The atypical hues of the Santa Cruz blue-and-white cargo: non-invasive analysis of glaze defects and color variations in mid-Ming porcelain

Abstract Color variations and sometimes the frosted appearance of Chinese blue-and-white porcelain produced in folk kilns and recovered in underwater archaeological contexts are usually reported without further investigation. This study focuses on the causes responsible for the appearance of the gla...

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Main Authors: Ellen Hsieh, Christian Fischer, Bobby C. Orillaneda
Format: Article
Language:English
Published: SpringerOpen 2023-05-01
Series:Heritage Science
Subjects:
Online Access:https://doi.org/10.1186/s40494-023-00953-0
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author Ellen Hsieh
Christian Fischer
Bobby C. Orillaneda
author_facet Ellen Hsieh
Christian Fischer
Bobby C. Orillaneda
author_sort Ellen Hsieh
collection DOAJ
description Abstract Color variations and sometimes the frosted appearance of Chinese blue-and-white porcelain produced in folk kilns and recovered in underwater archaeological contexts are usually reported without further investigation. This study focuses on the causes responsible for the appearance of the glaze and blue decorations of late fifteenth-century blue-and-white porcelain from the Santa Cruz, one of the most important mid-Ming shipwrecks discovered in Asian waters. Besides detailed visual observations, chemical composition and colorimetric data were collected on a set of similarly shaped plates showing significant differences in the aspect of the glaze and tones and shades of the blue color. Results from portable X-ray fluorescence (pXRF) analysis confirmed the Jingdezhen origin of the ware and the use of domestic asbolane ores for the Co-based blue pigment. Visual and microstructural analysis has shown that the degree of opacity of the glaze is primarily linked to the crystallization of anorthite, which in some cases has pushed the pigment layer towards the surface, contributing to the development of white-brownish weathering spots. The colorimetric data acquired with fiber optics reflectance spectroscopy (FORS) allowed us to quantify chromaticity parameters and confirm the visual perception of a ‘not-so-blue’ color of the decoration. Without excluding a possible contribution of the underwater environment, the observed variations can be mainly attributed to the ware’s production and more specifically to pigment characteristics, manufacturing processes, and firing conditions even though the connection with these factors is not straightforward and prompts further research and broader discussions. From a historical perspective, it is suggested that the atypical hues are correlated with the progressive switch from foreign to domestic pigment sources during the Chenghua period (1465–87 CE) and the subsequent technological adaptations required by an ever-increasing demand for Chinese blue-and-white porcelain at the turn of the sixteenth century.
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spelling doaj.art-51e305bfc30a4d72b05c8df6eb9384702023-05-21T11:22:59ZengSpringerOpenHeritage Science2050-74452023-05-0111111710.1186/s40494-023-00953-0The atypical hues of the Santa Cruz blue-and-white cargo: non-invasive analysis of glaze defects and color variations in mid-Ming porcelainEllen Hsieh0Christian FischerBobby C. Orillaneda1Institute of Anthropology, Research Center for Underwater Archaeology and Heritage, National Tsing Hua UniversityMaritime and Underwater Cultural Heritage Division, National Museum of the PhilippinesAbstract Color variations and sometimes the frosted appearance of Chinese blue-and-white porcelain produced in folk kilns and recovered in underwater archaeological contexts are usually reported without further investigation. This study focuses on the causes responsible for the appearance of the glaze and blue decorations of late fifteenth-century blue-and-white porcelain from the Santa Cruz, one of the most important mid-Ming shipwrecks discovered in Asian waters. Besides detailed visual observations, chemical composition and colorimetric data were collected on a set of similarly shaped plates showing significant differences in the aspect of the glaze and tones and shades of the blue color. Results from portable X-ray fluorescence (pXRF) analysis confirmed the Jingdezhen origin of the ware and the use of domestic asbolane ores for the Co-based blue pigment. Visual and microstructural analysis has shown that the degree of opacity of the glaze is primarily linked to the crystallization of anorthite, which in some cases has pushed the pigment layer towards the surface, contributing to the development of white-brownish weathering spots. The colorimetric data acquired with fiber optics reflectance spectroscopy (FORS) allowed us to quantify chromaticity parameters and confirm the visual perception of a ‘not-so-blue’ color of the decoration. Without excluding a possible contribution of the underwater environment, the observed variations can be mainly attributed to the ware’s production and more specifically to pigment characteristics, manufacturing processes, and firing conditions even though the connection with these factors is not straightforward and prompts further research and broader discussions. From a historical perspective, it is suggested that the atypical hues are correlated with the progressive switch from foreign to domestic pigment sources during the Chenghua period (1465–87 CE) and the subsequent technological adaptations required by an ever-increasing demand for Chinese blue-and-white porcelain at the turn of the sixteenth century.https://doi.org/10.1186/s40494-023-00953-0Santa Cruz shipwreckBlue-and-white porcelainJingdezhenpXRFFORSCobalt blue
spellingShingle Ellen Hsieh
Christian Fischer
Bobby C. Orillaneda
The atypical hues of the Santa Cruz blue-and-white cargo: non-invasive analysis of glaze defects and color variations in mid-Ming porcelain
Heritage Science
Santa Cruz shipwreck
Blue-and-white porcelain
Jingdezhen
pXRF
FORS
Cobalt blue
title The atypical hues of the Santa Cruz blue-and-white cargo: non-invasive analysis of glaze defects and color variations in mid-Ming porcelain
title_full The atypical hues of the Santa Cruz blue-and-white cargo: non-invasive analysis of glaze defects and color variations in mid-Ming porcelain
title_fullStr The atypical hues of the Santa Cruz blue-and-white cargo: non-invasive analysis of glaze defects and color variations in mid-Ming porcelain
title_full_unstemmed The atypical hues of the Santa Cruz blue-and-white cargo: non-invasive analysis of glaze defects and color variations in mid-Ming porcelain
title_short The atypical hues of the Santa Cruz blue-and-white cargo: non-invasive analysis of glaze defects and color variations in mid-Ming porcelain
title_sort atypical hues of the santa cruz blue and white cargo non invasive analysis of glaze defects and color variations in mid ming porcelain
topic Santa Cruz shipwreck
Blue-and-white porcelain
Jingdezhen
pXRF
FORS
Cobalt blue
url https://doi.org/10.1186/s40494-023-00953-0
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