Photocatalytic degradation of Rhodamine B dye with TiO2 immobilized on SiC foam using full factorial design

Abstract Textile effluents treatment is one of the important environmental challenges nowadays. Photocatalysis has proven its effectiveness for the removal of recalcitrant compounds, and it is considered as a green technology for the treatment of effluents. However, good photocatalytic yield is stro...

Full description

Bibliographic Details
Main Authors: Paul Henri Allé, Guy Didier Fanou, Didier Robert, Kopoin Adouby, Patrick Drogui
Format: Article
Language:English
Published: SpringerOpen 2020-08-01
Series:Applied Water Science
Subjects:
Online Access:http://link.springer.com/article/10.1007/s13201-020-01282-4
_version_ 1818280229686214656
author Paul Henri Allé
Guy Didier Fanou
Didier Robert
Kopoin Adouby
Patrick Drogui
author_facet Paul Henri Allé
Guy Didier Fanou
Didier Robert
Kopoin Adouby
Patrick Drogui
author_sort Paul Henri Allé
collection DOAJ
description Abstract Textile effluents treatment is one of the important environmental challenges nowadays. Photocatalysis has proven its effectiveness for the removal of recalcitrant compounds, and it is considered as a green technology for the treatment of effluents. However, good photocatalytic yield is strongly related to the operating parameters. In this study, a supported TiO2 on a β-SiC foam was tested for the removal of Rhodamine B (RhB). The photocatalytic discoloration of RhB synthetic solution in our condition was about 90%. The effects of each parameter were assessed through a full factorial design. Sixteen tests were carried out and the response was RhB removal. The most influent parameters were TiO2/β-SiC foam quantity, the concentration of RhB, the volume of H2O2 and pH. Their contributions on RhB removal were, respectively, 53.01, 30.49, 2.7, and 2.48% according to Pareto diagram. Analysis of the coefficients shows that initial concentration of RhB and volume of H2O2 had a negative effect on the response. However, the quantity of TiO2/β-SiC foam and pH had a positive effect on the response. The influence of the flow rate on the process was assessed. The results showed a slight increase in RhB removal. Furthermore, the aging test of TiO2/β-SiC foam on the photocatalytic efficiency was carried out after ten successive photocatalysis tests. Only 6.7% loss of yield was observed. These results are very encouraging for an application at the industrial scale.
first_indexed 2024-12-12T23:45:55Z
format Article
id doaj.art-51cff636294245ca84a74dfc45b20756
institution Directory Open Access Journal
issn 2190-5487
2190-5495
language English
last_indexed 2024-12-12T23:45:55Z
publishDate 2020-08-01
publisher SpringerOpen
record_format Article
series Applied Water Science
spelling doaj.art-51cff636294245ca84a74dfc45b207562022-12-22T00:06:50ZengSpringerOpenApplied Water Science2190-54872190-54952020-08-011091910.1007/s13201-020-01282-4Photocatalytic degradation of Rhodamine B dye with TiO2 immobilized on SiC foam using full factorial designPaul Henri Allé0Guy Didier Fanou1Didier Robert2Kopoin Adouby3Patrick Drogui4Laboratoire des Procédés Industriels de Synthèse, de l’Environnement et des Energies Nouvelles (LAPISEN), Institut National Polytechnique Félix Houphouët-BoignyLaboratoire des Procédés Industriels de Synthèse, de l’Environnement et des Energies Nouvelles (LAPISEN), Institut National Polytechnique Félix Houphouët-BoignyInstitut de Chimie de Procédé pour L’Energie, L’Environnement et la Santé (ICPEES-UMR 7515 CNRS), Université de StrasbourgLaboratoire des Procédés Industriels de Synthèse, de l’Environnement et des Energies Nouvelles (LAPISEN), Institut National Polytechnique Félix Houphouët-BoignyInstitut National de la Recherche Scientifique (INRS Eau Terre et Environnement), Université du QuébecAbstract Textile effluents treatment is one of the important environmental challenges nowadays. Photocatalysis has proven its effectiveness for the removal of recalcitrant compounds, and it is considered as a green technology for the treatment of effluents. However, good photocatalytic yield is strongly related to the operating parameters. In this study, a supported TiO2 on a β-SiC foam was tested for the removal of Rhodamine B (RhB). The photocatalytic discoloration of RhB synthetic solution in our condition was about 90%. The effects of each parameter were assessed through a full factorial design. Sixteen tests were carried out and the response was RhB removal. The most influent parameters were TiO2/β-SiC foam quantity, the concentration of RhB, the volume of H2O2 and pH. Their contributions on RhB removal were, respectively, 53.01, 30.49, 2.7, and 2.48% according to Pareto diagram. Analysis of the coefficients shows that initial concentration of RhB and volume of H2O2 had a negative effect on the response. However, the quantity of TiO2/β-SiC foam and pH had a positive effect on the response. The influence of the flow rate on the process was assessed. The results showed a slight increase in RhB removal. Furthermore, the aging test of TiO2/β-SiC foam on the photocatalytic efficiency was carried out after ten successive photocatalysis tests. Only 6.7% loss of yield was observed. These results are very encouraging for an application at the industrial scale.http://link.springer.com/article/10.1007/s13201-020-01282-4PhotocatalysisTiO2/β-SiC foamRhodamine BFactorial design
spellingShingle Paul Henri Allé
Guy Didier Fanou
Didier Robert
Kopoin Adouby
Patrick Drogui
Photocatalytic degradation of Rhodamine B dye with TiO2 immobilized on SiC foam using full factorial design
Applied Water Science
Photocatalysis
TiO2/β-SiC foam
Rhodamine B
Factorial design
title Photocatalytic degradation of Rhodamine B dye with TiO2 immobilized on SiC foam using full factorial design
title_full Photocatalytic degradation of Rhodamine B dye with TiO2 immobilized on SiC foam using full factorial design
title_fullStr Photocatalytic degradation of Rhodamine B dye with TiO2 immobilized on SiC foam using full factorial design
title_full_unstemmed Photocatalytic degradation of Rhodamine B dye with TiO2 immobilized on SiC foam using full factorial design
title_short Photocatalytic degradation of Rhodamine B dye with TiO2 immobilized on SiC foam using full factorial design
title_sort photocatalytic degradation of rhodamine b dye with tio2 immobilized on sic foam using full factorial design
topic Photocatalysis
TiO2/β-SiC foam
Rhodamine B
Factorial design
url http://link.springer.com/article/10.1007/s13201-020-01282-4
work_keys_str_mv AT paulhenrialle photocatalyticdegradationofrhodaminebdyewithtio2immobilizedonsicfoamusingfullfactorialdesign
AT guydidierfanou photocatalyticdegradationofrhodaminebdyewithtio2immobilizedonsicfoamusingfullfactorialdesign
AT didierrobert photocatalyticdegradationofrhodaminebdyewithtio2immobilizedonsicfoamusingfullfactorialdesign
AT kopoinadouby photocatalyticdegradationofrhodaminebdyewithtio2immobilizedonsicfoamusingfullfactorialdesign
AT patrickdrogui photocatalyticdegradationofrhodaminebdyewithtio2immobilizedonsicfoamusingfullfactorialdesign