Thermodynamic analysis of the processes of interaction and formation of nitrogen and sulfur compounds during the combustion of Kansk-Achinsk coals
The paper identifies and examines the mechanisms of the interaction of nitrogen and sulfur compounds during the combustion of Kansk-Achinsk coals (KAC). The researches were carried out on the basis of the model of extreme intermediate states (MEIS) developed at The L.A. Melentiev Institute of Energy...
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Format: | Article |
Language: | English |
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EDP Sciences
2023-01-01
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Series: | E3S Web of Conferences |
Online Access: | https://www.e3s-conferences.org/articles/e3sconf/pdf/2023/98/e3sconf_rses23_01048.pdf |
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author | Elsukov Vladimir Latushkina Svetlana |
author_facet | Elsukov Vladimir Latushkina Svetlana |
author_sort | Elsukov Vladimir |
collection | DOAJ |
description | The paper identifies and examines the mechanisms of the interaction of nitrogen and sulfur compounds during the combustion of Kansk-Achinsk coals (KAC). The researches were carried out on the basis of the model of extreme intermediate states (MEIS) developed at The L.A. Melentiev Institute of Energy Systems and presented in a number of publications. The KAC of various deposits characterized by different content of sulfur and mineral components are considered. On the basis of computational experiments, the influence of alkaline elements of the mineral part (Ca, Na, K) on the formation of NO and SO2 was determined. The temperature interval of the transition of condensed calcium sulfate to sulfur dioxide during the combustion of KAC of various (including new) deposits has been clarified. Based on the modeling of thermodynamic states, the results of industrial tests are considered, in which inversely proportional dependences of NO and SO2 on the resulting calcium sulfate have been recorded. These dependences can be explained by multidirectional energy flows during the formation of CaSO4/c and NOx. |
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id | doaj.art-51e27668d4d44914a5e663aefc9e61c5 |
institution | Directory Open Access Journal |
issn | 2267-1242 |
language | English |
last_indexed | 2024-03-08T11:13:20Z |
publishDate | 2023-01-01 |
publisher | EDP Sciences |
record_format | Article |
series | E3S Web of Conferences |
spelling | doaj.art-51e27668d4d44914a5e663aefc9e61c52024-01-26T10:39:43ZengEDP SciencesE3S Web of Conferences2267-12422023-01-014610104810.1051/e3sconf/202346101048e3sconf_rses23_01048Thermodynamic analysis of the processes of interaction and formation of nitrogen and sulfur compounds during the combustion of Kansk-Achinsk coalsElsukov Vladimir0Latushkina Svetlana1Bratsk State UniversityBratsk State UniversityThe paper identifies and examines the mechanisms of the interaction of nitrogen and sulfur compounds during the combustion of Kansk-Achinsk coals (KAC). The researches were carried out on the basis of the model of extreme intermediate states (MEIS) developed at The L.A. Melentiev Institute of Energy Systems and presented in a number of publications. The KAC of various deposits characterized by different content of sulfur and mineral components are considered. On the basis of computational experiments, the influence of alkaline elements of the mineral part (Ca, Na, K) on the formation of NO and SO2 was determined. The temperature interval of the transition of condensed calcium sulfate to sulfur dioxide during the combustion of KAC of various (including new) deposits has been clarified. Based on the modeling of thermodynamic states, the results of industrial tests are considered, in which inversely proportional dependences of NO and SO2 on the resulting calcium sulfate have been recorded. These dependences can be explained by multidirectional energy flows during the formation of CaSO4/c and NOx.https://www.e3s-conferences.org/articles/e3sconf/pdf/2023/98/e3sconf_rses23_01048.pdf |
spellingShingle | Elsukov Vladimir Latushkina Svetlana Thermodynamic analysis of the processes of interaction and formation of nitrogen and sulfur compounds during the combustion of Kansk-Achinsk coals E3S Web of Conferences |
title | Thermodynamic analysis of the processes of interaction and formation of nitrogen and sulfur compounds during the combustion of Kansk-Achinsk coals |
title_full | Thermodynamic analysis of the processes of interaction and formation of nitrogen and sulfur compounds during the combustion of Kansk-Achinsk coals |
title_fullStr | Thermodynamic analysis of the processes of interaction and formation of nitrogen and sulfur compounds during the combustion of Kansk-Achinsk coals |
title_full_unstemmed | Thermodynamic analysis of the processes of interaction and formation of nitrogen and sulfur compounds during the combustion of Kansk-Achinsk coals |
title_short | Thermodynamic analysis of the processes of interaction and formation of nitrogen and sulfur compounds during the combustion of Kansk-Achinsk coals |
title_sort | thermodynamic analysis of the processes of interaction and formation of nitrogen and sulfur compounds during the combustion of kansk achinsk coals |
url | https://www.e3s-conferences.org/articles/e3sconf/pdf/2023/98/e3sconf_rses23_01048.pdf |
work_keys_str_mv | AT elsukovvladimir thermodynamicanalysisoftheprocessesofinteractionandformationofnitrogenandsulfurcompoundsduringthecombustionofkanskachinskcoals AT latushkinasvetlana thermodynamicanalysisoftheprocessesofinteractionandformationofnitrogenandsulfurcompoundsduringthecombustionofkanskachinskcoals |