Detection and Analysis of Microfibers and Microplastics in Wastewater from a Textile Company

Textile wastewater is polluted by inorganic/organic substances, polymers, dyes, and microfibers (MFs), which are microplastics (MPs) and natural fibers. This work is aimed at the preliminary investigation of MFs and MPs in textile industrial wastewater, and at evaluating the removal efficiency of an...

Full description

Bibliographic Details
Main Authors: Sinem Hazal Akyildiz, Rossana Bellopede, Hande Sezgin, Ipek Yalcin-Enis, Bahattin Yalcin, Silvia Fiore
Format: Article
Language:English
Published: MDPI AG 2022-10-01
Series:Microplastics
Subjects:
Online Access:https://www.mdpi.com/2673-8929/1/4/40
_version_ 1797438447208628224
author Sinem Hazal Akyildiz
Rossana Bellopede
Hande Sezgin
Ipek Yalcin-Enis
Bahattin Yalcin
Silvia Fiore
author_facet Sinem Hazal Akyildiz
Rossana Bellopede
Hande Sezgin
Ipek Yalcin-Enis
Bahattin Yalcin
Silvia Fiore
author_sort Sinem Hazal Akyildiz
collection DOAJ
description Textile wastewater is polluted by inorganic/organic substances, polymers, dyes, and microfibers (MFs), which are microplastics (MPs) and natural fibers. This work is aimed at the preliminary investigation of MFs and MPs in textile industrial wastewater, and at evaluating the removal efficiency of an on-site wastewater treatment plant (WWTP). Ten samples of inflows and outflows of the WWTP of a textile company (applying a physic-chemical process) have been analyzed. Firstly, the samples underwent a pretreatment with 15% hydrogen peroxide at 25 °C for 5 days to remove organic compounds. Secondly, the MFs were recovered from the aqueous phase by pre-screening centrifugation, density separation, and filtration as alternative options. Filtration obtained the best performances, compared to the other recovery processes. Thirdly, the MFs were counted through optical microscopy and the MPs were identified through micro-FTIR. The MFs amount in the inflow samples was in the range of 893–4452 MFs/L. The outflow samples (310–2404 MFs/L) exhibited a 38–65% reduction compared to the inflows, demonstrating that up to 62% of residual MFs can enter the sewer network or the receiving water body. Cotton and wool, and numerous MPs (acrylic, polyester, polypropylene, polyamide, and viscose/rayon) were identified in the inflow and outflow samples (with the only exception of “dense” viscose (rayon), not detected in the outflows, and probably retained by the WWTP with the sludge). This study, even if just preliminary, offers interesting hints for future research on MFs/MPs detection in textile wastewater, and on the performance of a full-scale WWT process for their removal.
first_indexed 2024-03-09T11:38:02Z
format Article
id doaj.art-51b3d4432d744d60817d56feb01e797d
institution Directory Open Access Journal
issn 2673-8929
language English
last_indexed 2024-03-09T11:38:02Z
publishDate 2022-10-01
publisher MDPI AG
record_format Article
series Microplastics
spelling doaj.art-51b3d4432d744d60817d56feb01e797d2023-11-30T23:38:20ZengMDPI AGMicroplastics2673-89292022-10-011457258610.3390/microplastics1040040Detection and Analysis of Microfibers and Microplastics in Wastewater from a Textile CompanySinem Hazal Akyildiz0Rossana Bellopede1Hande Sezgin2Ipek Yalcin-Enis3Bahattin Yalcin4Silvia Fiore5Department of Textile Engineering, Faculty of Technology, Marmara University, Göztepe Campus, 34722 Istanbul, TurkeyDepartment of Engineering for Environment, Land and Infrastructures, Politecnico di Torino, 10129 Torino, ItalyDepartment of Textile Engineering, Technologies and Design Faculty, Istanbul Technical University, Gumussuyu Campus, 34437 Istanbul, TurkeyDepartment of Textile Engineering, Technologies and Design Faculty, Istanbul Technical University, Gumussuyu Campus, 34437 Istanbul, TurkeyDepartment of Chemistry, Faculty of Science, Marmara University, Göztepe Campus, 34722 Istanbul, TurkeyDepartment of Engineering for Environment, Land and Infrastructures, Politecnico di Torino, 10129 Torino, ItalyTextile wastewater is polluted by inorganic/organic substances, polymers, dyes, and microfibers (MFs), which are microplastics (MPs) and natural fibers. This work is aimed at the preliminary investigation of MFs and MPs in textile industrial wastewater, and at evaluating the removal efficiency of an on-site wastewater treatment plant (WWTP). Ten samples of inflows and outflows of the WWTP of a textile company (applying a physic-chemical process) have been analyzed. Firstly, the samples underwent a pretreatment with 15% hydrogen peroxide at 25 °C for 5 days to remove organic compounds. Secondly, the MFs were recovered from the aqueous phase by pre-screening centrifugation, density separation, and filtration as alternative options. Filtration obtained the best performances, compared to the other recovery processes. Thirdly, the MFs were counted through optical microscopy and the MPs were identified through micro-FTIR. The MFs amount in the inflow samples was in the range of 893–4452 MFs/L. The outflow samples (310–2404 MFs/L) exhibited a 38–65% reduction compared to the inflows, demonstrating that up to 62% of residual MFs can enter the sewer network or the receiving water body. Cotton and wool, and numerous MPs (acrylic, polyester, polypropylene, polyamide, and viscose/rayon) were identified in the inflow and outflow samples (with the only exception of “dense” viscose (rayon), not detected in the outflows, and probably retained by the WWTP with the sludge). This study, even if just preliminary, offers interesting hints for future research on MFs/MPs detection in textile wastewater, and on the performance of a full-scale WWT process for their removal.https://www.mdpi.com/2673-8929/1/4/40filtrationmicrofibermicroplastictextilewastewater
spellingShingle Sinem Hazal Akyildiz
Rossana Bellopede
Hande Sezgin
Ipek Yalcin-Enis
Bahattin Yalcin
Silvia Fiore
Detection and Analysis of Microfibers and Microplastics in Wastewater from a Textile Company
Microplastics
filtration
microfiber
microplastic
textile
wastewater
title Detection and Analysis of Microfibers and Microplastics in Wastewater from a Textile Company
title_full Detection and Analysis of Microfibers and Microplastics in Wastewater from a Textile Company
title_fullStr Detection and Analysis of Microfibers and Microplastics in Wastewater from a Textile Company
title_full_unstemmed Detection and Analysis of Microfibers and Microplastics in Wastewater from a Textile Company
title_short Detection and Analysis of Microfibers and Microplastics in Wastewater from a Textile Company
title_sort detection and analysis of microfibers and microplastics in wastewater from a textile company
topic filtration
microfiber
microplastic
textile
wastewater
url https://www.mdpi.com/2673-8929/1/4/40
work_keys_str_mv AT sinemhazalakyildiz detectionandanalysisofmicrofibersandmicroplasticsinwastewaterfromatextilecompany
AT rossanabellopede detectionandanalysisofmicrofibersandmicroplasticsinwastewaterfromatextilecompany
AT handesezgin detectionandanalysisofmicrofibersandmicroplasticsinwastewaterfromatextilecompany
AT ipekyalcinenis detectionandanalysisofmicrofibersandmicroplasticsinwastewaterfromatextilecompany
AT bahattinyalcin detectionandanalysisofmicrofibersandmicroplasticsinwastewaterfromatextilecompany
AT silviafiore detectionandanalysisofmicrofibersandmicroplasticsinwastewaterfromatextilecompany