Reactive Conductive Ink Capable of In Situ and Rapid Synthesis of Conductive Patterns Suitable for Inkjet Printing

We report a fabrication method of the conductive pattern based on in situ reactive silver precursor inks by inkjet printing. The reactive silver precursor inks were prepared with ethylene glycol and deionized water mixture as the solvent, and silver nitrate as silver source. Sodium borohydride solut...

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Main Authors: Yuehui Wang, Dexi Du, Zhimin Zhou, Hui Xie, Jingze Li, Yuzhen Zhao
Format: Article
Language:English
Published: MDPI AG 2019-09-01
Series:Molecules
Subjects:
Online Access:https://www.mdpi.com/1420-3049/24/19/3548
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author Yuehui Wang
Dexi Du
Zhimin Zhou
Hui Xie
Jingze Li
Yuzhen Zhao
author_facet Yuehui Wang
Dexi Du
Zhimin Zhou
Hui Xie
Jingze Li
Yuzhen Zhao
author_sort Yuehui Wang
collection DOAJ
description We report a fabrication method of the conductive pattern based on in situ reactive silver precursor inks by inkjet printing. The reactive silver precursor inks were prepared with ethylene glycol and deionized water mixture as the solvent, and silver nitrate as silver source. Sodium borohydride solution as the reducing agent was first coated on photographic paper by screen printing process, and then dried at 50 °C for 4 h. Furthermore, the reactive silver precursor inks were printed on a photographic paper coated with sodium borohydride using inkjet printing to form silver nanoparticles in situ due to redox reaction, and thus a conductive pattern was obtained. The effects of the reactive silver precursor ink concentration and printing layer number and treatment temperature on the electrical properties and microstructures of the printed patterns were investigated systematically. The size range of in situ-formed silver nanoparticles was 50−90 nm. When the reactive silver precursor ink concentration was 0.13 g/mL, the five-layer printed pattern exhibited a sheet resistance of 4.6 Ω/γ after drying at room temperature for 2 h; furthermore, the sheet resistance of the printed pattern decreased to 1.4 Ω/γ after drying at 130 °C for 2 h. In addition, the display function circuit was printed on the photographic paper to realize the display of the numbers 0−99. It provides new research ideas for the development of environmentally friendly and low-cost flexible paper-based circuits.
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spelling doaj.art-51d44fbb9a3449f08e561d67350660212022-12-22T01:32:01ZengMDPI AGMolecules1420-30492019-09-012419354810.3390/molecules24193548molecules24193548Reactive Conductive Ink Capable of In Situ and Rapid Synthesis of Conductive Patterns Suitable for Inkjet PrintingYuehui Wang0Dexi Du1Zhimin Zhou2Hui Xie3Jingze Li4Yuzhen Zhao5Zhongshan Institute, University of Electronic Science and Technology of China, Zhongshan 528402, ChinaZhongshan Institute, University of Electronic Science and Technology of China, Zhongshan 528402, ChinaZhongshan Institute, University of Electronic Science and Technology of China, Zhongshan 528402, ChinaZhongshan Institute, University of Electronic Science and Technology of China, Zhongshan 528402, ChinaSchool of Materials and Energy, University of Electronic Science and Technology of China, Chengdu 610054, ChinaDepartment of Materials Science and Engineering, Tsinghua University, Beijing 100084, ChinaWe report a fabrication method of the conductive pattern based on in situ reactive silver precursor inks by inkjet printing. The reactive silver precursor inks were prepared with ethylene glycol and deionized water mixture as the solvent, and silver nitrate as silver source. Sodium borohydride solution as the reducing agent was first coated on photographic paper by screen printing process, and then dried at 50 °C for 4 h. Furthermore, the reactive silver precursor inks were printed on a photographic paper coated with sodium borohydride using inkjet printing to form silver nanoparticles in situ due to redox reaction, and thus a conductive pattern was obtained. The effects of the reactive silver precursor ink concentration and printing layer number and treatment temperature on the electrical properties and microstructures of the printed patterns were investigated systematically. The size range of in situ-formed silver nanoparticles was 50−90 nm. When the reactive silver precursor ink concentration was 0.13 g/mL, the five-layer printed pattern exhibited a sheet resistance of 4.6 Ω/γ after drying at room temperature for 2 h; furthermore, the sheet resistance of the printed pattern decreased to 1.4 Ω/γ after drying at 130 °C for 2 h. In addition, the display function circuit was printed on the photographic paper to realize the display of the numbers 0−99. It provides new research ideas for the development of environmentally friendly and low-cost flexible paper-based circuits.https://www.mdpi.com/1420-3049/24/19/3548reactive inksilver nanoparticlesinkjet printingconductive pattern
spellingShingle Yuehui Wang
Dexi Du
Zhimin Zhou
Hui Xie
Jingze Li
Yuzhen Zhao
Reactive Conductive Ink Capable of In Situ and Rapid Synthesis of Conductive Patterns Suitable for Inkjet Printing
Molecules
reactive ink
silver nanoparticles
inkjet printing
conductive pattern
title Reactive Conductive Ink Capable of In Situ and Rapid Synthesis of Conductive Patterns Suitable for Inkjet Printing
title_full Reactive Conductive Ink Capable of In Situ and Rapid Synthesis of Conductive Patterns Suitable for Inkjet Printing
title_fullStr Reactive Conductive Ink Capable of In Situ and Rapid Synthesis of Conductive Patterns Suitable for Inkjet Printing
title_full_unstemmed Reactive Conductive Ink Capable of In Situ and Rapid Synthesis of Conductive Patterns Suitable for Inkjet Printing
title_short Reactive Conductive Ink Capable of In Situ and Rapid Synthesis of Conductive Patterns Suitable for Inkjet Printing
title_sort reactive conductive ink capable of in situ and rapid synthesis of conductive patterns suitable for inkjet printing
topic reactive ink
silver nanoparticles
inkjet printing
conductive pattern
url https://www.mdpi.com/1420-3049/24/19/3548
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AT huixie reactiveconductiveinkcapableofinsituandrapidsynthesisofconductivepatternssuitableforinkjetprinting
AT jingzeli reactiveconductiveinkcapableofinsituandrapidsynthesisofconductivepatternssuitableforinkjetprinting
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