv AT anponyavina modelingofopticalpropertiesofhybridmetalorganicnanostructures
AT kabarbarchyk modelingofopticalpropertiesofhybridmetalorganicnanostructures
AT adzamkovets modelingofopticalpropertiesofhybridmetalorganicnanostructures
AT satikhomirov modelingofopticalpropertiesofhybridmetalorganicnanostructures