rac-Ethyl rel-(2R,3R,4S)-4-hydroxy-1,2-dimethyl-5-oxopyrrolidine-3-carboxylate
The asymmetric unit of the title compound, C9H15NO4, consists of a functionalized pyrrolidine ring having an envelope conformation, synthesized as an ethyl ester. The molecule has three chiral centres and crystallized as a racemic mixture. In the crystal, molecules are linked by pairwise O—H...O bon...
| Main Authors: | , , , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2023-02-01
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| Series: | IUCrData |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314623000755 |
| _version_ | 1811158126875901952 |
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| author | Fatin Nur Ain Abdul Rashid Muhamad Zulfaqar Bacho Muhamad Azwan Hamali Alexandra M. Z. Slawin Mohd Fazli Mohammat Ruwaida Shamsujunaidi Mohd Abdul Fatah Abdul Manan |
| author_facet | Fatin Nur Ain Abdul Rashid Muhamad Zulfaqar Bacho Muhamad Azwan Hamali Alexandra M. Z. Slawin Mohd Fazli Mohammat Ruwaida Shamsujunaidi Mohd Abdul Fatah Abdul Manan |
| author_sort | Fatin Nur Ain Abdul Rashid |
| collection | DOAJ |
| description | The asymmetric unit of the title compound, C9H15NO4, consists of a functionalized pyrrolidine ring having an envelope conformation, synthesized as an ethyl ester. The molecule has three chiral centres and crystallized as a racemic mixture. In the crystal, molecules are linked by pairwise O—H...O bonds, generating dimers with twofold rotational symmetry. |
| first_indexed | 2024-04-10T05:19:05Z |
| format | Article |
| id | doaj.art-51b508d821894a8ca99e23e682ed21d4 |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-04-10T05:19:05Z |
| publishDate | 2023-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-51b508d821894a8ca99e23e682ed21d42023-03-08T12:47:08ZengInternational Union of CrystallographyIUCrData2414-31462023-02-0182x23007510.1107/S2414314623000755bh4072rac-Ethyl rel-(2R,3R,4S)-4-hydroxy-1,2-dimethyl-5-oxopyrrolidine-3-carboxylateFatin Nur Ain Abdul Rashid0Muhamad Zulfaqar Bacho1Muhamad Azwan Hamali2Alexandra M. Z. Slawin3Mohd Fazli Mohammat4Ruwaida Shamsujunaidi5Mohd Abdul Fatah Abdul Manan6Organic Synthesis Research Laboratory, Institute of Science, Universiti Teknologi MARA, 42300 Bandar Puncak Alam, Selangor, MalaysiaOrganic Synthesis Research Laboratory, Institute of Science, Universiti Teknologi MARA, 42300 Bandar Puncak Alam, Selangor, MalaysiaFaculty of Applied Sciences, Universiti Teknologi MARA, 40450 Shah Alam, Selangor, MalaysiaEaStCHEM School of Chemistry, University of St Andrews, North Haugh, St Andrews, KY16 9ST, United KingdomOrganic Synthesis Research Laboratory, Institute of Science, Universiti Teknologi MARA, 42300 Bandar Puncak Alam, Selangor, MalaysiaFaculty of Applied Sciences, Universiti Teknologi MARA, 40450 Shah Alam, Selangor, MalaysiaFaculty of Applied Sciences, Universiti Teknologi MARA, 40450 Shah Alam, Selangor, MalaysiaThe asymmetric unit of the title compound, C9H15NO4, consists of a functionalized pyrrolidine ring having an envelope conformation, synthesized as an ethyl ester. The molecule has three chiral centres and crystallized as a racemic mixture. In the crystal, molecules are linked by pairwise O—H...O bonds, generating dimers with twofold rotational symmetry.http://scripts.iucr.org/cgi-bin/paper?S2414314623000755crystal structureoxopyrrolidinering conformationhydrogen bonds |
| spellingShingle | Fatin Nur Ain Abdul Rashid Muhamad Zulfaqar Bacho Muhamad Azwan Hamali Alexandra M. Z. Slawin Mohd Fazli Mohammat Ruwaida Shamsujunaidi Mohd Abdul Fatah Abdul Manan rac-Ethyl rel-(2R,3R,4S)-4-hydroxy-1,2-dimethyl-5-oxopyrrolidine-3-carboxylate IUCrData crystal structure oxopyrrolidine ring conformation hydrogen bonds |
| title | rac-Ethyl rel-(2R,3R,4S)-4-hydroxy-1,2-dimethyl-5-oxopyrrolidine-3-carboxylate |
| title_full | rac-Ethyl rel-(2R,3R,4S)-4-hydroxy-1,2-dimethyl-5-oxopyrrolidine-3-carboxylate |
| title_fullStr | rac-Ethyl rel-(2R,3R,4S)-4-hydroxy-1,2-dimethyl-5-oxopyrrolidine-3-carboxylate |
| title_full_unstemmed | rac-Ethyl rel-(2R,3R,4S)-4-hydroxy-1,2-dimethyl-5-oxopyrrolidine-3-carboxylate |
| title_short | rac-Ethyl rel-(2R,3R,4S)-4-hydroxy-1,2-dimethyl-5-oxopyrrolidine-3-carboxylate |
| title_sort | rac ethyl rel 2r 3r 4s 4 hydroxy 1 2 dimethyl 5 oxopyrrolidine 3 carboxylate |
| topic | crystal structure oxopyrrolidine ring conformation hydrogen bonds |
| url | http://scripts.iucr.org/cgi-bin/paper?S2414314623000755 |
| work_keys_str_mv | AT fatinnurainabdulrashid racethylrel2r3r4s4hydroxy12dimethyl5oxopyrrolidine3carboxylate AT muhamadzulfaqarbacho racethylrel2r3r4s4hydroxy12dimethyl5oxopyrrolidine3carboxylate AT muhamadazwanhamali racethylrel2r3r4s4hydroxy12dimethyl5oxopyrrolidine3carboxylate AT alexandramzslawin racethylrel2r3r4s4hydroxy12dimethyl5oxopyrrolidine3carboxylate AT mohdfazlimohammat racethylrel2r3r4s4hydroxy12dimethyl5oxopyrrolidine3carboxylate AT ruwaidashamsujunaidi racethylrel2r3r4s4hydroxy12dimethyl5oxopyrrolidine3carboxylate AT mohdabdulfatahabdulmanan racethylrel2r3r4s4hydroxy12dimethyl5oxopyrrolidine3carboxylate |