6-Phenyl-6,7-dihydrodibenzo[c,f][1,5]azabismocin-12(5H)-yl perchlorate

In the title compound, [Bi(C20H17N)(ClO4)] or C20H17BiClNO4, the BiIII ion assumes a distorted ψ trigonal–bipyramidal geometry, with two C atoms and the electron lone pair of the Bi atom at the equatorial positions and an amine N atom and a perchlorate O atom at the apical...

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Main Authors: Xiao-Wen Zhang, Ting Fan
Format: Article
Language:English
Published: International Union of Crystallography 2011-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811021039
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author Xiao-Wen Zhang
Ting Fan
author_facet Xiao-Wen Zhang
Ting Fan
author_sort Xiao-Wen Zhang
collection DOAJ
description In the title compound, [Bi(C20H17N)(ClO4)] or C20H17BiClNO4, the BiIII ion assumes a distorted ψ trigonal–bipyramidal geometry, with two C atoms and the electron lone pair of the Bi atom at the equatorial positions and an amine N atom and a perchlorate O atom at the apical positions. Weak intermolecular C—H...O hydrogen bonding is present in the crystal structure.
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spelling doaj.art-51ce5a800ff84933af57a13a8486ed0f2022-12-21T17:18:16ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-07-01677m875m87510.1107/S16005368110210396-Phenyl-6,7-dihydrodibenzo[c,f][1,5]azabismocin-12(5H)-yl perchlorateXiao-Wen ZhangTing FanIn the title compound, [Bi(C20H17N)(ClO4)] or C20H17BiClNO4, the BiIII ion assumes a distorted ψ trigonal–bipyramidal geometry, with two C atoms and the electron lone pair of the Bi atom at the equatorial positions and an amine N atom and a perchlorate O atom at the apical positions. Weak intermolecular C—H...O hydrogen bonding is present in the crystal structure.http://scripts.iucr.org/cgi-bin/paper?S1600536811021039
spellingShingle Xiao-Wen Zhang
Ting Fan
6-Phenyl-6,7-dihydrodibenzo[c,f][1,5]azabismocin-12(5H)-yl perchlorate
Acta Crystallographica Section E
title 6-Phenyl-6,7-dihydrodibenzo[c,f][1,5]azabismocin-12(5H)-yl perchlorate
title_full 6-Phenyl-6,7-dihydrodibenzo[c,f][1,5]azabismocin-12(5H)-yl perchlorate
title_fullStr 6-Phenyl-6,7-dihydrodibenzo[c,f][1,5]azabismocin-12(5H)-yl perchlorate
title_full_unstemmed 6-Phenyl-6,7-dihydrodibenzo[c,f][1,5]azabismocin-12(5H)-yl perchlorate
title_short 6-Phenyl-6,7-dihydrodibenzo[c,f][1,5]azabismocin-12(5H)-yl perchlorate
title_sort 6 phenyl 6 7 dihydrodibenzo c f 1 5 azabismocin 12 5h yl perchlorate
url http://scripts.iucr.org/cgi-bin/paper?S1600536811021039
work_keys_str_mv AT xiaowenzhang 6phenyl67dihydrodibenzocf15azabismocin125hylperchlorate
AT tingfan 6phenyl67dihydrodibenzocf15azabismocin125hylperchlorate