Preparation of hydroxide ion conductive KOH–layered double hydroxide electrolytes for an all-solid-state iron–air secondary battery
Anion conductive solid electrolytes based on Mg–Al layered double hydroxide (LDH) were prepared for application in an all-solid-state Fe–air battery. The ionic conductivity and the conducting ion species were evaluated from impedance and electromotive force measurements. The ion conductivity of LDH...
| Main Authors: | , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Taylor & Francis Group
2014-06-01
|
| Series: | Journal of Asian Ceramic Societies |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2187076414000360 |
| _version_ | 1818936948259028992 |
|---|---|
| author | Taku Tsuneishi Hisatoshi Sakamoto Kazushi Hayashi Go Kawamura Hiroyuki Muto Atsunori Matsuda |
| author_facet | Taku Tsuneishi Hisatoshi Sakamoto Kazushi Hayashi Go Kawamura Hiroyuki Muto Atsunori Matsuda |
| author_sort | Taku Tsuneishi |
| collection | DOAJ |
| description | Anion conductive solid electrolytes based on Mg–Al layered double hydroxide (LDH) were prepared for application in an all-solid-state Fe–air battery. The ionic conductivity and the conducting ion species were evaluated from impedance and electromotive force measurements. The ion conductivity of LDH was markedly enhanced upon addition of KOH. The electromotive force in a water vapor concentration cell was similar to that of an anion-conducting polymer membrane. The KOH–LDH obtained was used as a hydroxide ion conductive electrolyte for all-solid-state Fe–air batteries. The cell performance of the Fe–air batteries was examined using a mixture of KOH–LDH and iron-oxide-supported carbon as the negative electrode. |
| first_indexed | 2024-12-20T05:44:10Z |
| format | Article |
| id | doaj.art-51c7a82ec38448ea9c571f46bdc2b3fc |
| institution | Directory Open Access Journal |
| issn | 2187-0764 |
| language | English |
| last_indexed | 2024-12-20T05:44:10Z |
| publishDate | 2014-06-01 |
| publisher | Taylor & Francis Group |
| record_format | Article |
| series | Journal of Asian Ceramic Societies |
| spelling | doaj.art-51c7a82ec38448ea9c571f46bdc2b3fc2022-12-21T19:51:21ZengTaylor & Francis GroupJournal of Asian Ceramic Societies2187-07642014-06-012216516810.1016/j.jascer.2014.03.003Preparation of hydroxide ion conductive KOH–layered double hydroxide electrolytes for an all-solid-state iron–air secondary batteryTaku Tsuneishi0Hisatoshi Sakamoto1Kazushi Hayashi2Go Kawamura3Hiroyuki Muto4Atsunori Matsuda5Department of Environmental and Life Sciences, Toyohashi University of Technology, 1-1 Hibarigaoka, Tempaku-cho, Toyohashi, Aichi 441-8580, JapanElectronic Research Laboratory, Technical Development Group, Kobe Steel, Ltd., 1-5-5 Takatsukadai, Nishi-ku, Kobe, Hyogo 651-2271, JapanElectronic Research Laboratory, Technical Development Group, Kobe Steel, Ltd., 1-5-5 Takatsukadai, Nishi-ku, Kobe, Hyogo 651-2271, JapanDepartment of Electrical and Electronic Information Engineering, Toyohashi University of Technology, 1-1 Hibarigaoka, Tempaku-cho, Toyohashi, Aichi 441-8580, JapanDepartment of Environmental and Life Sciences, Toyohashi University of Technology, 1-1 Hibarigaoka, Tempaku-cho, Toyohashi, Aichi 441-8580, JapanDepartment of Environmental and Life Sciences, Toyohashi University of Technology, 1-1 Hibarigaoka, Tempaku-cho, Toyohashi, Aichi 441-8580, JapanAnion conductive solid electrolytes based on Mg–Al layered double hydroxide (LDH) were prepared for application in an all-solid-state Fe–air battery. The ionic conductivity and the conducting ion species were evaluated from impedance and electromotive force measurements. The ion conductivity of LDH was markedly enhanced upon addition of KOH. The electromotive force in a water vapor concentration cell was similar to that of an anion-conducting polymer membrane. The KOH–LDH obtained was used as a hydroxide ion conductive electrolyte for all-solid-state Fe–air batteries. The cell performance of the Fe–air batteries was examined using a mixture of KOH–LDH and iron-oxide-supported carbon as the negative electrode.http://www.sciencedirect.com/science/article/pii/S2187076414000360Layered double hydroxideHydroxide ion conductorIron oxide-supported carbonFe–air battery |
| spellingShingle | Taku Tsuneishi Hisatoshi Sakamoto Kazushi Hayashi Go Kawamura Hiroyuki Muto Atsunori Matsuda Preparation of hydroxide ion conductive KOH–layered double hydroxide electrolytes for an all-solid-state iron–air secondary battery Journal of Asian Ceramic Societies Layered double hydroxide Hydroxide ion conductor Iron oxide-supported carbon Fe–air battery |
| title | Preparation of hydroxide ion conductive KOH–layered double hydroxide electrolytes for an all-solid-state iron–air secondary battery |
| title_full | Preparation of hydroxide ion conductive KOH–layered double hydroxide electrolytes for an all-solid-state iron–air secondary battery |
| title_fullStr | Preparation of hydroxide ion conductive KOH–layered double hydroxide electrolytes for an all-solid-state iron–air secondary battery |
| title_full_unstemmed | Preparation of hydroxide ion conductive KOH–layered double hydroxide electrolytes for an all-solid-state iron–air secondary battery |
| title_short | Preparation of hydroxide ion conductive KOH–layered double hydroxide electrolytes for an all-solid-state iron–air secondary battery |
| title_sort | preparation of hydroxide ion conductive koh layered double hydroxide electrolytes for an all solid state iron air secondary battery |
| topic | Layered double hydroxide Hydroxide ion conductor Iron oxide-supported carbon Fe–air battery |
| url | http://www.sciencedirect.com/science/article/pii/S2187076414000360 |
| work_keys_str_mv | AT takutsuneishi preparationofhydroxideionconductivekohlayereddoublehydroxideelectrolytesforanallsolidstateironairsecondarybattery AT hisatoshisakamoto preparationofhydroxideionconductivekohlayereddoublehydroxideelectrolytesforanallsolidstateironairsecondarybattery AT kazushihayashi preparationofhydroxideionconductivekohlayereddoublehydroxideelectrolytesforanallsolidstateironairsecondarybattery AT gokawamura preparationofhydroxideionconductivekohlayereddoublehydroxideelectrolytesforanallsolidstateironairsecondarybattery AT hiroyukimuto preparationofhydroxideionconductivekohlayereddoublehydroxideelectrolytesforanallsolidstateironairsecondarybattery AT atsunorimatsuda preparationofhydroxideionconductivekohlayereddoublehydroxideelectrolytesforanallsolidstateironairsecondarybattery |